Synthesis and the third-order optical nonlinearities of two novel charge-transfer complexes of a heteropoly blue type (C9H7NO)4 H7PMo12O40·3H2O (C9H7NO=quinolin-8-ol) and (phen)3 H7PMo12O40·CH3CN·H2O (phen=1,10-phenanthroline)

Polyhedron ◽  
1999 ◽  
Vol 18 (10) ◽  
pp. 1419-1423 ◽  
Author(s):  
Yun-shan Zhou ◽  
En-bo Wang ◽  
Jun Peng ◽  
Jie Liu ◽  
Chang-wen Hu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Optical Nonlinearities ◽  
Third Order ◽  
The Third

Third-Order Optical Nonlinearity in a Polymer Composite

1989 ◽  
Vol 175 ◽  
Author(s):  
K. M. White ◽  
R. E. Harelstad ◽  
C. V. Francis ◽  
D. J. Gerbi ◽  
J. Stevens ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Polymeric Composite ◽  
Optical Nonlinearity ◽  
Electron Delocalization ◽  
Charge Transfer Complexes ◽  
Third Order ◽  
Third Harmonic ◽  
The Third ◽  
Nonlinear Characterization ◽  
Alternative Approach

AbstractThird-order optical nonlinearity in organic materials has generally been sought from molecules and polymers having extended i-electron delocalization in conjugated bonding schemes. In an alternative approach, we have investigated the third-order optical response of a polymeric composite containing charge transfer complexes in which the nonlinearity originates from intermolecular electron delocalization between π-electron clouds in charge transfer stacks. The material, which is composed of a polymer having electrondonating pendant side groups that complex with dopant electron-acceptor molecules, has been processed into an optically clear thin film. Nonlinear characterization of the film by means of third-harmonic generation suggests enhancement of the third-order response arising from charge transfer interactions.

The third-order optical nonlinearities of thiophene-bearing phthalocyanines studied by Z-scan technique

2011 ◽  
Vol 218 (1) ◽  
pp. 64-68 ◽  
Author(s):  
Zihui Chen ◽  
Xinyu Zhou ◽  
Zhongyu Li ◽  
Lihong Niu ◽  
Jiaxiang Yi ◽  
...  
Keyword(s):  
Optical Nonlinearities ◽  
Third Order ◽  
The Third

Single beam Z-scan measurement of the third order optical nonlinearities of styryl7 dye

Optik ◽  
2014 ◽  
Vol 125 (20) ◽  
pp. 6152-6154 ◽  
Author(s):  
S. Kumaresan ◽  
M. Basheer Ahamed
Keyword(s):  
Optical Nonlinearities ◽  
Third Order ◽  
Single Beam ◽  
The Third

Large nonresonant third‐order hyperpolarizabilities of organic charge‐transfer complexes

1991 ◽  
Vol 59 (4) ◽  
pp. 381-383 ◽  
Author(s):  
Qihuang Gong ◽  
Zongju Xia ◽  
Y. H. Zou ◽  
Xiansheng Meng ◽  
Lin Wei ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Third Order

Homoconjugated Push-Pull and Spiro Systems: Intramolecular Charge-Transfer Interactions and Third-Order Optical Nonlinearities

2010 ◽  
Vol 49 (35) ◽  
pp. 6207-6211 ◽  
Author(s):  
Shin-ichiro Kato ◽  
Marten T. Roberts Beels ◽  
Philip La Porta ◽  
W. Bernd Schweizer ◽  
Corinne Boudon ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Optical Nonlinearities ◽  
Third Order

Investigation on ultrafast third-order optical nonlinearity of metal(dmit) 2 /(mnt) 2 charge transfer complexes

2003 ◽  
Vol 12 (3) ◽  
pp. 305-309 ◽  
Author(s):  
Wang Shu-Feng ◽  
Huang Wen-Tao ◽  
Liu Chu-Ling ◽  
Yang Hong ◽  
Gong Qi-Huang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Optical Nonlinearity ◽  
Charge Transfer Complexes ◽  
Third Order

Microstructures and the third-order optical nonlinearities of semimetal Bi nanocrystals in the sodium borosilicate glass

2011 ◽  
Vol 65 (12) ◽  
pp. 1959-1962 ◽  
Author(s):  
Xinyu Yang ◽  
Weidong Xiang ◽  
Haitao Liu ◽  
Haijun Zhao ◽  
Xiyan Zhang ◽  
...  
Keyword(s):  
Borosilicate Glass ◽  
Optical Nonlinearities ◽  
Sodium Borosilicate Glass ◽  
Third Order ◽  
The Third

Third order NLO properties of corannulene and its Li-doped dimers: effect of concave–convex and convex–convex structures

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79783-79791 ◽  
Author(s):  
Li Wang ◽  
Wen-Yong Wang ◽  
Xin-Yan Fang ◽  
Chang-Li Zhu ◽  
Yong-Qing Qiu
Keyword(s):  
Charge Transfer ◽  
Third Order ◽  
Nlo Properties ◽  
The Third ◽  
Nlo Response

The convex–convex stacking motif of corannulene dimers enhances the third-order NLO response due to obvious interlayer charge transfer.

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