Application of an extended DLVO theory for the calculation of the interactions between emulsified oil droplets in alcohol solutions

1999 ◽  
Vol 14 (1-4) ◽  
pp. 19-26 ◽  
Author(s):  
Agnieszka Wiącek ◽  
Emil Chibowski
2020 ◽  
Author(s):  
Saranya Pullanchery ◽  
Sergey Kulik ◽  
halil okur ◽  
Hilton. B. de Aguiar ◽  
Sylvie Roke

Hydrophobic oil droplets, particles and air bubbles can be dispersed in water as kinetically stabilized dispersions. It has been established since the 19th century that such objects harbor a negative electrostatic potential roughly twice larger than the thermal energy. The source of this charge continues to be one of the core observations in relation to hydrophobicity and its molecular explanation is still debated. What is clear though, is that the stabilizing interaction in these systems is understood in terms of electrostatic repulsion via DLVO theory. Recent work [Carpenter et al., PNAS 116 (2019) 9214] has added another element into the discussion, reporting the creation of bare near-zero charged droplets of oil in water that are stable for several days. Key to the creation of the droplets is a rigorous glassware cleaning procedure. Here, we investigate these conclusions and show that the cleaning procedure of glassware has no influence on the electrophoretic mobility of the droplets, that oil droplets with near-zero charge are unstable, and provide an alternative possible explanation for the observations involving glass surface chemistry.


2019 ◽  
Vol 26 (29) ◽  
pp. 29789-29798
Author(s):  
Xiaoying Zhang ◽  
Jing Wei ◽  
Xiangtong Zhou ◽  
Akihiro Horio ◽  
Shanwei Li ◽  
...  

1992 ◽  
Vol 180-181 ◽  
pp. 564-566 ◽  
Author(s):  
P. Lesieur ◽  
P. Lindner ◽  
C. Desforge ◽  
J. Lambard ◽  
T. Zemb
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