Algorithm for evaluating layer thickness based on electron average energy shift analysis

Author(s):  
A. Givon ◽  
E. Tiferet ◽  
I. Orion
1990 ◽  
Vol 198 ◽  
Author(s):  
F.F. So ◽  
S.R. Forrest ◽  
Y.Q. Shi ◽  
W.H. Steier

ABSTRACTMultiple quantum well structures consisting of alternating layers of two crystalline organic semiconductors, namely, 3,4,9,10 perylenetetracarboxylic dianhydride (PTCDA) and 3,4,7,8 naphthalenetetracarboxylic dianhydride (NTCDA), have been grown by organic molecular beam deposition. The layer thickness was varied from 10 to 200 Å. Birefringence measurements indicate that there is a strong structural ordering in all PrCDA layers, although the PrCDA and NTCDA crystal structures are incommensurate. From optical absorption measurements, it is found there is a blue shift in the lowest energy PICDA singlet exciton line with decreasing layer thickness. A model based on exciton quantum confinement is proposed to explain the energy shift. We have measured the low temperature photoluminescence spectra of organic quantum well structures, and found a slight red shift in the spectra with decreasing well width. These results are also discussed.


1989 ◽  
Vol 39 (9) ◽  
pp. 4599-4609 ◽  
Author(s):  
J. Oreg ◽  
W. H. Goldstein ◽  
A. Bar-Shalom ◽  
M. Klapisch

2001 ◽  
Vol 693 ◽  
Author(s):  
Gyu Gwang Sim ◽  
P. W. Yu ◽  
D. C. Reynolds ◽  
D. C. Look ◽  
Sang Soo Kim ◽  
...  

AbstractWurzite GaN epilayers on sapphire substrates usually suffer from biaxial compressive strain due to the mismatches of the thermal expansion coefficients and the lattice constants between GaN layers and sapphire substrates. We have investigated the layer thickness effects on strain and transition energies by photoluminescence (PL), photoreflectance (PR) and X-ray diffraction (XRD). Samples used in this study are grown by hydride vapor phase epitaxy (HVPE) and have the layer thickness of 0.76, 2.6, 5.3 and 48 m. The PL and PR spectra showed the redshift of the transition energies with increasing layer thickness. This is attributed to strain-induced energy shift. The layer thickness dependence of strains is directly observed by XRD. The strain along the c -axis (εzz) decreased with increasing layer thickness. This indicates the strain is relaxed with layer thickness. From strain variation with layer thickness, we suggest that strain relaxation process is rapid at the initial stage of growth and becomes slower as the layer grows. The full width at half maximum (FWHM) of PL spectra and theta rocking curves decrease with increasing layer thickness. This indicates the crystal quality improves as the strain is reduced. Since the strain effect is very small at the layer thickness of 48 μm, we expect zero strain for thicker layers that can potentially be used as substrates for homoepitaxy.


Author(s):  
О. О. Грицай ◽  
А. К. Гримало ◽  
В. В. Колотий

Author(s):  
Alain Claverie ◽  
Zuzanna Liliental-Weber

GaAs layers grown by MBE at low temperatures (in the 200°C range, LT-GaAs) have been reported to have very interesting electronic and transport properties. Previous studies have shown that, before annealing, the crystalline quality of the layers is related to the growth temperature. Lowering the temperature or increasing the layer thickness generally results in some columnar polycrystalline growth. For the best “temperature-thickness” combinations, the layers may be very As rich (up to 1.25%) resulting in an up to 0.15% increase of the lattice parameter, consistent with the excess As. Only after annealing are the technologically important semi-insulating properties of these layers observed. When annealed in As atmosphere at about 600°C a decrease of the lattice parameter to the substrate value is observed. TEM studies show formation of precipitates which are supposed to be As related since the average As concentration remains almost unchanged upon annealing.


Sign in / Sign up

Export Citation Format

Share Document