Red and near-infrared absorption enhancement for low bandgap polymer solar cells by combining the optical microcavity and optical spacers

2011 ◽  
Vol 95 (12) ◽  
pp. 3400-3407 ◽  
Author(s):  
Yongbing Long
2019 ◽  
Vol 7 (8) ◽  
pp. 3745-3751 ◽  
Author(s):  
Juan Chen ◽  
Guangda Li ◽  
Qinglian Zhu ◽  
Xia Guo ◽  
Qunping Fan ◽  
...  

Non-fullerene polymer solar cells based on a low bandgap polymer PTB7-Th and an ultra-narrow bandgap acceptor ACS8 exhibited an optimal PCE of 13.2%, indicating that the blend of PTB7-Th/ACS8 has potential for the practical applications of PSCs.


2006 ◽  
Vol 18 (16) ◽  
pp. 2169-2173 ◽  
Author(s):  
F. Zhang ◽  
W. Mammo ◽  
L. M. Andersson ◽  
S. Admassie ◽  
M. R. Andersson ◽  
...  

2016 ◽  
Vol 8 (6) ◽  
pp. 1-12 ◽  
Author(s):  
Ning Li ◽  
Dazheng Chen ◽  
Chunfu Zhang ◽  
Jingjing Chang ◽  
Zhenhua Lin ◽  
...  

2017 ◽  
Vol 5 (43) ◽  
pp. 22588-22597 ◽  
Author(s):  
Xiaojun Li ◽  
Tinghai Yan ◽  
Haijun Bin ◽  
Guangchao Han ◽  
Lingwei Xue ◽  
...  

A low bandgap n-OS molecule SJ-IC was synthesized by inserting double bond π-bridges between the donor and acceptor units of IDT-IC, and SJ-IC as an acceptor shows broad absorption and improved photovoltaic performance when using a broad bandgap polymer J61 as a donor.


2017 ◽  
Vol 10 (7) ◽  
pp. 1610-1620 ◽  
Author(s):  
Yongxi Li ◽  
Lian Zhong ◽  
Bhoj Gautam ◽  
Hai-Jun Bin ◽  
Jiu-Dong Lin ◽  
...  

Low-bandgap polymers/molecules are an interesting family of semiconductor materials, and have enabled many recent exciting breakthroughs in the field of organic electronics, especially for organic photovoltaics (OPVs).


2019 ◽  
Vol 7 (42) ◽  
pp. 13301-13306 ◽  
Author(s):  
Hua Tan ◽  
Xiangjun Zheng ◽  
Jianing Zhu ◽  
Junting Yu ◽  
Weiguo Zhu

An A–D–D–A-type near-infrared non-fullerene small-molecule acceptor IDT2-DFIC with indacenodithiophene–indacenodithiophene (IDT2) as donating core and 2-(5,6-difluoro-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile (2FIC) as electron withdrawing end groups has been synthesized.


2008 ◽  
Vol 80 (10) ◽  
pp. 2151-2161 ◽  
Author(s):  
Sergey A. Zapunidy ◽  
Dmitry S. Martyanov ◽  
Elena M. Nechvolodova ◽  
Marina V. Tsikalova ◽  
Yuri N. Novikov ◽  
...  

Polymer solar cells have shown high potential to convert solar energy into electricity in a cost-effective way. One of the basic reasons limiting the polymer solar cell efficiency is insufficient absorption of the solar radiation by the active layer that limits the photocurrent. To increase the photocurrent, one needs low-bandgap materials with strong absorption below 2 eV. In this work, we study two types of low-bandgap materials: ground-state charge-transfer complexes (CTCs) of a conjugated polymer, MEH-PPV (poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylenevinylene]), and an exohedral metallocomplex of fullerene, (η2-C60)IrH(CO)[(+)DIOP] (IrC60). We demonstrate that the CTC formed between MEH-PPV and conjugated molecules with high electron affinity, namely, 2,4,7-trinitrofluorenone (TNF) and 1,5-dinitroantraquinone (DNAQ), can have strong optical absorption extending down to the near infrared. We have observed that the photoexcited CTC can generate free charges. We also report on optical studies of IrC60 as a possible acceptor for polymer/fullerene solar cells. IrC60 strongly absorbs in the visible spectral range, in particular in the red part, and therefore has a potential for increasing the photocurrent as compared with polymer/methanofullerene solar cells. Our studies of MEH-PPV/IrC60 blended films show that long-lived charges are efficiently generated at MEH-PPV upon photoexcitation of the blend.


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