Structural differences in self-assembled monolayers of anthraquinone derivatives on silver and gold electrodes studied by cyclic voltammetry and in situ SERS spectroscopy

1999 ◽  
Vol 478 (1-2) ◽  
pp. 83-91 ◽  
Author(s):  
Katsuhiko Nishiyama ◽  
Shin-ichiro Tahara ◽  
Yasutaka Uchida ◽  
Shotaro Tanoue ◽  
Isao Taniguchi
2019 ◽  
Vol 7 (45) ◽  
pp. 14088-14097
Author(s):  
Jonas von Irmer ◽  
Florian Frieß ◽  
Dominik Herold ◽  
Jonas Kind ◽  
Christina M. Thiele ◽  
...  

The photochromic and electrochemical switching capabilities of two dithienylethenes with different substitutions and their self-assembled monolayers on gold surfaces are characterized by in situ NMR-spectroscopy and cyclic voltammetry.


2015 ◽  
Vol 2 (3) ◽  
pp. 434-442 ◽  
Author(s):  
Anne Meunier ◽  
Eleonore Triffaux ◽  
Dan Bizzotto ◽  
Claudine Buess-Herman ◽  
Thomas Doneux

1999 ◽  
Vol 77 (5-6) ◽  
pp. 1077-1084 ◽  
Author(s):  
R Scott Reese ◽  
Marye Anne Fox

Self-assembled monolayers of sulfur-terminated oligonucleotide duplexes were formed on flat gold surfaces, either by exposure of a self-assembled monolayer bearing one oligonucleotide strand to the complementary strand or by preformation of a oligonucleotide duplex that was then deposited on a fresh gold surface. Virtually identical spectral behavior was observed whether the duplex was produced before deposition or by in situ complementary association. With a duplex bearing an appropriate pyrene end-label, the resulting thin film was photoresponsive. Surface emission measurements show no evidence for pyrene aggregation on the modified surfaces. The polarity of the photocurrent, reflecting photoinduced electron transfer initiated by photoexcitation of pyrene, is opposite that expected from the oligonucleotide-mediated reduction of the appended pyrene excited state.Key words: oligonucleotide, self-assembled monolayer, duplex formation, photoelectrochemistry, surface emission.


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