Net deposition of mercury to the Antarctic Plateau enhanced by sea salt

2017 ◽  
Vol 583 ◽  
pp. 81-87 ◽  
Author(s):  
Yeongcheol Han ◽  
Youngsook Huh ◽  
Soon Do Hur ◽  
Sungmin Hong ◽  
Ji Woong Chung ◽  
...  
Keyword(s):  
Sea Salt ◽  
Antarctic Plateau ◽  
The Antarctic

scholarly journals The Weddell Sea region: an important precipitation channel to the interior of the Antarctic ice sheet as revealed by glaciochemical investigation of surface snow along the longest trans-Antarctic route

1999 ◽  
Vol 29 ◽  
pp. 55-60 ◽  
Author(s):  
Qin Dahe ◽  
Paul A. Mayewski ◽  
Ren Jiawen ◽  
Xiao Cunde ◽  
Sun Junying
Keyword(s):  
Ice Sheet ◽  
Weddell Sea ◽  
Sea Salt ◽  
East Antarctica ◽  
Antarctic Ice Sheet ◽  
Air Masses ◽  
Antarctic Plateau ◽  
Salt Ions ◽  
Surface Snow ◽  
The Antarctic

AbstractGlaciochemical analysis of surface snow samples, collected along a profile crossing the Antarctic ice sheet from the Larsen Ice Shelf, Antarctic Peninsula, via the Antarctic Plateau through South Pole, Vostok and Komsomolskaya to Mirny station (at the east margin of East Antarctica), shows that the Weddell Sea region is an important channel for air masses to the high plateau of the Antarctic ice sheet (>2000 m a.s.l.). This opinion is supported by the following. (1) The fluxes of sea-salt ions such as Na+, Mg2 + and CF display a decreasing trend from the west to the east of interior Antarctica. In |eneral, as sea-salt aerosols are injected into the atmosphere over the Antarctic ice sheet from the Weddell Sea, large aerosols tend to decrease. For the inland plateau, few large particles of sea-salt aerosol reach the area, and the sea-salt concentration levels are low (2) The high altitude of the East Antarctic plateau, as well as the polar cold high-pressure system, obstruct the intrusive air masses mainly from the South Indian Ocean sector. (3) For the coastal regions of the East Antarctic ice sheet, the elevation rises to 2000 m over a distance from several to several tens of km. High concentrations of sea salt exist in snow in East Antarctica but are limited to a narrow coastal zone. (4) Fluxes of calcium and non-sea-salt sulfate in snow from the interior plateau do not display an eastward-decreasing trend. Since calcium is mainly derived from crustal sources, and nssSO42- is a secondary aerosol, this again confirms that the eastward-declining tendency of sea-salt ions indicates the transfer direction of precipitation vapor.

scholarly journals Year-round record of bulk and size-segregated aerosol composition in central Antarctica (Concordia site) Part 2: Biogenic sulfur (sulfate and methanesulfonate) aerosol

2017 ◽  
Author(s):  
Michel Legrand ◽  
Susanne Preunkert ◽  
Rolf Weller ◽  
Lars Zipf ◽  
Christoph Elsässer ◽  
...  
Keyword(s):  
Southern Ocean ◽  
Ice Cores ◽  
Photochemical Activity ◽  
Sea Salt ◽  
Aerosol Composition ◽  
Antarctic Plateau ◽  
Chemical Destruction ◽  
The Antarctic ◽  
The Relationship ◽  
Ozone Levels

Abstract. Multiple year-round (2006–2015) records of the bulk and size-segregated composition of aerosol were obtained at the inland site of Concordia located in East Antarctica. The well-marked maximum of non-sea-salt sulfate (nssSO4) in January (84 ± 25 ng m−3 against 4.4 ± 2.3 ng m−3 in July) is consistent with observations made at the coast (280 ± 78 ng m−3 in January against 16 ± 9 ng m−3 in July at Dumont d’Urville, for instance). In contrast, the well-marked maximum of MSA at the coast in January (60 ± 23 ng m−3 at Dumont d’Urville) is not observed at Concordia (4.6 ± 2.4 ng m−3 in January). Instead, the MSA level at Concordia peaks in October (5.6 ± 1.9 ng m−3) and March (13.2 ± 6.1 ng m−3). As a result, a surprisingly low MSA to nssSO4 ratio (RMSA) is observed at Concordia in mid-summer (0.05 ± 0.02 in January against 0.25 ± 0.09 in March). We find that the low value of RMSA in mid-summer at Concordia is mainly driven by a drop of MSA levels that takes place in submicron aerosol (0.3 µm diameter). The drop of MSA coincides with periods of high photochemical activity as indicated by high ozone levels, strongly suggesting the occurrence of an efficient chemical destruction of MSA over the Antarctic plateau in mid-summer. The relationship between MSA and nssSO4 levels is examined separately for each season and indicates that concentration of non-biogenic sulfate over the Antarctic plateau does not exceed 1 ng m−3 in fall and winter and remains below 5 ng m−3 in spring. This weak non-biogenic sulfate level is discussed in the light of radionuclides (210Pb, 10Be, and 7Be) also measured on bulk aerosol samples collected at Concordia. The findings highlight the complexity in using MSA in deep ice cores extracted from inland Antarctica as a proxy of past DMS emissions from the southern ocean.

