Preparation and optical properties of sol–gel derived photo-patternable organic–inorganic hybrid films for optical waveguide applications

2009 ◽  
Vol 518 (1) ◽  
pp. 290-294 ◽  
Author(s):  
C.Y. Jia ◽  
Wenxiu Que ◽  
W.G. Liu
1998 ◽  
Vol 519 ◽  
Author(s):  
Y. Yan ◽  
Z. Duan ◽  
D.-G. Chen ◽  
S. Ray Chaudhuri

AbstractThe insoluble, strongly hydrogen bonded organic pigment of 3,6-bis-(4-chlorphenyl)-l,4- diketopyrrolo [3,4-c] pyrrole was transiently blocked by adding carbamate groups, and consequently incorporated into organic-inorganic hybrid matrices by a sol-gel process. The homo- (pigment-pigment) and hetero-intermolecular (pigment-matrix) interactions were found to control both the assembly and dispersion of pigment molecules in the hybrid coating films. A weaker interaction between matrices and pigment molecules results in aggregation of the carbamate pigment in the methyl-silicate films. A stronger interaction forms a homogenous dispersion and coloration of the phenyl-silicate films. The as-prepared methyl- and phenylsilicate films doped with the organic pigment were distinguished by a morphology change and a blue (hypsochromic) shift in absorption from 550 to 460 nm. Thermal treatment can remove the carbamate groups and in-situ form the organic pigment in the hybrid films.


Langmuir ◽  
2006 ◽  
Vol 22 (12) ◽  
pp. 5220-5223 ◽  
Author(s):  
Eun-Seok Kang ◽  
Masahide Takahashi ◽  
Yomei Tokuda ◽  
Toshinobu Yoko

2011 ◽  
Vol 49 (19) ◽  
pp. 4193-4203 ◽  
Author(s):  
CÉ Guinto Gamys ◽  
Emmanuel Beyou ◽  
Elodie Bourgeat-Lami ◽  
Pierre Alcouffe ◽  
Laurent David

2018 ◽  
Vol 9 (1) ◽  
pp. 304 ◽  
Author(s):  
Xuehua Zhang ◽  
Chu Xue ◽  
Wei Zhang ◽  
Liang Yu ◽  
Qian Wang ◽  
...  

2015 ◽  
Vol 6 (2) ◽  
pp. 23
Author(s):  
Andressa Renatta Simão ◽  
Carlos Jorge Ribeiro Silva ◽  
Maria Fernanda Jesus Rego Paiva Proença

<div class="WordSection1"><div class="WordSection1"><p>Organic-inorganic gels hybrid matrix (HOI) doped with functionalized carbon nanotubes (CNT) and chromenes were prepared by sol-gel method and was characterized their optical and eletrical properties. The applicationof infrared spectroscopy (FTIR) spectroscopy and ultraviolet and visible allowed in order to evaluate their optical properties. It was used the technique of impedance spectroscopy to assess the electrical conductivity and permittivity of such materials. We conclude that the process of synthesis of HOI-doped with chromene or <span style="text-decoration: line-through;"> </span>CNT allows to produce for materials that display similar to the pure precursor compounds dispersed therein revealing the proper process suitable for the purpose to obtain homogeneous material, with or without electrical conductivity and permittivity, it enables the immobilization when property changes occur these types of molecules / structures.</p></div><p>Keywords: Sol-gel organic-inorganic hybrid, chromene, carbon nanotube.</p><p> </p></div>


2009 ◽  
Vol 129 (9) ◽  
pp. 1036-1041 ◽  
Author(s):  
Nobuaki Kitazawa ◽  
Dhebbajaji Yaemponga ◽  
Masami Aono ◽  
Yoshihisa Watanabe

2012 ◽  
Author(s):  
Ahmad Sharmi Abdullah ◽  
Amirjan Nawabjan ◽  
Norazan Mohd Kassim ◽  
Mohd Haniff Ibrahim ◽  
Mohamad Zahid Abdul Malek

Pandu gelombang optik jalur berasaskan bahan–bahan sol–gel organik–bukan organic (hybrid) direka, disimulasi dan dibentuk. Bahan–bahan sol–gel hybrid tersebut disediakan daripada vinyltriethoxysilane (VTES), tetraethoxysilane (TEOS) dan tetrabutoxytitanate (TTBu) malalui kaedah pemprosesan sol–gel. Pandu gelombang optik tersebut telah dibentuk di atas lapisan quartz menggunakan kaedah penyalutan berputar, lithografi langsung, dan goresan kimia basah. Beberapa lapisan sol telah dibentuk demi mendapatkan struktur pandu gelombang dengan ketebalan yang sesuai untuk laluan mod cahaya sebagaimana diperolehi daripada simulasi. Kebolehan pandu gelombang untuk memandu cahaya pada panjang gelombang 1550 nm telah dicirikan mengunakan kaedah direct end–face fiber butt–coupling. Struktur fizikal pandu gelombang tersebut telah diperhatikan melalui mikroskop berkuasa tinggi. Keputusan yang diperolehi menunjukkan bahawa bahan yang dicadangkan boleh digunakan dalam aplikasi pemanduan gelombang optik pada panjang gelombang 1550 nm. Simulasi menunjukkan bahawa pandu gelombang jalur satu mod dapat direalisasikan jika ketebalan dan kelebaran pandu gelombang tersebut berada pada suatu julat nilai tertentu. Julat nilai tersebut dapat diperolehi melalui pengawalan parameter–parameter penyalutan berputar dan pembentukan mikro. Kualiti keratan rentas yang baik juga diperhatikan telah diperolehi melalui kaedah pembelahan semulajadi. Kata kunci: Pemprosesan sol–gel; bahan organik–bukan organic; pandu gelombang jalur Ridge optical waveguides based on organic–inorganic (hybrid) sol–gel materials were designed, simulated and fabricated. The hybrid sol–gel materials were synthesized from vinyltriethoxysilane (VTES), tetraethoxysilane (TEOS) and tetrabutoxytitanate (TTBu) precursors by means of sol–gel processing technique. The optical waveguides were fabricated on quartz substrate using spin coating, direct photolithography, and wet chemical etching techniques. Multiple layers of sol were deposited so as to obtain waveguide structure with suitable thickness for mode propagation such as acquired from the simulation. Waveguiding ability of the ridge optical waveguides at 1550 nm wavelength was characterized using direct end–face fiber butt–coupling method. Physical structure of the waveguides was observed through high power microscope. Observation showed that the proposed material possesses the ability for waveguiding application at the wavelength of 1550 nm. Simulation showed that a single mode ridge optical waveguide could be realized provided that the structure thickness and width are within certain range. The range is attainable through proper control of spin coating and micropatterning parameters. Acceptable end–face quality resulted from natural cleaving process was also discovered. Key words: Sol–gel processing; organic–inorganic material; ridge optical waveguide


Nanomaterials ◽  
2016 ◽  
Vol 6 (3) ◽  
pp. 44 ◽  
Author(s):  
Hsiao-Yuan Ma ◽  
Tzong-Liu Wang ◽  
Pei-Yu Chang ◽  
Chien-Hsin Yang

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