scholarly journals Risk analysis of the delayed ettringite formation in pile caps foundation in the metropolitan region of Recife - PE - Brasil

2016 ◽  
Vol 9 (3) ◽  
pp. 357-394 ◽  
Author(s):  
I. F. Torres ◽  
T. Andrade

ABSTRACT Currently, there is an awareness that is critical to assess the durability characteristics of concrete with as much attention as the mechanical properties. The durability of concrete structures can often be affected by chemical attacks, jeopardizing its performance and security. When concrete is subjected to high temperature at early ages, many physical and chemical changes in hardened concrete may occur. It iswidely accepted that concrete subjected to these conditions of temperature and exposed to moisture is prone to cracking due to Delayed Ettringite Formation (DEF). This work aims at providing a DEF risk analysis on foundation pile caps at the Metropolitan Region of Recife - PE. Temperature rise measurement was performed in situ at 5 different caps through datalogger and thermocouples equipments. Furthermore, the Duggan test was performed in order to assess the level of expansion of 3 cements studied: X (CP II E 40), Y (CP II F 32) and Z (CP V ARI RS). Simultaneously, the chemical compositions of these cements and their respective clinkers were quantified by analysis of X-ray fluorescence (XRF). The cement X (CP II E 40) showed the chemical characteristics favoring with more intensity DEF and, as a result, higher level of expansion in the test Duggan. It is noteworthy that incorporation of metakaolin (8% and 16%) and silica fume (5% and 10%) showed mitigating potential of expansions. It is important to point out that all factors related to thermal properties and chemical composition of the concrete used in the region converge to a condition of ideal susceptibility for triggering DEF. Therefore, it is essential at least minimum and basic requirements in the design specification in order to avoid high temperatures in the massive concrete elements, preventing them from delayed ettringite formation.

2007 ◽  
Vol 2007 ◽  
pp. 224-224 ◽  
Author(s):  
Atiyeh Bohluli ◽  
Abasali Naserian ◽  
Reza Valizadeh

Iran is the greatest pistachio producer in the world. A large quantity of pistachio by-product (at least 150,000 tons in DM) is produced from pistachio dehulling process in Iran, annually. The results of some experiments show this by¬product can be used as a feedstuff for ruminants (Shakeri and Fazaeli, 2005; VAhmani et. al., 2005). However, more information about physical and chemical compositions of this by-product is needed. Pistachio by-product is mainly consists of epicarp, peduncle, leaf and a little amount of mesocarp and kernel. The aim of this study was to determine chemical composition and in situ dry matter disappearance of each part of pistachio by-product (Ohadi variety) after 0, 12 and 24 h incubation in the rumen.


2018 ◽  
Author(s):  
Devon Jakob ◽  
Le Wang ◽  
Haomin Wang ◽  
Xiaoji Xu

<p>In situ measurements of the chemical compositions and mechanical properties of kerogen help understand the formation, transformation, and utilization of organic matter in the oil shale at the nanoscale. However, the optical diffraction limit prevents attainment of nanoscale resolution using conventional spectroscopy and microscopy. Here, we utilize peak force infrared (PFIR) microscopy for multimodal characterization of kerogen in oil shale. The PFIR provides correlative infrared imaging, mechanical mapping, and broadband infrared spectroscopy capability with 6 nm spatial resolution. We observed nanoscale heterogeneity in the chemical composition, aromaticity, and maturity of the kerogens from oil shales from Eagle Ford shale play in Texas. The kerogen aromaticity positively correlates with the local mechanical moduli of the surrounding inorganic matrix, manifesting the Le Chatelier’s principle. In situ spectro-mechanical characterization of oil shale will yield valuable insight for geochemical and geomechanical modeling on the origin and transformation of kerogen in the oil shale.</p>


2021 ◽  
Vol 5 (7) ◽  
pp. 191
Author(s):  
Yanshuai Wang ◽  
Siyao Guo ◽  
Biqin Dong ◽  
Feng Xing

The functionalization of graphene has been reported widely, showing special physical and chemical properties. However, due to the lack of surface functional groups, the poor dispersibility of graphene in solvents strongly limits its engineering applications. This paper develops a novel green “in-situ titania intercalation” method to prepare a highly dispersed graphene, which is enabled by the generation of the titania precursor between the layer of graphene at room temperature to yield titania-graphene nanocomposites (TiO2-RGO). The precursor of titania will produce amounts of nano titania between the graphene interlayers, which can effectively resist the interfacial van der Waals force of the interlamination in graphene for improved dispersion state. Such highly dispersed TiO2-RGO nanocomposites were used to modify epoxy resin. Surprisingly, significant enhancement of the mechanical performance of epoxy resin was observed when incorporating the titania-graphene nanocomposites, especially the improvements in tensile strength and elongation at break, with 75.54% and 176.61% increases at optimal usage compared to the pure epoxy, respectively. The approach presented herein is easy and economical for industry production, which can be potentially applied to the research of high mechanical property graphene/epoxy composite system.


2011 ◽  
Vol 382 ◽  
pp. 372-374
Author(s):  
Yong Jiang ◽  
Zhi Bin Jiang ◽  
Guo Jie Shao ◽  
Dong Cheng Guo ◽  
Yu Tian ◽  
...  

Purpose: The purpose of this study was to study the compositions of the polygonaceae medicinal plants called rumex root. Methods: Solvent method and chromatography was used to purificate the chemical compositions of Rumex, and the molecular structure of the compound was identified by physical and chemical properties and spectral data. Results: Two compounds were obtained from the ethanol extract of rumex root, which were identified as Chrysophanol and Physcione. Conclusions: Experimental basis was provided for the further study of the active ingredients of rumex root and the development and utilization of medical resources.


2017 ◽  
Vol 143 ◽  
pp. 580-588 ◽  
Author(s):  
Björn Höhlig ◽  
Christof Schröfl ◽  
Simone Hempel ◽  
Ina Noack ◽  
Viktor Mechtcherine ◽  
...  

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