Additivity of statistical moments in the exponentially modified Gaussian model of chromatography

2003 ◽  
Vol 478 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Samuel B Howerton ◽  
Chomin Lee ◽  
Victoria L McGuffin
1984 ◽  
Vol 67 (4) ◽  
pp. 728-731 ◽  
Author(s):  
John A Lansden

Abstract A liquid chromatographic procedure has been developed for analysis of cyclopiazonic acid in peanuts. The chromatographic system specifies a C18 or C8 column loaded with 4-dodecyldiethylenetriamine and an aqueous mobile phase containing 4-dodecyldiethylenetriamine, zinc acetate, ammonium acetate, 2-propanol, and acetonitrile. Cyclopiazonic acid was extracted from peanuts with methanol-chloroform (20 + 80), partitioned into aqueous sodium bicarbonate, acidified, and back-extracted into dichloromethane. The limit of detection (280 nm UV) was approximately 4 ng and detector response was linear to at least 1 μg pure cyclopiazonic acid. The recovery of cyclopiazonic acid from peanuts spiked at 68.9, 210, and 955 μ/kg was 85.9% (12.86% CV), 72.9% (6.43% CV), and 81.4% (0.40% CV), respectively. Calculation of the chromatographic peak parameters based on the exponentially modified Gaussian model indicated that the C18 column produced less peak skewing than did the C8 column.


2020 ◽  
Vol 20 (8) ◽  
pp. 129
Author(s):  
Hui-Jie Han ◽  
Xiao-Ping Lu ◽  
Ya-Zhou Yang ◽  
Hao Zhang ◽  
Admire Muchimamui Mutelo

2006 ◽  
Vol 111 (E11) ◽  
Author(s):  
Sarah K. Noble ◽  
Carlé M. Pieters ◽  
Takahiro Hiroi ◽  
Lawrence A. Taylor

1982 ◽  
Vol 15 (2) ◽  
pp. 537-541 ◽  
Author(s):  
Jeffrey Kovac ◽  
Charles C. Crabb

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