Novel form stable phase change materials based on the composites of polyethylene glycol/polymeric solid-solid phase change material

2015 ◽  
Vol 134 ◽  
pp. 80-88 ◽  
Author(s):  
Changzhong Chen ◽  
Wenmin Liu ◽  
Zhiqiang Wang ◽  
Kelin Peng ◽  
Wanli Pan ◽  
...  
e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Peng Xi ◽  
Xiao-hua Gu ◽  
Bowen Cheng

AbstractA novel copolymer as a macromonomer with a polyethylene glycol (PEG) unit as the phase change element and a vinyl group was synthesized for the preparation of polymeric solid-solid phase change materials. The IR, 1HNMR, DSC and WAXD and POM were employed to determine the structure and properties of the novel monomer. The results show that the novel monomer possess steady molecular structure, excellent crystal properties, higher phase change enthalpy and reactivity. Furthermore, the novel polymeric solid-solid phase change material was also prepared via the copolymerization of the novel copolymer macromonomer and styrene. The phase change properties of the polymeric solid-solid phase change material were characterized.


2011 ◽  
Vol 284-286 ◽  
pp. 1983-1986 ◽  
Author(s):  
Qi Song Shi ◽  
Tai Qi Liu

This study involved the preparation and characterization of polyethylene glycol (PEG)/ polyacrylamide (PAM) composite as solid-solid phase change materials (PCM). In this study, the polyethylene glycol / polyacrylamide composites as solid-solid phase change material was prepared, and the phase change behavior and crystalline morphology of the phase change materials were investigated using differential scanning calorimeter (DSC) , wide-angle X-ray diffraction (WAXD). Results indicated that the composite remained solid when the weight percentage of PEG was less than 60%. The PEG/PAM composite that exhibited solid-solid phase change behavior can be used as a new kind of phase change material for the shortage of thermal energy and temperature control.


2021 ◽  
pp. 103592
Author(s):  
Tongyan Ren ◽  
Guotong Du ◽  
Qiyu Li ◽  
Yuechuan Wang ◽  
Xiaowei Fu ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15821-15830 ◽  
Author(s):  
Bo Tan ◽  
Zhaohui Huang ◽  
Zhaoyu Yin ◽  
Xin Min ◽  
Yan'gai Liu ◽  
...  

A shape-stabilized composite phase change material comprising PEG and porous carbon was prepared by absorbing PEG into porous carbon.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Junwei Zhang ◽  
Yan Chen ◽  
Zeguang Nie ◽  
Zhengshou Chen ◽  
Junkai Gao

AbstractIn this study, silver microspheres (SMS) were introduced into cotton stalk porous-carbon (CSP) to prepare silver microsphere doping porous-carbon (SMS-CSP), and then SMS-CSP was used as the matrix of polyethylene glycol (PEG) to synthesize shape-stable phase change material of PEG/SMS-CSP. It was found that the introduction of SMS into CSP could not only greatly improve the loading capacity of the porous-carbon for PEG, but also could increase the thermal conductivity of PEG/SMS-CSP. Additionally, the method of introducing SMS into porous-carbon had the advantages of environmental protection and simple operation. Moreover, the raw material of cotton stalk is a kind of agricultural waste, which has the merits of wide source, low price and easy to obtain. Furthermore, in the preparation of cotton stalk porous-carbon, with the increase of pyrolysis temperature the thermal conductivity of PEG/SMS-CSP could be enhanced significantly. The mechanism about the enhancement of thermal conductivity was clarified, which could provide more basic theory for the study about the thermal conductivity of shape-stable phase change materials (ss-PCMs) based on porous-carbon.


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