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Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 313
Author(s):  
Sergey Shevtsov ◽  
Igor Zhilyaev ◽  
Shun-Hsyung Chang ◽  
Jiing-Kae Wu ◽  
Natalia Snezhina

The increasingly widespread use of vacuum assisted technologies in the manufacture of polymer-composite structures does not always provide the required product quality and repeatability. Deterioration of quality most often appears itself in the form of incomplete filling of the preform with resin as a result of the inner and outer dry spot formation, as well as due to premature gelation of the resin and blockage of the vacuum port. As experience shows, these undesirable phenomena are significantly dependent on the location of the resin and vacuum ports. This article presents a method for making a decision on the rational design of a process layout. It is based on early forecasting of its objectives in terms of quality and reliability when simulating its finite element model, on the correlation analysis of the preliminary and final quality assessments, as well as on the study of the cross-correlation of a group of early calculated sub-criteria. The effectiveness of the proposed method is demonstrated by the example of vacuum infusion of a 3D thin-walled structure of complex geometry.


2022 ◽  
Vol 4 (2) ◽  
Author(s):  
Edward Clark ◽  
Monika Bleszynski ◽  
Matt Gordon

Abstract Abstract Options for recycling fiber composite polymer (FCP) materials are scarce, as these materials cannot be normally recycled and are toxic when improperly disposed. Additionally, reducing water usage is an increasing concern, as the concrete industry currently uses 10% of the world’s industrial water. Therefore, building upon our previous work, this research explores the use of polymer hybrid carbon and glass composite waste products as reinforcements in high-pressure compacted cement. Our material used nearly 70% less water during manufacturing and exhibited improved durability and salt corrosion resistance. Compression strength tests were performed on high-pressure compacted materials containing 6.0 wt% recycled admixtures before and after saltwater aging, and the results showed that the material retained 90% of its original compression strength after aging, as it contained fewer pores and cavities. Our experimental work was supplemented by molecular dynamics. Simulations, which indicated that the synergetic effects of compaction and FCP admixture addition slowed the diffusion of corrosive salt ions by an average of 84%. Thus, our high-pressure compacted cement material may be suitable for extended use in marine environments, while also reducing the amount of commercial fiber composite polymer waste material that is sent to the landfill. Article Highlights Fiber composite waste was successfully recycled into denser, high-pressure compacted ordinary Portland cement materials. High-pressure compacted cement samples containing 6% recycled admixtures retained 90% of their compression strength after salt aging. The high-pressure compaction method utilized 70% less water during specimen fabrication.


Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 258
Author(s):  
Ching-Cheng Huang

This study presents a designed alginate-based polymeric composite foam material containing decellularized elastic cartilage microscaffolds from porcine elastic cartilage by using supercritical fluid and papain treatment for medical scaffold biomaterials. The microstructure and thermal property of the designed alginate-based polymeric composite foam materials with various controlled ratios of alginate molecules and decellularized elastic cartilage microscaffolds were studied and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and differential thermal gravimetric analysis (TGA/DTG). The microstructure and thermal property of the composite foam materials were affected by the introduction of decellularized elastic cartilage microscaffolds. The designed alginate-based polymeric composite foam materials containing decellularized elastic cartilage microscaffolds were ionically cross-linked with calcium ions by soaking the polymeric composite foam materials in a solution of calcium chloride. Additional calcium ions further improved the microstructure and thermal stability of the resulting ionic cross-linked alginate-based polymeric composite foam materials. Furthermore, the effect of crosslinking functionality on microstructures and thermal properties of the resulting polymeric composite foam materials were studied to build up useful information for 3D substrates for cultivating and growing cartilage cells and/or cartilage tissue engineering.


