Thermal Decomposition of 3-Nitro-1,2,4-Triazole-5-One (NTO) and Nanosize NTO Catalyzed by NiFe2O4

Nanosize Nickel ferrite (NiF) was synthesized by the co-precipitation methods and its effect as a 5 % by mass additive was studied on the thermal decomposition of micrometer and nanometer size NTO. In the presence of 5 % NiF additive, the thermal decomposition peak temperature of NTO was decreased from 276.36 to 260.18 oC and that of nano NTO was decreased from 261.38 to 258.89 oC (β=10 oC min-1). The kinetics parameters confirms the catalytic activity of NiF for the thermal decomposition of NTO, and nNTO as the parameters such as activation energy (NTO=~25.45 % and nNTO=~45.94 % decrement), and pre-exponential factor (NTO=~21.94 % and nNTO=~43.12 % decrement) were decreased when 5 % NiF additive was added to NTO, and nNTO. The rate of the decomposition process was increased in the presence of 5 % NiF catalyst, indicating the faster thermal decomposition of both NTO, and nNTO in the presence of nickel catalyst.

Asymmetry Thermal Analyses of Self-Supporting Friction Stir Welding

Due to the inherent issue of requiring rigid back support, friction stir welding (FSW) has serious limitations for the welding of hollow structures. Self-supporting friction stir welding was proposed to join hollow aluminum extrusions, which could reduce the hindrance of the welding tool and the requirement of rigid back support. In this paper, finite element modeling analyses were carried out for the asymmetric temperature field in the process of self-supporting FSW. The peak temperature of the stir zone appeared in the upper shoulder affected zone, followed by the lower shoulder affected zone. In the upper shoulder affected zone, a peak temperature was not shown at the center of the curve due to the positive correlation between heat generation and radius and different heat dissipation rates. Considering the influence of thermal input and rotation speed on joint formation, 200 mm/min travel speed and 800 rpm rotation speed are the most proper parameters for 5-mm-thick 6082-T6 aluminum alloy self-supporting FSW butt welds.

Modelling of Thermal Quantities for Quick Process Assessment and Process Capability Space Refinement at an Early Design Phase During Laser Welding

This research aims at understanding the impact of welding process parameters and beam oscillation on the weld thermal cycle during laser welding. A three-dimensional heat transfer model is developed to simulate the welding process, based on the finite element (FE) method. The calculated thermal cycle and weld morphology are in good agreement with experimental results from literature. By utilizing the developed heat transfer model, the effect of welding process parameters such as heat source power, welding speed, radius of oscillation, and frequency of oscillation on the intermediate performance indicators (IPIs) such as peak temperature, heat-affected zone volume (HAZ), and cooling rate is quantified. Parametric contour maps for peak temperature, HAZ volume, and cooling rate are developed for the estimation of the process capability space. An integrated approach for rapid process assessment, process capability space refinement, based on IPIs is proposed. The process capability space will guide the identification of the initial welding process parameters window and help in reducing the number of experiments required by refining the feasible region of process parameters based on the interactions with the IPIs. Here, the peak temperature indicates the mode of welding performed while the HAZ volume and cooling rate are weld quality indicators. The regression relationship between the welding process parameters and the IPIs is established for quick estimation of IPIs to replace time-consuming numerical simulations. The proposed approach provides a unique ability to simulate the laser welding process and provides a robust range of process parameters.

Simulation of Friction Stir Spot Welding of Copper and Aluminium During Plunging Phase

Simulation is limited and remains briefly addressed in the literature of friction stir spot welding (FSSW) process in joining dissimilar copper and aluminium. Thus, this study simulated the FSSW process of copper and aluminium to investigate the peak temperature during the plunging phase produced by all possible combinations of levels for tool rotational speed, plunge rate, and plunge depth according to the full factorial design. The modeling was established by Coupled Eulerian-Lagrangian (CEL) model and ‘dynamic, temperature-displacement, explicit’ analysis. The highest peak temperature of 994.4 oC was produced by 2400 rpm rotational speed, 100 mm/min plunge rate, and 1.6 mm plunge depth. The combination was suggested to be the optimum welding parameters in joining copper to aluminium as sufficient heat input was essential to soften the area around the welding tool and adequately plasticize the material. Three sets of confirmation tests presented consistent responses with a mean peak temperature of 994.4 °C, which validated that the response produced by the suggested optimum welding parameters was reliable. The statistical result reported that the variability in the factors could explain 84.12% of the variability in the response. However, only the rotational speed and plunge depth were statistically significant. The residual plots showed that the regression line model was valid.

