98/01307 The dissolution process of the NiO cathodes for molten carbonate fuel cells: state-of-the-art

1998 ◽  
Vol 39 (2) ◽  
pp. 115
2016 ◽  
Vol 308 ◽  
pp. 97-108 ◽  
Author(s):  
Andi Mehmeti ◽  
Francesca Santoni ◽  
Massimiliano Della Pietra ◽  
Stephen J. McPhail

2021 ◽  
Vol 9 ◽  
Author(s):  
Suzanne Ferguson ◽  
Anthony Tarrant

This paper presents the findings of the techno-economic assessment undertaken by Wood for the UK Government Department for Business, Energy and Industrial Strategy on the large-scale deployment of Molten Carbonate Fuel Cells (MCFCs) for post-combustion CO2 capture integrated with a new build combined cycle gas turbine power plant for the generation of low carbon electricity. The findings are compared with a state of the art proprietary amine scrubbing technology. Based on a new build power plant to be installed in the North East of England, with a power train comprising two trains of H-class gas turbines each with a dedicated steam turbine, the configuration presented utilises MCFCs between the gas turbine exhausts and their heat recovery steam generators and cryogenic separation for unconverted fuel recycle and CO2 purification. It was found that the proposed configuration could achieve 92% CO2 capture from the overall power plant with MCFCs while achieving 42% of additional new power production with only 2.6 %-points of thermal efficiency penalty compared to a conventional proprietary amine benchmark. While the total project capital cost increased by 65%, the high overall thermal efficiency and additional power generated resulted in a Levelised Cost of Electricity almost identical to the benchmark at £70/MWh (US$97/MWh). A number of areas are identified for potential further improvement in this scheme. It is concluded that use of MCFC technology, which also has the capability to be tailored for hydrogen production and combined heat and power services, shows significant potential to be competitive with, or exceed, the cost and technical performance of current state of the art technologies for post-combustion CO2 capture.


2017 ◽  
Vol 42 (25) ◽  
pp. 16235-16243 ◽  
Author(s):  
Mihui Lee ◽  
Chang-Whan Lee ◽  
Hyung-Chul Ham ◽  
Jonghee Han ◽  
Sung Pil Yoon ◽  
...  

Author(s):  
K. Hemmes ◽  
M. Houwing ◽  
N. Woudstra

Direct carbon fuel cells (DCFCs) have great thermodynamic advantages over other high temperature fuel cells such as molten carbonate fuel cells (MCFCs) and solid oxide fuel cells. They can have 100% fuel utilization, no Nernst loss (at the anode), and the CO2 produced at the anode is not mixed with other gases and is ready for re-use or sequestration. So far, only studies have been reported on cell development. In this paper, we study the performance of a CO2-producing DCFC system model. The theoretically predicted advantages that are confirmed on a bench scale are also confirmed on a system level, except for the production of pure CO2. Net system efficiencies of around 78% were found for the developed system. An exergy analysis of the system shows where the losses in the system occur. If the cathode of the DCFC must be operated as a standard MCFC cathode, the required CO2 at the cathode is the reason why a large part of the pure CO2 from the anode is recycled and mixed with the incoming air and cannot be used directly for sequestration. Bench scale studies should be performed to test the minimum amount of CO2 needed at the cathode. This might be lower than in a standard MCFC operation due to the pure CO2 at the anode side that enhances diffusion toward the cathode.


2014 ◽  
Vol 63 ◽  
pp. 6517-6526 ◽  
Author(s):  
Maurizio Spinelli ◽  
Matteo C. Romano ◽  
Stefano Consonni ◽  
Stefano Campanari ◽  
Maurizio Marchi ◽  
...  

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