Experimental study of incongruent evaporation kinetics of enstatite in vacuum and in hydrogen gas

2002 ◽  
Vol 66 (4) ◽  
pp. 713-728 ◽  
Author(s):  
Shogo Tachibana ◽  
Akira Tsuchiyama ◽  
Hiroko Nagahara
Author(s):  
A. L. Lebedev ◽  
I. V. Avilina

Experimental study of kinetics of dissolution of hypso anhydrites at 25 ᵒC made it possible to formulate model of the process in the form of a balance equation for the kinetics of dissolution of gypsum, anhydrite (first and second orders, respectively) and kinetics of precipitation of gypsum (second order). The processing of the experimental data were carried out on the basis of the solution of the Riccati equation. When taking into account the common-ion effect on the solubility of gypsum and anhydrite, the calculated values turned out to be more comparable with the experimental ones.


2017 ◽  
Vol 07 (04) ◽  
pp. 99-112 ◽  
Author(s):  
Etienne Portuguez ◽  
Arnaud Alzina ◽  
Philippe Michaud ◽  
Djamila Hourlier ◽  
Agnès Smith

CORROSION ◽  
1958 ◽  
Vol 14 (12) ◽  
pp. 34-38 ◽  
Author(s):  
T. G. OWE BERG

Abstract The reaction mechanisms for the absorption of hydrogen by metals from moist hydrogen gas and dilute acid solutions, for the desorption from metals of dissolved hydrogen in the presence of water and for hydrogen solubility and permeation under those conditions are discussed. Their kinetics are also given. Formulae are derived for rates and equilibria. These are compared with experimental data. The migration of H atoms in the metal is concluded to be associated with zero or nearly zero activation energy. Diffusion is rapid enough to maintain almost uniform distribution of H atoms in the metal during absorption and desorption under ordinary conditions. 3.8.4


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