Experimental study on gas-phase ignition of cellulose under thermal radiation

1982 ◽  
Vol 19 (1) ◽  
pp. 787-795 ◽  
Author(s):  
Yoshio Yoshizawa ◽  
Hironobu Kubota
1981 ◽  
Vol 59 (11) ◽  
pp. 1615-1621 ◽  
Author(s):  
Scott D. Tanner ◽  
Gervase I. Mackay ◽  
Diethard K. Bohme

Flowing afterglow measurements are reported which provide rate constants and product identifications at 298 ± 2 K for the gas-phase reactions of OH− with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2=C=CH2, CH3—C≡CH, and C6H5CH3. The main channels observed were proton transfer and solvation of the OH−. Hydration with one molecule of H2O was observed either to reduce the rate slightly and lead to products which are the hydrated analogues of the "nude" reaction, or to stop the reaction completely, k ≤ 10−12 cm3 molecule−1 s−1. The reaction of OH−•H2O with CH3—C≡CH showed an uncertain intermediate behaviour.


2015 ◽  
Vol 48 (4) ◽  
pp. 045204 ◽  
Author(s):  
Pavel Bakule ◽  
Oleksandr Sukhorukov ◽  
Katsuhiko Ishida ◽  
Francis Pratt ◽  
Donald Fleming ◽  
...  

2015 ◽  
Vol 54 (37) ◽  
pp. 9251-9256 ◽  
Author(s):  
Bin Zhang ◽  
Yi Liu ◽  
Delphine Laboureur ◽  
M. Sam Mannan

Author(s):  
Svetlana Sineva ◽  
Jeff Chen ◽  
Taufiq Hidayat ◽  
Maksym Shevchenko ◽  
Peter C. Hayes ◽  
...  

Abstract Laboratory experimental study was undertaken to characterise the four-phase slag/matte/metal/tridymite equilibria of the Cu-Fe-O-S-Si system at 1473 K [1200°C], 1523 K [1250° C] and 1573 [1300°C] in a "closed" system without interaction with gas phase. The research methodology involved high temperature equilibration, ultra-fast quenching of the equilibrated samples followed by quantitative measurement of the equilibrated phases by electron probe X-ray microanalysis. Attainment of chemical equilibrium was carefully checked by the 4-points test approach. The results obtained in the present study provide reliable fundamental experimental information, which is crucial for the development and optimisation of the multicomponent thermodynamic database for copper-containing systems.


1993 ◽  
Vol 58 (19) ◽  
pp. 5276-5277 ◽  
Author(s):  
Javier Catalan ◽  
Pilar Perez ◽  
Jose Elguero
Keyword(s):  

1999 ◽  
Vol 1 (12) ◽  
pp. 2929-2933 ◽  
Author(s):  
Carlos E. Canosa-Mas ◽  
Martin D. King ◽  
Phillip J. Scarr ◽  
Katherine C. Thompson ◽  
Richard P. Wayne

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