Life cycle assessment of biodiesel production from free fatty acid-rich wastes

2012 ◽  
Vol 38 (1) ◽  
pp. 155-162 ◽  
Author(s):  
Javier Dufour ◽  
Diego Iribarren
2015 ◽  
Vol 26 (3) ◽  
pp. 389-406 ◽  
Author(s):  
Maria Francesca Milazzo ◽  
Francesco Spina

Purpose – The purpose of this paper is to quantify the human health impacts of soy-biodiesel production with the aim to discuss about its environmental sustainability. Design/methodology/approach – The integrated use of two current approaches, risk assessment (RA) and life cycle assessment (LCA), has allowed improvement of the potentialities of both in obtaining a more complete analysis. The implementation of a life cycle indicator for the assessment of the impacts on the human health, integrating the features of both approaches, is the main focus of this paper. Findings – It has been found that, although the biodiesel is a green fuel, it has some criticalities in its life cycle, which cannot be disregarded. In fact, even if biodiesel is essentially a clean fuel there are some phases, prior to the industrial phase, that can cause negative effects on human health and ecosystems. Practical implications – Results suggest some measures which can be adopted to substantially reduce human health impacts. Further alternative could be analysed in future to gain more insight about the use of biodiesel fuels. Originality/value – The estimation of the impacts of a process producing biodiesel has been made by using a novel approach. The novelty is associated with the calculation of the impacts on human health by using the transfer factors applied in RA. The use of such factors, properly modified in order to estimate the impacts on a wider scale than a site-dimension, allows defining a holistic approach, as LCA and RA are used as complete units but at the same time can be related to each other.


2018 ◽  
Vol 156 ◽  
pp. 03002
Author(s):  
Iwan Ridwan ◽  
Mukhtar Ghazali ◽  
Adi Kusmayadi ◽  
Resza Diwansyah Putra ◽  
Nina Marlina ◽  
...  

The oleic acid solubility in methanol is low due to two phase separation, and this causes a slow reaction time in biodiesel production. Tetrahydrofuran as co-solvent can decrease the interfacial surface tension between methanol and oleic acid. The objective of this study was to investigate the effect of co-solvent, methanol to oleic acid molar ratio, catalyst amount, and temperature of the reaction to the free fatty acid conversion. Oleic acid esterification was conducted by mixing oleic acid, methanol, tetrahydrofuran and Amberlyst 15 as a solid acid catalyst in a batch reactor. The Amberlyst 15 used had an exchange capacity of 2.57 meq/g. Significant free fatty acid conversion increments occur on biodiesel production using co-solvent compared without co-solvent. The highest free fatty acid conversion was obtained over methanol to the oleic acid molar ratio of 25:1, catalyst use of 10%, the co-solvent concentration of 8%, and a reaction temperature of 60°C. The highest FFA conversion was found at 28.6 %, and the steady state was reached after 60 minutes. In addition, the use of Amberlyst 15 oleic acid esterification shows an excellent performance as a solid acid catalyst. Catalytic activity was maintained after 4 times repeated use and reduced slightly in the fifth use.


2014 ◽  
Vol 625 ◽  
pp. 897-900 ◽  
Author(s):  
Junaid Ahmad ◽  
Suzana Yusup ◽  
Awais Bokhari ◽  
Ruzaimah Nik Mohammad Kamil

Energy crises, depletion of fossil fuel reservoirs, environmental pollution, global warming, green house effect and starvation are becoming very serious problems in the modern world. Biodiesel is a liquid fuel which can be the best alternative for the fossil fuels. In this study, non-edible rubber seed oil (RSO) with high free fatty acid (FFA) content (45%) was used for the production of biodiesel. The process comprises of two steps, in the first step acid esterification was used to reduce the FFA and in the second step base transesterification was employed to convert the treated oil into rubber seed oil methyl esters (RSOMEs). The conversion yield of biodiesel was analyzed using gas chromatography. The fuel properties were tested using the standard procedure of ASTM D6751 and EN14214. All the properties were within the ranges of the biodiesel standards. The result shows that rubber seed oil is a potential non-edible source for biodiesel production.


2010 ◽  
Vol 24 (7) ◽  
pp. 4062-4077 ◽  
Author(s):  
Anna L. Stephenson ◽  
Elena Kazamia ◽  
John S. Dennis ◽  
Christopher J. Howe ◽  
Stuart A. Scott ◽  
...  

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