Hot corrosion of different alloys in chloride and carbonate molten-salt mixtures under argon atmosphere

Solar Energy ◽  
2019 ◽  
Vol 189 ◽  
pp. 254-267 ◽  
Author(s):  
Xiaoru Zhuang ◽  
Wenrui Liu ◽  
Xinhai Xu
2021 ◽  
Vol 168 (2) ◽  
pp. 026502
Author(s):  
R. L. Fitzhugh ◽  
A. D. Clark ◽  
S. D. Nickerson ◽  
M. J. Memmott ◽  
J. N. Harb

2019 ◽  
Vol 39 (4) ◽  
pp. 1496-1506 ◽  
Author(s):  
Lei Guo ◽  
Chenglong Zhang ◽  
Qing He ◽  
Zhihua Li ◽  
Jianxing Yu ◽  
...  

1970 ◽  
Vol 3 (2) ◽  
pp. 77-82 ◽  
Author(s):  
TS Sidhu ◽  
S Prakash ◽  
RD Agrawal

The present study aims to evaluate the hot corrosion behaviour of the Ni-based alloy Superni- 75 in the molten salt environment of Na2SO-60%V2O5 at 900°C under cyclic conditions. The thermogravimetric technique was used to establish the kinetics of corrosion. X-ray diffraction, scanning electron microscopy/energy-dispersive analysis and electron probe microanalysis techniques were used to analyse the corrosion products. Superni-75 has successfully provided the hot corrosion resistance to the given molten salt environment. The hot corrosion resistance of the Superni-75 has been attributed to the formation of uniform, homogeneous and adherent thick layer of the scale consisting mainly of oxides of nickel and chromium, and refractory Ni(VO3)2. These oxides and refractory nickel vanadates have blocked the penetration of oxygen and other corrosive species to the substrate. Keywords: Hot corrosion, nickel-based alloy, superalloy, molten salt environment   DOI: 10.3329/jname.v3i2.922 Journal of Naval Architecture and Marine Engineering 3(2006) 77-82


2018 ◽  
Vol 8 (8) ◽  
pp. 1305 ◽  
Author(s):  
Hyun Kim ◽  
Byeongnam Jo

An anomalous increase of the specific heat was experimentally observed in molten salt nanofluids using a differential scanning calorimeter. Binary carbonate molten salt mixtures were used as a base fluid, and the base salts were doped with graphite nanoparticles. Specific heat measurements of the nanofluids were performed to examine the effects of the composition of two salts consisting of the base fluid. In addition, the effect of the nanoparticle concentration was investigated as the concentration of the graphite nanoparticles was varied from 0.025 to 1.0 wt %. Moreover, the dispersion homogeneity of the nanoparticles was explored by increasing amount of surfactant in the synthesis process of the molten salt nanofluids. The results showed that the specific heat of the nanofluid was enhanced by more than 30% in the liquid phase and by more than 36% in the solid phase at a nanoparticle concentration of 1 wt %. It was also observed that the concentration and the dispersion homogeneity of nanoparticles favorably affected the specific heat enhancement of the molten salt nanofluids. The dispersion status of graphite nanoparticles into the salt mixtures was visualized via scanning electron microscopy. The experimental results were explained according to the nanoparticle-induced compressed liquid layer structure of the molten salts.


2011 ◽  
Vol 383-390 ◽  
pp. 4688-4692
Author(s):  
Ramkumar K. Devendranath ◽  
N. Arivazhagan ◽  
S Narayanan

An attempt was made to study the hot corrosion behavior on gas tungeten arc welded Austenitic stainless steel AISI 304 and Nickel-copper alloy Monel 400. These materials are widely used in power plant, petro-chemical and marine applications where the weldments are usually subjected to aggressive corrosion environment. GTA welding was carried out using ENiCu-7 and E308L filler wires. Various regions of the weldment of AISI 304, Monel 400 were exposed to the air oxidation as well as in the molten salt environment consist of K2SO4 + NaCl (60%) at 700°C. Mechanical properties of the weldments were also studied. The corrosion products of the weldments were analyzed using SEM/EDAX, XRD analysis.


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