Metal-organic layers as a platform for developing single-atom catalysts for photochemical CO2 reduction

Nano Energy ◽  
2021 ◽  
Vol 80 ◽  
pp. 105542
Author(s):  
Ji-Hong Zhang ◽  
Wei Yang ◽  
Min Zhang ◽  
Hong-Juan Wang ◽  
Rui Si ◽  
...  
Author(s):  
Danni Zhou ◽  
Xinyuan Li ◽  
Huishan Shang ◽  
Fengjuan Qin ◽  
Wenxing Chen

Metal-organic framework (MOF) derived single-atom catalysts (SACs), featured unique active sites and adjustable topological structures, exhibit high electrocatalytic performance on carbon dioxide reduction reactions (CO2RR). By modulating elements and atomic...


2020 ◽  
Vol 142 (51) ◽  
pp. 21493-21501
Author(s):  
Ying Guo ◽  
Yucheng Wang ◽  
Yan Shen ◽  
Zhuanyun Cai ◽  
Zhe Li ◽  
...  

2019 ◽  
Vol 55 (65) ◽  
pp. 9657-9660 ◽  
Author(s):  
Xuefu Hu ◽  
Peican Chen ◽  
Cankun Zhang ◽  
Zhiye Wang ◽  
Cheng Wang

Excited state energies on a two-dimensional light-harvesting metal–organic layer (MOL) are efficiently transported to Re- and Ir-based reaction centers for converting CO2 to CO or HCOOH.


Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2029
Author(s):  
Muhammad Usman ◽  
Muhammad Humayun ◽  
Mustapha D. Garba ◽  
Latif Ullah ◽  
Zonish Zeb ◽  
...  

Electrochemical CO2 reduction reaction (CO2RR) provides a promising approach to curbing harmful emissions contributing to global warming. However, several challenges hinder the commercialization of this technology, including high overpotentials, electrode instability, and low Faradic efficiencies of desirable products. Several materials have been developed to overcome these challenges. This mini-review discusses the recent performance of various cobalt (Co) electrocatalysts, including Co-single atom, Co-multi metals, Co-complexes, Co-based metal–organic frameworks (MOFs), Co-based covalent organic frameworks (COFs), Co-nitrides, and Co-oxides. These materials are reviewed with respect to their stability of facilitating CO2 conversion to valuable products, and a summary of the current literature is highlighted, along with future perspectives for the development of efficient CO2RR.


2021 ◽  
Author(s):  
Zhen Han ◽  
Yaomei Fu ◽  
Yingchao Zhang ◽  
Xiao Zhang ◽  
Xing Meng ◽  
...  

We designed and synthesized TVPT-MOFs, combined with g-C3N4, and the yield of CO2 reduction could reach 56 μmol·g−1·h−1.


2021 ◽  
Author(s):  
Hai-Long Jiang ◽  
Yan Zhang ◽  
Long Jiao ◽  
Weijie Yang ◽  
Chenfan Xie
Keyword(s):  

2021 ◽  
Author(s):  
Cornelia Elizabeth Pompe ◽  
Petra Agota Szilagyi

Metal-organic frameworks are promising host supporting matrices for catalytically active guest. In particular, their crystallinity renders them desirable as their pores may act as atom-precise templates for the growth of...


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