Assessing the importance of nonlinearity for aircraft emissions' impact on O3 and PM2.5

ABSTRACTThe International Civil Aviation Organization (ICAO) Circular Cir 337 is the first step towards ICAO establishing an Aeroplane CO2Emissions Standard to form part of Annex 16, Volume III to the Chicago Convention. It describes itself as ‘a work in progress’. This paper reviews Cir 337 against the background of flight physics, the published literature on aircraft fuel burn and CO2emissions and the current practices of the aircraft and engine manufacturers and the airline operators. We have taken, as our starting point, the aim of ICAO to reduce the fuel used per revenue tonne-kilometre performed and argue that the Breguet range equation, which captures all the relevant flight physics, should be the basis of the metric system underpinning the standard. Our overall conclusion is that Cir 337 provides an excellent basis for the initial regulation of aviation's CO2emissions and, further in the future, for developing measures to increase the fuel efficiency of the operational side of civil aviation. Our main criticism of the circular in its current form is that it does not address the ICAO goal of reducingfuel used per revenue tonne-kilometre performedand makes no reference to payload. This defect could be eliminated simply by omission of the exponent 0.24 of the Reference Geometric Factor (RGF) in the formula for the metric given in Chapter 2 (paragraph 2.2) of the circular. Retaining theRGFto the power unity in the metric and multiplying it by an appropriate value of the effective floor loading would convert it to what the 37thAssembly of ICAO called for – a statement of fuel used per revenue tonne-kilometre performed. Finally, correlating the amended metric against design range, as determined from the measured specific air range and the key certificated masses, provides a sound scientific basis for an initial regulation to cap passenger aircraft emissions.

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Passenger aircraft emissions analysis at Ordu-Giresun International Airport, Turkey in 2017

Aircraft Engineering and Aerospace Technology ◽

10.1108/aeat-09-2020-0209 ◽

2021 ◽

Vol ahead-of-print (ahead-of-print) ◽

Author(s):

Ilkay Orhan

Keyword(s):

Aircraft Engine ◽

Civil Aviation ◽

Exhaust Emission ◽

Aircraft Emissions ◽

Emission Data ◽

Emission Analysis ◽

Content Type ◽

International Airport ◽

Engine Emission ◽

The Impact

Purpose The purpose of this study is to present the pollutant gas produced by hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx) and the quantity of fuel burned from commercial aircraft at Ordu-Giresun International Airport, Turkey during the landing and take-off (LTO) cycles in 2017. Design/methodology/approach The flight data recorded by the General Directorate of State Airports Authority and the aircraft engine emission data from International Civil Aviation Organization (ICAO) Engine Exhaust Emission Databank were used for calculation. The aircraft and engine types used by the airlines for flight at Ordu-Giresun International Airport were determined. To evaluate the effect of taxi time on emission amounts, analysis and evaluations were made by taking different taxi times into consideration. Findings As a result of the emission analysis, the amount of fuel consumed by the aircraft were calculated as 6,551.52 t/y, and the emission amounts for CO, HC and NOx were estimated as 66.81, 4.20 and 79.97 t/y, respectively. Practical implications This study is aimed to reveal the effect and contribution of taxi time on the emitted emission at the airport during the LTO phase of the aircraft. Originality/value This study helps aviation authorities explain the importance of developing procedures that ensure the delivery of aircraft to flights in minimum time by raising awareness of the impact of taxi time on emitted emissions, and contributes to the determination of an aircraft emission inventory at Ordu-Giresun International Airport.

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Qualitative and Quantitative Characterization of Airport-related Ultrafine Particles using Liquid Chromatography – High-Resolution Mass Spectrometry (UHPLC/HRMS)

10.5194/egusphere-egu21-7777 ◽

2021 ◽

Author(s):

Florian Ungeheuer ◽

Diana Rose ◽

Dominik van Pinxteren ◽

Florian Ditas ◽

Stefan Jacobi ◽

...

Keyword(s):

Chemical Composition ◽

Ultrafine Particles ◽

Chemical Characterization ◽

Engine Oil ◽

Aircraft Emissions ◽

Jet Engine ◽

Qualitative And Quantitative ◽

Ionization Mode ◽

Lubrication Oils

We present the results from a chemical characterization study of ultrafine particles (UFP), collected nearby Frankfurt International Airport where particle size distribution measurements showed high number concentrations for particles with a diameter <50 nm. Aluminium filter samples were collected at an air quality monitoring station in a distance of 4 km to Frankfurt airport, using the 13-stage cascade impactor Nano-MOUDI (MSP Model-115). The chemical characterization of the ultrafine particles in the size range of 0.010-0.018 &#956;m, 0.018-0.032 &#956;m and 0.032-0.056 &#956;m was accomplished by the development of an optimized filter extraction method. An UHPLC method for chromatographic separation of homologous series of hydrophobic and high molecular weight organic compounds, followed by heated electrospray ionization (ESI) and mass analysis using an Orbitrap high-resolution mass spectrometer was developed. Using a non-target screening, ~200 compounds were detected in the positive ionization mode after filtering, in order to ensure high quality of the obtained data. We determined the molecular formula of positively charged adducts ([M+H]+; [M+Na]+), and for each impaction stage we present molecular fingerprints (Molecular weight vs Retention time, Kroll-diagram, Van-Krevelen-diagram, Kendrick mass defect plot) in order to visualize the complex chemical composition. The negative ionization mode led only to the detection of a few compounds (<20) for which reason the particle characterization focuses on the positive ionization mode. We found that the majority of detected compounds belong to homologous series of two different kinds of organic esters, which are base stocks of aircraft lubrication oils. In reference to five different jet engine lubrication oils of various manufacturers, we identified the corresponding lubricant base stocks and their additives in the ultrafine particles by the use of matching retention time, exact mass and MS/MS fragmentation pattern of single organic molecules. As the relevance of the chemical composition of UFP regarding human health is depending on the mass contribution of each compound we strived for quantification of the jet engine oil compounds. This was achieved by standard addition of purchased original standards to the native sample extracts. Two amines serving as stabilizers, one organophosphate used as an anti-wear agent/metal deactivator and two ester base stocks were quantified. Quantification of the two homologous ester series was carried out using one ester compound and cross-calibration. The quantitative determination is burdened by the uncertainty regarding sampling artefacts in the Nano-MOUDI. Therefore we characterized the cascade impactor in a lab experiment using the ester standard. Particle size distribution measurements conducted parallel to the filter sampling enables the determination of jet engine oil contribution to the UFP mass. Results indicate that aircraft emissions strongly influence the mass balance of 0.010-0.018 &#956;m particles. This contribution decreases for bigger sized particles (0.018-0.056 &#956;m) as presumably more sources get involved. The hereby-introduced method allows the qualitative and quantitative assignment of aircraft emissions towards the chemical composition and total mass of airport related ultrafine particles.

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