Early diagenetic stabilization of trace elements in reptile bone remains as an indicator of Maastrichtian–Late Paleocene climatic changes: evidence from the Naran Bulak locality, the Gobi Desert (South Mongolia)

2001 ◽  
Vol 143 (1-2) ◽  
pp. 15-39 ◽  
Author(s):  
V.S. Samoilov ◽  
Ch. Benjamini ◽  
E.V. Smirnova
2013 ◽  
Vol 10 (2) ◽  
pp. 2205-2244 ◽  
Author(s):  
I. Antcibor ◽  
S. Zubrzycki ◽  
A. Eschenbach ◽  
L. Kutzbach ◽  
D. Bol'shiyanov ◽  
...  

Abstract. Soils are an important compartment of ecosystems and have the ability to immobilize chemicals preventing their movement to other environment compartments. Predicted climatic changes together with other anthropogenic influences on Arctic terrestrial environments may affect biogeochemical processes enhancing leaching and migration of trace elements in permafrost-affected soils. This is especially important since the Arctic ecosystems are considered to be very sensitive to climatic changes as well as to chemical contamination. This study characterizes background levels of trace metals in permafrost-affected soils of the Lena River Delta and its hinterland in northern Siberia (73.5° N–69.5° N) representing a remote region far from evident anthropogenic trace metal sources. Investigations on total element contents of iron (Fe), arsenic (As), manganese (Mn), zinc (Zn), nickel (Ni), copper (Cu), lead (Pb), cadmium (Cd), cobalt (Co) and mercury (Hg) in different soil types developed in different geological parent materials have been carried out. The highest concentrations of the majority of the measured elements were observed in soils belonging to ice-rich permafrost sediments formed during the Pleistocene (ice-complex) in the Lena River Delta region. Correlation analyses of trace metal concentrations and soil chemical and physical properties at a Holocene estuarine terrace and two modern floodplain levels in the southern-central Lena River Delta (Samoylov Island) showed that the main factors controlling the trace metal distribution in these soils are organic matter content, soil texture and contents of iron and manganese-oxides. Principal Component Analysis (PCA) revealed that soil oxides play a significant role in trace metal distribution in both top and bottom horizons. Occurrence of organic matter contributes to Cd binding in top soils and Cu binding in bottom horizons. Observed ranges of the background concentrations of the majority of trace elements were similar to background levels reported for other pristine arctic areas and did not exceed mean global background concentrations examined for the continental crust as well as for the world's soils.


1983 ◽  
Vol 73 (4) ◽  
pp. 251-278 ◽  
Author(s):  
Arthur H. Hickman ◽  
Alan E. Wright

ABSTRACTApproximately 700 samples from five slate, three marble and five quartzite units have been analysed for 26 elements to determine the use of geochemistry in stratigraphic correlation. Statistical treatment of the data has established that for all the slates and marbles, and certain of the quartzites, geochemistry is a viable method of distinguishing units of similar lithology. The most useful elements for distinguishing the four main slate units are P, Cr. Zn, Cu and, to a lesser extent, Rb, Sr, Y, Nb, Ba, La and Ce. Sr may indicate climatic changes or variable organic activity. The three marble units were considered as three limestone and three dolostone types. Dolostones are distinguished by high insoluble residue contents and the elements that distinguish between the dolostones are heavily influenced by these. Limestones, however, have very large differences in Sr. SiO2, Al2O3, K2O, Cr, Mn, Cu, Rb, Sr, Y and Zr have been used in discrimint function analysis. These parameters are strongly controlled by the insoluble residue with Al2O3, K2O, Cr and Rb being correlated with shaley impurities and SiO2, TiO2 and Zr with sandy impurities. Sr, Pb, Y and Zn, and to a lesser extent S and Mn, appear to be associated with the carbonate fraction.The quartzites were found to be of three major types: (1) a very variable deltaic deposit (Appin Quartzite Formation), (2) marine bodies of immature quartz sands (Glen Coe and Eilde Quartzite formations) and (3) highly mature quartz sands (Binnein Quartzite Formation and northerly outcrops of the Glen Coe Quartzite Formation). It is possible to distinguish these three types on the basis of some trace elements (Zn, Rb, Sr, Y, Ba, La, Ce) but it is not feasible to distinguish between the Glen Coe and Eilde quartzites purely on geochemistry. The Eilde Flags, an immature estuarine sandstone, has a geochemistry intermediate between that of the quartzites and the pelites, although with higher CaO, Zr and Ba than either.


