A displacement-energy model of studying the delaminating behavior of multi-layer REBCO coated conductor tapes

2019 ◽  
Vol 560 ◽  
pp. 10-18 ◽  
Author(s):  
Stephen Ogbonna Mbam ◽  
Zhao-Fei Jiang ◽  
Xiao-Fan Gou
Author(s):  
Dominic Di Toro ◽  
Kevin P. Hickey ◽  
Herbert E. Allen ◽  
Richard F. Carbonaro ◽  
Pei C. Chiu

<div>A linear free energy model is presented that predicts the second order rate constant for the abiotic reduction of nitroaromatic compounds (NACs). For this situation previously presented models use the one electron reduction potential of the NAC reaction. If such value is not available, it has been has been proposed that it could be computed directly or estimated from the electron affinity (EA). The model proposed herein uses the Gibbs free energy of the hydrogen atom transfer (HAT) as the parameter in the linear free energy model. Both models employ quantum chemical computations for the required thermodynamic parameters. The available and proposed models are compared using second order rate constants obtained from five investigations reported in the literature in which a variety of NACs were exposed to a variety of reductants. A comprehensive analysis utilizing all the NACs and reductants demonstrate that the computed hydrogen atom transfer model and the experimental one electron reduction potential model have similar root mean square errors and residual error probability distributions. In contrast, the model using the computed electron affinity has a more variable residual error distribution with a significant number of outliers. The results suggest that a linear free energy model utilizing computed hydrogen transfer reaction free energy produces a more reliable prediction of the NAC abiotic reduction second order rate constant than previously available methods. The advantages of the proposed hydrogen atom transfer model and its mechanistic implications are discussed as well.</div>


Author(s):  
Bernhard Obst ◽  
Rainer Nast ◽  
Gunter Kotzyba ◽  
Florian Wetscher

2021 ◽  
Vol 11 (14) ◽  
pp. 6517
Author(s):  
Marta Varo-Martínez ◽  
Luis Manuel Fernández-Ahumada ◽  
Rafael López-Luque ◽  
José Ramírez-Faz

PV self-consumption can contribute positively to the spread of PV and, therefore, to the progress of renewable energies as a key element in a decarbonized energy model. However, the policies of each country regarding the promotion of this type of renewable technology is fundamental for their growth. Despite the high number of sunshine hours registered in Spain, self-consumption in this country has not been authorized until recently. In this new context, this work presents a systematic study of the profitability limits of a self-consumption PV installation under different conditions of installed peak power, orientation and inclination of the PV panels and level of obstruction of the installation. It was proved that, for the case of study (Córdoba, Spain), the maximum profitability was achieved for PV panels oriented to the south and with an inclination of 15° whereas the most unfavourable conditions are those of PV panels with an orientation and inclination of 180° and 90°, respectively. Furthermore, when the level of obstruction increases the maximum of the Net Present Value of self-consumptions PV installations decreases and this optimal value is achieved for installations with lower power. Finally, empirical adjustment equations have been developed to estimate the profitability parameters of self-consumptions PV installations as a function of their design variables.


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