Electronic spectroscopy and excited state dynamics of the Al–N2 complex

1998 ◽  
Vol 239 (1-3) ◽  
pp. 207-221 ◽  
Author(s):  
Xin Yang ◽  
Irina Gerasimov ◽  
Paul J. Dagdigian
Keyword(s):  
Excited State ◽  
Electronic Spectroscopy ◽  
Excited State Dynamics

Electronic spectroscopy and excited state dynamics of the Al–H2/D2 complex

2001 ◽  
Vol 118 ◽  
pp. 387-404 ◽  
Author(s):  
Xiaofeng Tan ◽  
Paul J. Dagdigian ◽  
Millard H. Alexander
Keyword(s):  
Excited State ◽  
Electronic Spectroscopy ◽  
Excited State Dynamics

scholarly journals Disentanglement of excited-state dynamics with implications for FRET measurements: two-dimensional electronic spectroscopy of a BODIPY-functionalized cavitand

2018 ◽  
Vol 9 (15) ◽  
pp. 3694-3703 ◽  
Author(s):  
John P. Otto ◽  
Lili Wang ◽  
Igor Pochorovski ◽  
Samuel M. Blau ◽  
Alán Aspuru-Guzik ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Excited State ◽  
Conformational Changes ◽  
Electronic Spectroscopy ◽  
Two Dimensional ◽  
Excited State Dynamics ◽  
Competing Dynamics

Two-dimensional electronic spectroscopy of energy transfer and competing dynamics highlights how conformational changes create issues with lifetime-based FRET measurements.

Electronic spectroscopy and excited state dynamics of the Ar⋅SH complex

1993 ◽  
Vol 98 (5) ◽  
pp. 4301-4304 ◽  
Author(s):  
Min‐Chieh Yang ◽  
Aldo P. Salzberg ◽  
Bor‐Chen Chang ◽  
Christopher C. Carter ◽  
Terry A. Miller
Keyword(s):  
Excited State ◽  
Electronic Spectroscopy ◽  
Excited State Dynamics

Excited-State Dynamics in the RNA Nucleotide Uridine 5’-Monophosphate Investigated by Femtosecond Broadband Transient Absorption Spectroscopy

2019 ◽  
Author(s):  
Matthew M. Brister ◽  
Carlos Crespo-Hernández
Keyword(s):  
Excited State ◽  
Excited States ◽  
Ground State ◽  
Transient Absorption ◽  
Electronic Energy ◽  
Transient Absorption Spectroscopy ◽  
Electronic Relaxation ◽  
Vibrationally Excited ◽  
Excited State Dynamics ◽  
Π State

<p></p><p> Damage to RNA from ultraviolet radiation induce chemical modifications to the nucleobases. Unraveling the excited states involved in these reactions is essential, but investigations aimed at understanding the electronic-energy relaxation pathways of the RNA nucleotide uridine 5’-monophosphate (UMP) have not received enough attention. In this Letter, the excited-state dynamics of UMP is investigated in aqueous solution. Excitation at 267 nm results in a trifurcation event that leads to the simultaneous population of the vibrationally-excited ground state, a longlived <sup>1</sup>n<sub>O</sub>π* state, and a receiver triplet state within 200 fs. The receiver state internally convert to the long-lived <sup>3</sup>ππ* state in an ultrafast time scale. The results elucidate the electronic relaxation pathways and clarify earlier transient absorption experiments performed for uracil derivatives in solution. This mechanistic information is important because long-lived nπ* and ππ* excited states of both singlet and triplet multiplicities are thought to lead to the formation of harmful photoproducts.</p><p></p>

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