2008 ◽  
Vol 46 (1) ◽  
pp. 96-103 ◽  
Author(s):  
Yi Yang ◽  
Bao-sheng Li ◽  
Shi-fan Qiu ◽  
Zheng Wu ◽  
Quan-zhou Gao ◽  
...  

Author(s):  
O.T. Woo ◽  
G.J.C. Carpenter

To study the influence of trace elements on the corrosion and hydrogen ingress in Zr-2.5 Nb pressure tube material, buttons of this alloy containing up to 0.83 at% Fe were made by arc-melting. The buttons were then annealed at 973 K for three days, furnace cooled, followed by ≈80% cold-rolling. The microstructure of cold-worked Zr-2.5 at% Nb-0.83 at% Fe (Fig. 1) contained both β-Zr and intermetallic precipitates in the α-Zr grains. The particles were 0.1 to 0.7 μm in size, with shapes ranging from spherical to ellipsoidal and often contained faults. β-Zr appeared either roughly spherical or as irregular elongated patches, often extending to several micrometres.The composition of the intermetallic particles seen in Fig. 1 was determined using Van Cappellen’s extrapolation technique for energy dispersive X-ray analysis of thin metal foils. The method was employed to avoid corrections for absorption and fluorescence via the Cliff-Lorimer equation: CA/CB = kAB · IA/IB, where CA and CB are the concentrations by weight of the elements A and B, and IA and IB are the X-ray intensities; kAB is a proportionality factor.


Author(s):  
D. A. Carpenter ◽  
Ning Gao ◽  
G. J. Havrilla

A monolithic, polycapillary, x-ray optic was adapted to a laboratory-based x-ray microprobe to evaluate the potential of the optic for x-ray micro fluorescence analysis. The polycapillary was capable of collecting x-rays over a 6 degree angle from a point source and focusing them to a spot approximately 40 µm diameter. The high intensities expected from this capillary should be useful for determining and mapping minor to trace elements in materials. Fig. 1 shows a sketch of the capillary with important dimensions.The microprobe had previously been used with straight and with tapered monocapillaries. Alignment of the monocapillaries with the focal spot was accomplished by electromagnetically scanning the focal spot over the beveled anode. With the polycapillary it was also necessary to manually adjust the distance between the focal spot and the polycapillary.The focal distance and focal spot diameter of the polycapillary were determined from a series of edge scans.


1979 ◽  
Vol 7 (6) ◽  
pp. 1330-1331
Author(s):  
E. D. WILLS

2004 ◽  
Vol 74 (4) ◽  
pp. 247-251 ◽  
Author(s):  
Lombardi-Boccia ◽  
Lanzi ◽  
Lucarini ◽  
Di Lullo

This study was undertaken to estimate the contribution of meat and meat products consumption to the daily intakes of trace elements (Fe, Zn, Cu, Se), heme iron, and selected B vitamins (thiamine, riboflavin, niacin) in Italy. Meat and meat products were selected on the basis of their consumption frequency reported by the most recent nationwide dietary individual survey carried out in Italy (INN-CA study). The daily intakes of total iron and heme iron were 1.65 and 1.13 mg/person/day. Zinc intake was 3.65 mg/person/day. Beef made the main contribution to iron, heme iron, and zinc daily intakes. Copper daily intake was 107.3 mug/person/day, with meat products provided the highest contribution (40 mug/person/day). Daily intake of selenium (7.14 mug/person/day) was provided mainly by poultry consumption. Thiamine intake was 228 mug/person/day, and meat products were the main source (110 mug/person/day). Riboflavin intake was 136 mug/person/day, with both beef and meat products as the main contributors (40 mug/person/day). Niacin intake was 7.53 mg/person/day, and poultry was the main source (2.28 mg/person/day). Meat and meat products were a valuable source of micronutrients, supplying 47, 48, and 24% of zinc, niacin, and thiamin daily requirements, respectively, and over 10% of iron, copper, selenium, and riboflavin daily average requirement values of the italian RDAs calculated for the population involved in the survey (INN-CA study).


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