Towards efficient solar demulsification (I): A solar electrical role on interfacial film of emulsions

Author(s):  
Chunhong Nie ◽  
Huan Du ◽  
Yupeng Zhang ◽  
Guoqiang Han ◽  
Heting Wang ◽  
...  
Keyword(s):  
Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1127
Author(s):  
Yuejie Jin ◽  
Dingrong Liu ◽  
Jinhua Hu

Polyglycerol polyricinolate (PGPR) and polyglycerol-2 dioleate were selected as model surfactants to construct water-in-oil (W/O) emulsions, and the effect of interfacial rheological properties of surfactant film on the stability of emulsions were investigated based on the interfacial dilatational rheological method. The hydrophobicity chain of PGPR is polyricinic acid condensed from ricinic acid, and that of polyglycerol-2 dioleate is oleic acid. Their dynamic interfacial tensions in 15 cycles of interfacial compression-expansion were determined. The interfacial dilatational viscoelasticity was analyzed by amplitude scanning in the range of 1–28% amplitude and frequency sweep in the range of 5–45 mHz under 2% amplitude. It was found that PGPR could quickly reach adsorption equilibrium and form interfacial film with higher interfacial dilatational viscoelastic modulus to resist the deformation of interfacial film caused by emulsion coalescence, due to its branched chain structure and longer hydrophobic chain, and the emulsion thus presented good stability. However, polyglycerol-2 dioleate with a straight chain structure had lower interfacial tension, and it failed to resist the interfacial disturbance caused by coalescence because of its lower interfacial dilatational viscoelastic modulus, and thus the emulsion was unstable. This study reveals profound understanding of the influence of branched structure of PGPR hydrophobic chain on the interfacial film properties and the emulsion stability, providing experimental reference and theoretical guidance for future design or improvement of surfactant.


Nature ◽  
1983 ◽  
Vol 305 (5935) ◽  
pp. 615-616 ◽  
Author(s):  
Shalini Menezes ◽  
Hans-Joachim Lewerenz ◽  
Klaus J. Bachmann

2004 ◽  
Vol 20 (02) ◽  
pp. 194-198 ◽  
Author(s):  
Kang Wan-Li ◽  
◽  
Zhang Hong-Yan ◽  
Li Dao-Shan ◽  
Wu Zhao-Liang ◽  
...  

Author(s):  
Stéphane Pezennec ◽  
Emmanuel Terriac ◽  
Bernard Desbat ◽  
Thomas Croguennec ◽  
Sylvie Beaufils ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
pp. 431-450 ◽  
Author(s):  
Joseph D. Paulsen

Many objects in nature and industry are wrapped in a thin sheet to enhance their chemical, mechanical, or optical properties. Similarly, there are a variety of methods for wrapping, from pressing a film onto a hard substrate to inflating a closed membrane, to spontaneously wrapping droplets using capillary forces. Each of these settings raises challenging nonlinear problems involving the geometry and mechanics of a thin sheet, often in the context of resolving a geometric incompatibility between two surfaces. Here, we review recent progress in this area, focusing on highly bendable films that are nonetheless hard to stretch, a class of materials that includes polymer films, metal foils, textiles, and graphene, as well as some biological materials. Significant attention is paid to two recent advances: a novel isometry that arises in the doubly-asymptotic limit of high flexibility and weak tensile forcing, and a simple geometric model for predicting the overall shape of an interfacial film while ignoring small-scale wrinkles, crumples, and folds.


2020 ◽  
Vol 3 (7) ◽  
pp. 7191-7199
Author(s):  
Suogang Guo ◽  
Nan Piao ◽  
Li Wang ◽  
Hong Xu ◽  
Guangyu Tian ◽  
...  

2020 ◽  
Vol 582 ◽  
pp. 411958 ◽  
Author(s):  
Semsettin Altindal ◽  
Javid Farazin ◽  
Gholamreza Pirgholi-Givi ◽  
Elif Maril ◽  
Yashar Azizian-Kalandaragh

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