Role of pyrolysis reaction temperature and heating-rate in the growth and morphology of carbon nanostructures

2017 ◽  
Vol 12 ◽  
pp. 229-238 ◽  
Author(s):  
Rajeev Kumar ◽  
Rajmohan Rajendiran ◽  
Harish Kumar Choudhary ◽  
Naveen Kumar G.M. ◽  
Badimela Balaiah ◽  
...  
2021 ◽  
Vol 127 (9) ◽  
Author(s):  
Mohamed N. Abd-el Salam ◽  
E. R. Shaaban ◽  
Mansour Mohamed
Keyword(s):  

2012 ◽  
Vol 512-515 ◽  
pp. 375-378
Author(s):  
Su Wen Yang ◽  
Jian Min Yi ◽  
Ke Qiang Qiu ◽  
Xin Deng ◽  
Jian Shan Chen

This thesis does thermal gravimetric analysis(TGA)studies on Chinese fir sawdust biomass by integrated thermal analyzer under vacuum conditions. Through the analysis on lostmass curve at different heating rate of 10, 15, 20 and 30°C/min, we found the process of Chinese fir sawdust vacuum pyrolysis can be mainly divided into three stages: evaporation of free water and combined water desorption, rapid lostmass of pyrolysis and slow decomposition of residues. The lostmass major temperature range is between 250 ~ 450°C, the peak temperature is between 365 ~ 400°C. When the pyrolysis temperature is 500°C, vacuum pyrolysis reaction of Chinese fir sawdust has basically completed. As the heating rate rises, the lostmass curve is moving to the right, the peak temperature is shifting to higher temperature, and the temperature range of thermal decomposition reaction widens significantly. According to experimental datas, we tried to obtain the vacuum pyrolysis dynamic parameters of Chinese fir sawdust, and the results are that the apparent activation energy of vacuum pyrolysis reaction of Chinese fir sawdust biomass is 128.34kJ/mol, with the pre-exponential factor being 6.42×109 and reaction order being 1.08, similar to first order reaction.


2013 ◽  
Vol 850-851 ◽  
pp. 160-163
Author(s):  
Jun Song ◽  
Jian Wang ◽  
Li Wang

The thermal properties of calcium oxalate were studied by means of TG analyzer. The factors such as heating rate, filling amounts of specimens and filling atmosphere etc., which may affect thermo gravimetric (TG) curves in TG analysis test were investigated. The results showed that, with the improving of heating rate, filling amounts of specimens and close packing, the starting reaction temperature was postponed more obviously and the width of reaction temperature range rises. The flow of the nitrogen gas enhanced heat transmission, caused the starting reaction temperature to shift to the low temperature zone, and it could also affect the response course. But the factors above didnt obviously influence the weightlessness of specimens.


2007 ◽  
Vol 99 (1) ◽  
Author(s):  
Arkady V. Krasheninnikov ◽  
Yoshiyuki Miyamoto ◽  
David Tománek

2010 ◽  
Vol 64 (1) ◽  
Author(s):  
Elena Konyushenko ◽  
Miroslava Trchová ◽  
Jaroslav Stejskal ◽  
Irina Sapurina

AbstractConditions of polyaniline (PANI) nanotubes preparation were analyzed. Aniline was oxidized with ammonium peroxydisulfate in 0.4 M acetic acid. There are two subsequent oxidation steps and the products were collected after each of them. At pH > 3, neutral aniline molecules are oxidized to non-conducting aniline oligomers. These produce templates for the subsequent growth of PANI nanotubes, which takes place preferably at pH 2–3. At pH < 2, granular morphology of the conducting PANI is obtained. High final acidity of the medium should be avoided in the preparation of nanotubes, e.g., by reducing the amount of sulfuric acid which is a by-product. Reduction of the peroxydisulfate-to-aniline mole ratio was tested for this purpose in the present study. Lowering of the reaction temperature from 20°C to −4°C had a positive effect on the formation of nanotubes.


Nano Letters ◽  
2011 ◽  
Vol 11 (6) ◽  
pp. 2464-2471 ◽  
Author(s):  
Renu Sharma ◽  
See-Wee Chee ◽  
Andrew Herzing ◽  
Ryan Miranda ◽  
Peter Rez

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