Additive Manufacturing of Miniaturized Peak Temperature Monitors for In-Pile Applications

Passive monitoring techniques have been used for peak temperature measurements during irradiation tests by exploiting the melting point of well-characterized materials. Recent efforts to expand the capabilities of such peak temperature detection instrumentation include the development and testing of additively manufactured (AM) melt wires. In an effort to demonstrate and benchmark the performance and reliability of AM melt wires, we conducted a study to compare prototypical standard melt wires to an AM melt wire capsule, composed of printed aluminum, zinc, and tin melt wires. The lowest melting-point material used was Sn, with a melting point of approximately 230 °C, Zn melts at approximately 420 °C, and the high melting-point material was aluminum, with an approximate melting point of 660 °C. Through differential scanning calorimetry and furnace testing we show that the performance of our AM melt wire capsule was consistent with that of the standard melt-wire capsule, highlighting a path towards miniaturized peak-temperature sensors for in-pile sensor applications.

Study of Natural Convection of Lithium-Ion Battery Module Employing Phase Change Material

When the Lithium-ion battery operates at high temperature, it would bring about short circuit; if it reaches a critical temperature, it will explode. It is important to reduce its maximum temperature by appropriate heat transfer technique. When it operates without an external force for cooling, it needs natural convection technique to take away heat dissipation. Therefore, this study numerically examines three-dimensional transient natural convection of cylindrical lithium-ion batteries inside a rectangular pack with air between cylinders. The heat transfer technique in this study applies PCM (phase change material) between cylinders without or with fin array on top changing distance between cells. The results indicated that for no fin array, the package adopting the PCM could achieve the peak temperature 14.2 °C smaller than the package adopting the air. However, the package adopting the PCM with fin array vertical to the top of the package can best enhance average Nusselt number by 120% compared with using air and no fin array. Replacing the air by the PCM can keep the peak temperature of the batteries within the desirable operation range.

Kajian Karakteristik Proses Pengomposan Limbah Tanaman Jagung Yang Diberi Tambahan Kipahit Dan Pupuk Kandang Kambing

Abstrak. Limbah pertanian jagung yang belum dimanfaatkan dengan baik dapat menyebabkan timbunan limbah yang mempersempit area penanaman selanjutnya. Salah satu pemanfaatan limbah tanaman jagung adalah dengan cara dikomposkan. Pengomposan dilakukan dengan penambahan tanaman kipahit dan pupuk kandang kambing untuk mengoptimalkan proses pengomposan. Penelitian ini bertujuan mengetahui karakteristik proses pengomposan menggunakan metode berkeley. Pengamatan dilakukan pada pengondisian bahan awal kompos dengan rasio C/N 30, 35 dan 40. Penelitian mendapatkan semakin rendah penyesuaian rasio C/N awal pengomposan maka suhu puncak proses pengomposan semakin tinggi. Proses pengomposan membentuk fase termofilik dengan titik tertinggi 63,3oC pada bioreaktor A. Proses pengomposan pada bioreaktor B mengalami fase termofilik paling lama yaitu 18 hari dan reduksi volume terbanyak yaitu 78,9%. Akhir pengomposan pada bioreaktor A, B dan C menghasilkan pH yang alkali dan rasio C/N berturut-turut 13,5, 10 dan 15,5. Parameter di atas telah sesuai dengan standar baku mutu kriteria pupuk organik padat SNI 7763:2018.Characteristics Study Of Corn Waste Composting Process With Tithonia And Sheep Manure Addition Abstract. Corn waste that was not used properly into waste stack which will reduce the area of the upcoming planting. Composting is one of the ways for corn waste management. Corn waste composting is carried out by adding tithonia and goat manure to optimize the process. The objective of the study is to determine the characteristics of composting process by using the Berkeley method. The observations were undertaken at various initial composting material C/N ratio 30, 35 and 40. Base on the study result, the lower C/N ratio, the higher thermophilic peak.. The composting process forms the highest peak temperature thermophilic at 63.3oC in bioreactor A. The composting process in bioreactor B has longest thermophilic phase (18 days) and the biggest reduction (78.9%). The last characteristics were observed are composting process in bioreactor A, B and C results in alkaline pH and C/N ratio 13.5, 10, and 15.5, respectively. The parameters above have qualified SNI 7763:2018.

Wildfires as a Weathering Agent of Carbonate Rocks

While most of the scientific effort regarding wildfires has predominantly focused on fire effects on vegetation and soils, the role of fire as an essential weathering agent has been largely overlooked. This study aims to evaluate rock decay processes during wildfires, in relation to ground temperatures and rock morphologies of limestone, dolomite, and chalk. In 2010, a major forest fire in Israel caused massive destruction of the exposed rocks and accelerated rock weathering over the burned slopes. While a detailed description of the bedrock exfoliation phenomenon was previously reported, here, we conducted an experimental open fire to determine the temperature and gradients responsible for boulder shattering. The results show ground temperatures of 700 °C after 5 min from ignition, while the peak temperature (880 °C) was reached after 9 min. Temperature gradients show a rapid increase during the first 5 min (136 °C/min), moderate increase during the next 4 min (43 °C/min), and slow decrease for the next 9 min (25 °C/min). After 12 min, all boulders of all formations were cracked or completely shattered. The behaviour of carbonate rocks upon heating was studied to identify the erosive effects of fire, namely the formation of new cracks and matrix deterioration.