Morphologia ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 39-47
Author(s):  
N.A. Galatenko ◽  
D.V. Kuliesh ◽  
R.A. Rozhnova ◽  
V.P. Gritsenko ◽  
L.F. Narazhayko

Background. The creation of polymeric composite materials with pronounced biological activity, which are able to act as implants with local prolonged action of the immobilized substance can be widely used in medical practice. Objective. Study of cellular reactions of surrounding tissues of experimental animals to implantation of polymeric composite materials based on isocyanurate-containing polyurethanes with ifosfamide, study of histotoxicity of the obtained materials by tissue culture method. Methods. Polymeric composite materials based on isocyanate-containing polyurethanes without and with ifosfamide were implanted into the body of white laboratory Wistar rats. Cellular responses of the organism and possible changes in the structure of test specimens after implantation were studied by light microscopy by analysis of histological micropreparations. In order to study the peculiarities of the dynamics of growth and development of fibroblastic elements, the method of tissue culture was used. Results. Conducted biological studies by in vivo and in vitro methods allowed to evaluate the effect of immobilized ifosfamide in the structure of isocyanurate-containing polyurethanes on cellular reactions of surrounding tissues during implantation in experimental animals, as well as the effect of extracts from developed polymer samples on cultured cell growth. Conclusion. It was found that the implantation of isocyanurate-containing polyurethanes with ifosfamide led to the development of intense cellular reactions in the area of implant placement, primarily the reaction of round cell elements. The presence of ifosfamide in the structure of the polymeric implantation material probably affected the proliferation of cellular elements, inhibited regenerative processes in the early stages of the study and delayed the formation of a mature connective tissue capsule around the implanted samples. The tissue culture method showed that when making an extract of isocyanurate-containing polyurethanes with ifosfamide in the culture medium, there was a large variability of cell forms, which led to the appearance of macrophage-like elements.


Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3387
Author(s):  
Irene Villa ◽  
Beatriz Santiago Gonzalez ◽  
Matteo Orfano ◽  
Francesca Cova ◽  
Valeria Secchi ◽  
...  

The sensitization of scintillation was investigated in crosslinked polymeric composite materials loaded with luminescent gold clusters aggregates acting as sensitizers, and with organic dye rhodamine 6G as the emitting species. The evolution in time of the excited states population in the systems is described by a set of coupled rate equations, in which steady state solution allowed obtainment of an expression of the sensitization efficacy as a function of the characteristic parameters of the employed luminescent systems. The results obtained indicate that the realization of sensitizer/emitter scintillating complexes is the strategy that must be pursued to maximize the sensitization effect in composite materials.


Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4287
Author(s):  
Elena Strungar ◽  
Dmitrii Lobanov ◽  
Valery Wildemann

This paper is devoted to the experimental study of polymeric composite specimens, with various types of reinforcement, in order to evaluate the breaking strength of specimens with open holes when undergoing uniaxial compression and tensile tests. Four types of interlaced 3D woven preforms were considered (orthogonal, orthogonal combined, with pairwise inter-layer reinforcement, and with pairwise inter-layer reinforcement and a longitudinal layer), with a layered preform used for comparison. Tensile tests of solid specimens without a hole, under ASTM D 3039, and of specimens with an open hole, under ASTM D 5766, were carried out using the Instron 5989 universal electromechanical testing system. Movements and strains on the specimen surface were recorded using a Vic-3D contactless optical video system and the digital images correlation method (DIC). For all the series of carbon fiber tension specimens, strain and stress diagrams, mechanical characteristics, and statistical processing for 10 specimens were obtained. The paper evaluated deformation fields for certain points in time; the obtained fields showed an irregular distribution of deformation and dependency on types of reinforcing fibers. A coefficient of strength variation is introduced, which is defined as a ratio of the ultimate stress limits obtained on solid samples with and without open holes. Within the framework of ASTM D 5766, when calculating the ultimate stress, the hole is not taken into account, and the paper shows that for certain structures a hole cannot be excluded. The hole size must not be neglected when calculating the ultimate stress.


2021 ◽  
Vol 306 (12) ◽  
pp. 2170049
Author(s):  
Fawzan S. Alfares ◽  
Ece Guler ◽  
Hussain Alenezi ◽  
Muhammet Emin Cam ◽  
Mohan Edirisinghe

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