Influence of temperature on the liquid-to-liquid extraction of 1-propanol from aqueous solutions containing nitromethane

2002 ◽  
Vol 198 (2) ◽  
pp. 267-279
Author(s):  
René A. Clará ◽  
Mónica Gramajo de Doz ◽  
Norma Barnes ◽  
Horacio N. Sólimo
Author(s):  
Yiqun Huang ◽  
Pawan Singh Takhar ◽  
Juming Tang ◽  
Barry G Swanson

Rheological behaviors of high acyl (HA) gellan are not well understood partially because of its relatively late commercialization compared to low acyl gellan. The objective of this study was to investigate the effect of temperature (5-30 °C), calcium (0, 1 and 10 mM) and gellan concentrations (0.0044-0.1000% w/v) on the flow behaviors of high acyl gellan aqueous solutions using rheological tests. Gellan solutions with 0 or 1 mM added Ca++ exhibited shear thinning behavior at gellan concentrations above 0.0125%. The influence of temperature on apparent viscosity (shear rate, 100 s-1) of gellan solutions can be described with an Arrhenius relationship. The apparent viscosity of gellan solution at low concentrations was more sensitive to temperature changes. The addition of Ca++ led to a decrease in flow resistance for a dilute gellan solution (<0.0125%), but an increased resistance for a relatively concentrated gellan solution (>0.0125%).


Attention has previously been directed by one of us to the existence of a differential septum enclosing the seeds of Hordeum (barley). When the seeds are immersed in aqueous solutions of most electrolytes, and of many non-electrolytes, this covering behaves as a very efficient differential septum, water alone entering the seeds under the attractive influence of the finely granulated contents. The rate at which the water enters is considerably affected if substances are dissolved in it, being increased by some and diminished by others; it is also markedly dependent on the temperature of the water or solution in which the seeds are immersed. Variations of the rate at which water enters with alterations of the experimental conditions are presumably due mainly to changes in the water, and the seeds of Hordeum would thus appear to be a very suitable medium for the investigation of the nature of the changes produced in water by the presence of dissolved substances or by alterations of temperature.


2010 ◽  
Vol 207 (2) ◽  
pp. 370-374 ◽  
Author(s):  
Y. Khalavka ◽  
B. Mingler ◽  
G. Friedbacher ◽  
G. Okrepka ◽  
L. Shcherbak ◽  
...  

1903 ◽  
Vol 71 (467-476) ◽  
pp. 338-350 ◽  

Messrs. Bousfield and Lowry in their interesting paper, “The Influence of Temperature on the Conductivity of Electrolytic Solutions,” have discussed a hypothesis recently advanced by me. In this I stated the probability that the conductivities of all aqueous solutions approach, with decreasing temperature, a zero value at about the same temperature, and that the cause of this phenomenon is to be looked for in the disappearance of the fluidity of water. This hypothesis was very briefly mentioned, as it were, in parenthesis, in the midst of the discussion of the numerical data which formed the main portion of the paper.


Author(s):  
T. Geipel ◽  
W. Mader ◽  
P. Pirouz

Temperature affects both elastic and inelastic scattering of electrons in a crystal. The Debye-Waller factor, B, describes the influence of temperature on the elastic scattering of electrons, whereas the imaginary part of the (complex) atomic form factor, fc = fr + ifi, describes the influence of temperature on the inelastic scattering of electrons (i.e. absorption). In HRTEM simulations, two possible ways to include absorption are: (i) an approximate method in which absorption is described by a phenomenological constant, μ, i.e. fi; - μfr, with the real part of the atomic form factor, fr, obtained from Hartree-Fock calculations, (ii) a more accurate method in which the absorptive components, fi of the atomic form factor are explicitly calculated. In this contribution, the inclusion of both the Debye-Waller factor and absorption on HRTEM images of a (Oll)-oriented GaAs crystal are presented (using the EMS software.Fig. 1 shows the the amplitudes and phases of the dominant 111 beams as a function of the specimen thickness, t, for the cases when μ = 0 (i.e. no absorption, solid line) and μ = 0.1 (with absorption, dashed line).


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