Studies on delayed ettringite formation in early-age, heat-cured mortars

2002 ◽  
Vol 32 (11) ◽  
pp. 1729-1736 ◽  
Author(s):  
Zhaozhou Zhang ◽  
Jan Olek ◽  
Sidney Diamond
2016 ◽  
Vol 711 ◽  
pp. 722-729
Author(s):  
Othman Omikrine-Metalssi ◽  
Badreddine Kchakech ◽  
Stéphane Lavaud ◽  
Bruno Godart

Delayed ettringite formation (DEF) can affect the long-term durability of concrete structures by causing cracking and expansion of the material. Consequently, mechanical properties decrease which may cause large structural disorders due to unexpected deformations and additional stresses in concrete and reinforcement. This reaction consists in ettringite crystallization within concrete after hardening is substantially complete, and in which no sulphates come from outside the cement paste. It may occur in materials that have been subjected to temperature above about 65 °C at early age and to high humidity. At this high temperature, the ettringite turns unstable while the concrete is still plastic and forms again after cooling in the hardened material, thus generating swelling due to crystallisation pressure.This article aims to present a new model for the calculation of structures affected by DEF and to study the effect of the prefabrication temperature on the development of this reaction. In this context, the elaborated model was applied to the 3D simulations of a real bridge affected by this phenomenon. The results highlight that the temperature reached in the precast beams of the studied bridge during prefabrication has a significant effect on the displacements and stresses. Therefore, more precise control of the prefabrication temperature has to be applied in order to prevent the swelling and damage to structures.


2017 ◽  
Vol 143 ◽  
pp. 580-588 ◽  
Author(s):  
Björn Höhlig ◽  
Christof Schröfl ◽  
Simone Hempel ◽  
Ina Noack ◽  
Viktor Mechtcherine ◽  
...  

2016 ◽  
Vol 9 (3) ◽  
pp. 357-394 ◽  
Author(s):  
I. F. Torres ◽  
T. Andrade

ABSTRACT Currently, there is an awareness that is critical to assess the durability characteristics of concrete with as much attention as the mechanical properties. The durability of concrete structures can often be affected by chemical attacks, jeopardizing its performance and security. When concrete is subjected to high temperature at early ages, many physical and chemical changes in hardened concrete may occur. It iswidely accepted that concrete subjected to these conditions of temperature and exposed to moisture is prone to cracking due to Delayed Ettringite Formation (DEF). This work aims at providing a DEF risk analysis on foundation pile caps at the Metropolitan Region of Recife - PE. Temperature rise measurement was performed in situ at 5 different caps through datalogger and thermocouples equipments. Furthermore, the Duggan test was performed in order to assess the level of expansion of 3 cements studied: X (CP II E 40), Y (CP II F 32) and Z (CP V ARI RS). Simultaneously, the chemical compositions of these cements and their respective clinkers were quantified by analysis of X-ray fluorescence (XRF). The cement X (CP II E 40) showed the chemical characteristics favoring with more intensity DEF and, as a result, higher level of expansion in the test Duggan. It is noteworthy that incorporation of metakaolin (8% and 16%) and silica fume (5% and 10%) showed mitigating potential of expansions. It is important to point out that all factors related to thermal properties and chemical composition of the concrete used in the region converge to a condition of ideal susceptibility for triggering DEF. Therefore, it is essential at least minimum and basic requirements in the design specification in order to avoid high temperatures in the massive concrete elements, preventing them from delayed ettringite formation.


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