Electron donating capacity reduction of dissolved organic matter by solar irradiation reduces the cytotoxicity formation potential during wastewater chlorination

2018 ◽  
Vol 145 ◽  
pp. 94-102 ◽  
Author(s):  
Ye Du ◽  
Qian-Yuan Wu ◽  
Xiao-Tong Lv ◽  
Bei Ye ◽  
Xin-Min Zhan ◽  
...  
2020 ◽  
Author(s):  
Peter Herzsprung ◽  
Christin Wilske ◽  
Wolf von Tümpling ◽  
Norbert Kamjunke ◽  
Oliver J. Lechtenfeld

<p>Photochemical processing is a major transformation pathway for allochthonous and autochthonous dissolved organic matter (DOM). DOM consists of thousands or even millions of different molecules and the isomer-resolved identification molecular structures is still far from any analytical realization. The highest analytical resolution of DOM can be achieved on a molecular mass basis via Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR-MS). With this technique, the molecular elemental compositions of thousands of DOM components can be assessed, given that they are extractable from water (via e.g. solid phase extraction, SPE-DOM) and ionizable (e.g. via electrospray ionization).</p><p>Increasing levels of DOC in drinking water reservoirs pose serious challenges for drinking water processing. Photochemical processes potentially influence the DOM quality in the reservoir water. The photo degradation and / or the photo production of DOM components in surface freshwater as function of cumulated radiation was rarely investigated. In order to fill this gap we performed an irradiation experiment with water from a shaded forest stream flowing into a large reservoir (Muldenberg, Germany). DOC concentration, UV absorption, excitation-emission-matrices (EEMs) including calculated PARAFAC components and fluorescence indices, and FT-ICR MS derived molecular formulas of SPE-DOM were recorded at 13 different time points. The cumulated radiation was recorded during six days of solar irradiation (sunny days in August at 50.401847 deg. latitude and 12.380528 deg. longitude). Changes in relative peak intensity of DOM components as function of cumulated radiation were evaluated both by Spearman`s rank correlation and linear regression.</p><p>We found components with different types of photo reaction behavior. Relative aliphatic components like C<sub>9</sub>H<sub>12</sub>O<sub>5</sub> were identified as photo products showing a monotonous mass peak intensity increase with irradiation time. Highly unsaturated and oxygen-rich components like C<sub>15</sub>H<sub>6</sub>O<sub>8</sub> showed a more or less monotonous intensity decrease indicating photo degradation. Many similar components were positively correlated to the humic-like fluorescence intensity and the humification index (HIX). The strong degradation of these components can explain the high loss of fluorescence intensity and the drop of the HIX in our experiment. As a result of the high temporal resolution in our experiment (i.e. intensity change as function of cumulated irradiation) we found another type of photo reaction. Components like C<sub>15</sub>H<sub>16</sub>O<sub>8</sub> showed first increasing and then decreasing intensity indicating the formation of intermediate products.</p><p>In general, the river DOM from the forested catchment area showed high potential for photochemical transformations which probably occur in the sunlight exposed predam of the drinking water reservoir.</p>


Chemosphere ◽  
2016 ◽  
Vol 144 ◽  
pp. 816-826 ◽  
Author(s):  
Shuang Xue ◽  
Chao Wang ◽  
Zhaohong Zhang ◽  
Youtao Song ◽  
Qiang Liu

ScienceAsia ◽  
2013 ◽  
Vol 39 (1) ◽  
pp. 56 ◽  
Author(s):  
Charongpun Musikavong ◽  
Kamonnawin Inthanuchit ◽  
Kanjanee Srimuang ◽  
Thunwadee Tachapattaworakul Suksaroj ◽  
Chaisri Suksaroj

2011 ◽  
Vol 6 (1) ◽  
Author(s):  
Tassana Kueseng ◽  
Thunwadee Tachapattaworakul Suksaroj ◽  
Charongpun Musikavong ◽  
Chaisri Suksaroj

The present research aims to examine the coagulation process enhancement for dissolved organic matter (DOM) and The present research aims to examine the coagulation process enhancement for dissolved organic matter (DOM) and trihalomethane formatation potential (THMFP) removal from a raw water supply with low turbidity and specific ultraviolet absorption (SUVA). Coagulation conditions were optimized using polyaluminum chloride (PACl), PACl with dry cationic polymer (polymer), and PACl with polymer and powder activated carbon (PAC). DOM was measured in terms of dissolved organic carbon (DOC) and ultraviolet absorption at a wavelength of 254 nm (UV-254). Results show that the optimal condition for PACl, PACl and polymer, and PACl with polymer and PAC coagulation were PACl 20 mg/L at pH 7, PACl 20 mg/L and polymer 0·1 mg/L, and PACl 20 mg/L with polymer 0·1 mg/L and PAC 10 mg/L, respectively. When the DOM contents in coagulated water were fractioned to be hydrophilic (HPI) and hydrophobic (HPO) groups, it was found that the coagulation process could effectively remove more DOC of HPO than DOC of HPI. The coagulation using PACl combined with polymer and PAC provided the highest level of DOC of HPI, DOC of HPO, Trihalomethane formation potential (THMFP) of HPI, and THMFP of HPO removal efficiencies and were shown to be 65%, 75%, 77%, and 79%, respectively.


2022 ◽  
Vol 46 ◽  
pp. 102544
Author(s):  
Hengfeng Zhang ◽  
Yucong Zheng ◽  
Xiaochang C. Wang ◽  
Yongkun Wang ◽  
Mawuli Dzakpasu

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