scholarly journals Spatial and Temporal Variations of Snow Chemistry in Terre Adélie (East Antarctica)

1985 ◽  
Vol 7 ◽  
pp. 20-25 ◽  
Author(s):  
Michel Legrand ◽  
Robert J. Delmas
Keyword(s):  
Ion Chromatography ◽  
Temporal Variations ◽  
Sea Salt ◽  
East Antarctica ◽  
Snow Chemistry ◽  
Antarctic Plateau ◽  
Time Period ◽  
Terre Adélie ◽  
The Mean ◽  
The Antarctic

The chemistry of recently deposited snow sampled in 1982–83 along a 430 km coast-interior traverse in Terre Adelie, East Antarctica, is reported. In addition, three firn samples, covering the same time period (1959 to 1969) and collected on the traverse at D 55, D 80 and Dome C stations, respectively at 200, 430 and 1070 km from the sea, are also studied. Concentrations of major soluble impurities (H+, , Na+, K+, Cl−, and ) were determined by ion chromatography (except H+ which was titrated) on more than 200 samples. Conditions of sampling and analysis were carefully controlled in order to avoid contamination problems. A balanced ionic budget was generally obtained for each of the samples. For stations occupying an intermediary position between the coastal areas and the central Antarctic plateau, our results demonstrate that the two major impurities are H2SO4 and HNO3. HCl is also present, but at a lower level of concentration; the sea-salt contribution is dominant only at the most coastal sites (within 40 km) of the sea. The degree of neutralization of the snow acidity by NH3 is always very low as indicated by the values of content. The mean concentrations of H2SO4 along the traverse are relatively constant whereas an increase of the HNO3 concentrations is observed when going inland. It decreases, however, in most central areas. These results are discussed in relation to the glaciochemical data published for other locations on the Antarctic plateau, in particular the sulphate concentrations which depend strongly on explosive volcanic activity.

scholarly journals Spatial and Temporal Variations of Snow Chemistry in Terre Adélie (East Antarctica)

1985 ◽  
Vol 7 ◽  
pp. 20-25 ◽  
Author(s):  
Michel Legrand ◽  
Robert J. Delmas
Keyword(s):  
Ion Chromatography ◽  
Temporal Variations ◽  
Sea Salt ◽  
East Antarctica ◽  
Snow Chemistry ◽  
Antarctic Plateau ◽  
Time Period ◽  
Terre Adélie ◽  
The Mean ◽  
The Antarctic

The chemistry of recently deposited snow sampled in 1982–83 along a 430 km coast-interior traverse in Terre Adelie, East Antarctica, is reported. In addition, three firn samples, covering the same time period (1959 to 1969) and collected on the traverse at D 55, D 80 and Dome C stations, respectively at 200, 430 and 1070 km from the sea, are also studied. Concentrations of major soluble impurities (H+, , Na+, K+, Cl−, and ) were determined by ion chromatography (except H+ which was titrated) on more than 200 samples. Conditions of sampling and analysis were carefully controlled in order to avoid contamination problems. A balanced ionic budget was generally obtained for each of the samples. For stations occupying an intermediary position between the coastal areas and the central Antarctic plateau, our results demonstrate that the two major impurities are H2SO4 and HNO3. HCl is also present, but at a lower level of concentration; the sea-salt contribution is dominant only at the most coastal sites (within 40 km) of the sea. The degree of neutralization of the snow acidity by NH3 is always very low as indicated by the values of content. The mean concentrations of H2SO4 along the traverse are relatively constant whereas an increase of the HNO3 concentrations is observed when going inland. It decreases, however, in most central areas. These results are discussed in relation to the glaciochemical data published for other locations on the Antarctic plateau, in particular the sulphate concentrations which depend strongly on explosive volcanic activity.

