Non-linear optical study of hierarchical 3D Al doped ZnO nanosheet arrays deposited by successive ionic adsorption and reaction method

Abstract In this work, optical properties of undoped zinc oxide (ZnO) and chromium (Cr) doped ZnO prepared at different concentrations of Cr (2, 3, and 5 wt.%) on glass substrates by a spray pyrolysis method are reported. The structural properties investigated by X-ray diffraction revealed the hexagonal wurtzite structure, noting that the crystallite size of the films decreases with increasing Cr content. The optical characterization of the samples was carried out using spectral transmittance. The refractive index, energy gap, and extinction coefficient of pure and Cr-doped ZnO thin films have been calculated. The single oscillator model of Wemple–DiDomenico was used to study the dispersion of the refractive index. The oscillator parameters, the single oscillator energy, the dispersion energy, and the static refractive index were determined. The linear optical susceptibility and non-linear optical susceptibility were also studied and discussed. These promising results achieved by Cr-doping of ZnO exhibited an important behavior for technological applications in electronic, optoelectronic devices and non-linear optical applications.

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NON-LINEAR OPTICAL PROPERTIES OF A NEW ORGANIC-INORGANIC CRYSTAL : 2-AMINO-5-NITRO-PYRIDINIUM-DIHYDROGEN-PHOSPHATE (2A5NPDP)

Journal de Physique IV (Proceedings) ◽

10.1051/jp4:19917212 ◽

1991 ◽

Vol 01 (C7) ◽

pp. C7-785-C7-785

Author(s):

Z. KOTLER ◽

R. HIERLE ◽

D. JOSSE ◽

J. ZYSS ◽

R. MASSE

Keyword(s):

Optical Properties ◽

Dihydrogen Phosphate ◽

Inorganic Crystal ◽

Non Linear ◽

Linear Optical Properties ◽

Linear Optical

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Experimental and Theoretical (ab initio and DFT) Analysis of UV-Vis Spectra, Thermodynamic Functions and Non-linear Optical Properties of 2-Chloro-3,4-Dimethoxybenzaldehyde

JOURNAL OF ADVANCES IN PHYSICS ◽

10.24297/jap.v8i2.1519 ◽

2015 ◽

Vol 8 (2) ◽

pp. 2122-2134

Author(s):

Sarvendra Kumar ◽

Rajesh Kumar ◽

Jayant Teotia ◽

M. K. Yadav

Keyword(s):

Thermodynamic Functions ◽

Title Compound ◽

Density Functional ◽

Structural Characteristics ◽

Basis Sets ◽

Ultraviolet Absorption Spectrum ◽

Non Linear ◽

Different Temperatures ◽

Linear Optical Properties ◽

Linear Optical

In the present work, UV- Visible spectra of 2-Chloro-3,4-Dimethoxybenzaldehyde (2,3,4-CDMB) compoundÂ have been carried out experimentally and theoretically. The ultraviolet absorption spectrum of title compound in three solvents (Acetone, Diethyl Ether, CCl4) of different polarity were examined in the range of 200â€“500 nm. The structure of the molecule was optimized and the structural characteristics were determined by HF and DFT (B3LYP) methods with 6-31+G(d,p) and 6-311++G(d,p) as basis sets. The excitation energy, wavelength corresponds to absorption maxima () and oscillator strength (f) are calculated by Time-Dependent Density Functional Theory (TD-DFT) using B3LYP/6-31+G(d,p) and B3LYP/6-311++G(d,p) as basis sets. The electric dipole moment (Î¼), polarizability (Î±) and the first hyperpolarizability (Î² ) have been computed to evaluate the non-linear optical (NLO) response of the investigated compound by HF and DFT (B3LYP) with already mentioned basis sets. Thermodynamic functions of the title compound at different temperatures were also calculated.

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