A comparison of solar photovoltaics and molten carbonate fuel cells as commercial power plants

2011 ◽  
Vol 15 (1) ◽  
pp. 697-704 ◽  
Author(s):  
Jung-Ho Wee ◽  
Jae Hyung Roh ◽  
Jeongin Kim
Author(s):  
Maurizio Spinelli ◽  
Stefano Campanari ◽  
Stefano Consonni ◽  
Matteo C. Romano ◽  
Thomas Kreutz ◽  
...  

The state-of-the-art conventional technology for postcombustion capture of CO2 from fossil-fueled power plants is based on chemical solvents, which requires substantial energy consumption for regeneration. A promising alternative, available in the near future, is the application of molten carbonate fuel cells (MCFC) for CO2 separation from postcombustion flue gases. Previous studies related to this technology showed both high efficiency and high carbon capture rates, especially when the fuel cell is thermally integrated in the flue gas path of a natural gas-fired combined cycle or an integrated gasification combined cycle plant. This work compares the application of MCFC-based CO2 separation process to pulverized coal fired steam cycles (PCC) and natural gas combined cycles (NGCC) as a “retrofit” to the original power plant. Mass and energy balances are calculated through detailed models for both power plants, with fuel cell behavior simulated using a 0D model calibrated against manufacturers' specifications and based on experimental measurements, specifically carried out to support this study. The resulting analysis includes a comparison of the energy efficiency and CO2 separation efficiency as well as an economic comparison of the cost of CO2 avoided (CCA) under several economic scenarios. The proposed configurations reveal promising performance, exhibiting very competitive efficiency and economic metrics in comparison with conventional CO2 capture technologies. Application as a MCFC retrofit yields a very limited (<3%) decrease in efficiency for both power plants (PCC and NGCC), a strong reduction (>80%) in CO2 emission and a competitive cost for CO2 avoided (25–40 €/ton).


Author(s):  
Maurizio Spinelli ◽  
Stefano Campanari ◽  
Matteo C. Romano ◽  
Stefano Consonni ◽  
Thomas G. Kreutz ◽  
...  

The state-of-the-art conventional technology for post combustion capture of CO2 from fossil-fuelled power plants is based on chemical solvents, which requires substantial energy consumption for regeneration. Apromising alternative, available in the near future, is the application of Molten Carbonate Fuel Cells (MCFC) for CO2 separation from post-combustion flue gases. Previous studies related to this technology showed both high efficiency and high carbon capture rates, especially when the fuel cell is thermally integrated in the flue gas path of a natural gas-fired combined cycle or an integrated gasification combined cycle plant. This work compares the application of MCFC based CO2 separation process to pulverized coal fired steam cycles (PCC) and natural gas combined cycles (NGCC) as a ‘retrofit’ to the original power plant. Mass and energy balances are calculated through detailed models for both power plants, with fuel cell behaviour simulated using a 0D model calibrated against manufacturers’ specifications and based on experimental measurements, specifically carried out to support this study. The resulting analysis includes a comparison of the energy efficiency and CO2 separation efficiency as well as an economic comparison of the cost of CO2 avoided under several economic scenarios. The proposed configurations reveal promising performance, exhibiting very competitive efficiency and economic metrics in comparison with conventional CO2 capture technologies. Application as a MCFC retrofit yields a very limited (<3%) decrease in efficiency for both power plants (PCC and NGCC), a strong reduction (>80%) in CO2 emission and a competitive cost for CO2 avoided (25–40 €/ton).


Author(s):  
Suping Peng

AbstractCoal has been the main energy source in China for a long period. Therefore, the energy industry must improve coal power generation efficiency and achieve near-zero CO2 emissions. Integrated gasification fuel cell (IGFC) systems that combine coal gasification and high-temperature fuel cells, such as solid oxide fuel cells or molten carbonate fuel cells (MCFCs), are proving to be promising for efficient and clean power generation, compared with traditional coal-fired power plants. In 2017, with the support of National Key R&D Program of China, a consortium led by the China Energy Group and including 12 institutions was formed to develop the advanced IGFC technology with near-zero CO2 emissions. The objectives of this project include understanding the performance of an IGFC power generation system under different operating conditions, designing master system principles for engineering optimization, developing key technologies and intellectual property portfolios, setting up supply chains for key materials and equipment, and operating the first megawatt IGFC demonstration system with near-zero CO2 emission, in early 2022. In this paper, the main developments and projections pertaining to the IGFC project are highlighted.


Author(s):  
Umberto Desideri

This paper presents the state of the art and the perspectives of the use of molten carbonate fuel cells with renewable energy sources. The molten carbonate fuel cell is the only technology that can use fuels containing carbon monoxide and carbon dioxide in the anode gas. It has been even shown in experimental tests in single cells that carbon monoxide can be considered as a fuel in this type of fuel cell. The fuels that can be used in MCFC are landfill gas, biogas from anaerobic digestion processes and syngas from gasification of biomass and waste. The commercial size of MCFC stacks (125 to 250 kW) is the right size for use with such fuels which are generally not available for power plants with output larger than some MW. All the above fuels are characterized by the presence of contaminants that need be removed before their use in the fuel cell. Among the contaminants hydrogen sulfide and chlorine compounds seem to cause the worst damage. To be used with such fuels, MCFC still need to be deeply investigated and duration tests are needed to determine the highest tolerable concentrations in the anode gases.


2017 ◽  
Vol 42 (25) ◽  
pp. 16235-16243 ◽  
Author(s):  
Mihui Lee ◽  
Chang-Whan Lee ◽  
Hyung-Chul Ham ◽  
Jonghee Han ◽  
Sung Pil Yoon ◽  
...  

Author(s):  
K. Hemmes ◽  
M. Houwing ◽  
N. Woudstra

Direct carbon fuel cells (DCFCs) have great thermodynamic advantages over other high temperature fuel cells such as molten carbonate fuel cells (MCFCs) and solid oxide fuel cells. They can have 100% fuel utilization, no Nernst loss (at the anode), and the CO2 produced at the anode is not mixed with other gases and is ready for re-use or sequestration. So far, only studies have been reported on cell development. In this paper, we study the performance of a CO2-producing DCFC system model. The theoretically predicted advantages that are confirmed on a bench scale are also confirmed on a system level, except for the production of pure CO2. Net system efficiencies of around 78% were found for the developed system. An exergy analysis of the system shows where the losses in the system occur. If the cathode of the DCFC must be operated as a standard MCFC cathode, the required CO2 at the cathode is the reason why a large part of the pure CO2 from the anode is recycled and mixed with the incoming air and cannot be used directly for sequestration. Bench scale studies should be performed to test the minimum amount of CO2 needed at the cathode. This might be lower than in a standard MCFC operation due to the pure CO2 at the anode side that enhances diffusion toward the cathode.


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