scholarly journals Year-round record of bulk and size-segregated aerosol composition in central Antarctica (Concordia site) – Part 2: Biogenic sulfur (sulfate and methanesulfonate) aerosol

2017 ◽  
Vol 17 (22) ◽  
pp. 14055-14073 ◽  
Author(s):  
Michel Legrand ◽  
Susanne Preunkert ◽  
Rolf Weller ◽  
Lars Zipf ◽  
Christoph Elsässer ◽  
...  
Keyword(s):  
Dimethyl Sulfide ◽  
Ice Cores ◽  
Photochemical Activity ◽  
Sea Salt ◽  
Aerosol Composition ◽  
Antarctic Plateau ◽  
Chemical Destruction ◽  
The Antarctic ◽  
The Relationship ◽  
Ozone Levels

Abstract. Multiple year-round (2006–2015) records of the bulk and size-segregated composition of aerosol were obtained at the inland site of Concordia located in East Antarctica. The well-marked maximum of non-sea-salt sulfate (nssSO4) in January (100 ± 28 ng m−3 versus 4.4 ± 2.3 ng m−3 in July) is consistent with observations made at the coast (280 ± 78 ng m−3 in January versus 16 ± 9 ng m−3 in July at Dumont d'Urville, for instance). In contrast, the well-marked maximum of MSA at the coast in January (60 ± 23 ng m−3 at Dumont d'Urville) is not observed at Concordia (5.2 ± 2.0 ng m−3 in January). Instead, the MSA level at Concordia peaks in October (5.6 ± 1.9 ng m−3) and March (14.9 ± 5.7 ng m−3). As a result, a surprisingly low MSA-to-nssSO4 ratio (RMSA) is observed at Concordia in mid-summer (0.05 ± 0.02 in January versus 0.25 ± 0.09 in March). We find that the low value of RMSA in mid-summer at Concordia is mainly driven by a drop of MSA levels that takes place in submicron aerosol (0.3 µm diameter). The drop of MSA coincides with periods of high photochemical activity as indicated by high ozone levels, strongly suggesting the occurrence of an efficient chemical destruction of MSA over the Antarctic plateau in mid-summer. The relationship between MSA and nssSO4 levels is examined separately for each season and indicates that concentration of non-biogenic sulfate over the Antarctic plateau does not exceed 1 ng m−3 in fall and winter and remains close to 5 ng m−3 in spring. This weak non-biogenic sulfate level is discussed in the light of radionuclides (210Pb, 10Be, and 7Be) also measured on bulk aerosol samples collected at Concordia. The findings highlight the complexity in using MSA in deep ice cores extracted from inland Antarctica as a proxy of past dimethyl sulfide emissions from the Southern Ocean.

scholarly journals The growth of sublimation crystals and surface hoar on the Antarctic plateau

2014 ◽  
Vol 8 (4) ◽  
pp. 1205-1215 ◽  
Author(s):  
J.-C. Gallet ◽  
F. Domine ◽  
J. Savarino ◽  
M. Dumont ◽  
E. Brun
Keyword(s):  
Energy Budget ◽  
Temperature Drop ◽  
Snow Surface ◽  
Surface Mass ◽  
Antarctic Plateau ◽  
Time Variations ◽  
Sunny Weather ◽  
Frost Flowers ◽  
Snow Model ◽  
The Antarctic

Abstract. On the Antarctic plateau, precipitation quantities are so low that the surface mass budget is for an important part determined by exchanges of water vapor between the snow surface and the atmosphere surface. At Dome C (75° S, 123° E), we have frequently observed the growth of crystals on the snow surface under calm sunny weather. Here we present the time variations of specific surface area (SSA) and density of these crystals. Using the detailed snow model Crocus, we conclude that the formation of these crystals was very likely due to the nighttime formation of surface hoar crystals and to the daytime formation of sublimation crystals. These latter crystals form by processes similar to those involved in the formation of frost flowers on young sea ice. The formation of these crystals impacts the albedo, mass and energy budget of the Antarctic plateau. In particular, the SSA variations of the surface layer can induce an instantaneous forcing at the snow surface up to −10 W m−2 at noon, resulting in a surface temperature drop of 0.45 K. This result confirms that snow SSA is a crucial variable to consider in the energy budget and climate of snow-covered surfaces.

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