The long-term acid neutralizing capacity of steel slag

2000 ◽  
Vol 20 (2-3) ◽  
pp. 217-223 ◽  
Author(s):  
Jinying Yan ◽  
Luis Moreno ◽  
Ivars Neretnieks
1995 ◽  
Vol 26 (4-5) ◽  
pp. 369-388 ◽  
Author(s):  
Espen Lydersen ◽  
Arne Henriksen

Input of neutral salt, primarily NaCl, from sea spray is an important factor for short-term acidification of surface water, primarily in already acidified areas, because Na may substitute for H+ and cationic aluminium by cation-exchange reactions in the soil. By evaluating the variation of non-marine sodium (Na*) separately it is possible to estimate the major effect of seasalt episodes on the neutralizing capacity (ANC) of stream water. At four long-term monitored Norwegian catchments, the Na* in stream water on average explained 28 ± 4% of the monthly variations of ANC in stream water at Birkenes, and 27 ± 3%, 20 ± 2% and 56 ± 5% of the correspondent variations at Storgama, Langtjern and Kaarvatn, during the respective monitoring periods. The remaining variations in acid neutralizing capacity are explained by the difference between non-marine base cations (ΣCa*,Mg*,K*) and non-marine sulphate (SO4*) and NO3. This paper also indicates that seasalt episodes are probably of greater importance for the periodic variations in ANC of stream water than commonly recognized. During the last years, extreme seasalt episodes have occurred in southern Norway, and more frequently at winter-time, which means that seasalt inputs have played a more important role for the short-term variations of ANC in stream water the last years. This tendency is also strengthened by the fact that there has been a significant decline in the input of acidic sulphur compounds and non-marine base cations in stream water during the last 10-15 years. Because the decline in soil-derived base cations in stream water is somewhat lower than the correspondent decline of sulphate, a slowly improving ANC of stream water should be expected on long-term basis. Seasalt episodes of the same magnitude as those present during the last years, will therefore most likely cause less extreme water-chemical conditions in the years to come. Because the seasalt effect seems to be a short-term effect, there is no reason to claim that these effects may cause long-term acidification, a conclusion earlier drawn from several correspondent studies.


1989 ◽  
Vol 46 (2) ◽  
pp. 258-267 ◽  
Author(s):  
Charles T. Driscoll ◽  
William A. Ayling ◽  
G. F. Fordham ◽  
Leah M. Oliver

The reacidification of two lakes in the Adirondack region of New York treated by CaCO3 application was evaluated. Base treatment resulted in a very high immediate dissolution efficiency in both lakes (78–82%), increasing acid neutralizing capacity (ANC) to values of 450–550 μeq∙L−1. During the fall following manipulation, completely mixed water columns and elevated hydrologic inputs greatly facilitated reacidification, decreasing pH and diluting Ca2+ concentrations. Cranberry Pond effectively reacidified within 7 mo of treatment, while the ANC of Woods Lake decreased to near 0 μeq∙L−1 15 mo after application. In Cranberry Pond, pH values decreased below 5.5 resulting in transport of elevated concentrations of inorganic Al through the lake. Annual ANC budgets suggest that little CaCO3 penetrated to the sediments, limiting long-term release of ANC from sediment dissolution. Hydrolysis of Al, due to the elevated lake pH, served to consume ANC and there is evidence to indicate limited exchange of water column Ca2+ with sediments shortly after treatment followed by release of this Ca2+ during reacidification. However these processes did not significantly accelerate or attenuate the rate of reacidification. The rate of acidification could largely be explained by the flushing of ANC from the lakes by hydrologic inputs.


2014 ◽  
Vol 11 (1) ◽  
pp. 173-184 ◽  
Author(s):  
H. Borg ◽  
M. Sundbom

Abstract. The water chemistry of streams and precipitation in the province of Jämtland, northern Sweden has been monitored since the 1980s to study long-term trends, occurrence of acid episodes, and effects of liming. The acidity in precipitation increased in the 1970s, followed by a loss of acid neutralizing capacity (ANC) and low pH in the streams. Sulfur deposition began to decrease in the 1980s, until approximately 2000, after which the decrease levelled out. Stream water sulfate concentration followed the precipitation trend but decreased more slowly and since the late 1990s a subtle increase was observed. Sulfate concentrations in the snow typically have been higher than or equal to the stream sulfate levels. However, during the period of rapid deposition decrease and also since 2005 stream sulfate has sometimes exceeded snow sulfate, indicating desorption of stored soil sulfate, possibly because of climate-related changes in run-off routes through the soil profiles, following shorter periods of frost. From 1982 to 2000, total organic carbon (TOC) increased by approximately 0.1 mg L−1 yr−1. The mean trends in sulfate and TOC from approximately 1990 until today were generally opposite. Acidic episodes with pH 4.0 at flow peaks occurred frequently in the unlimed streams, despite relatively well-buffered waters at baseflow. To evaluate the main causes for the loss of ANC during episodes, the changes in major ion concentrations during high flow episodes were evaluated. The most important factors contributing to ANC loss were dilution of base cations (Na+, K+, Ca2+, Mg2+), enrichment of organic anions and enrichment of sulfate. Wetland liming started in 1985 after which the earlier observed extreme peak values of iron, manganese and aluminium, did not reoccur. The studied area is remote from emission sources in Europe, but the critical load of acidity is still exceeded. The long-term recovery observed in the unlimed streams is thus slow, and severe acidic episodes still occur.


A computer model is developed and calibrated for simulating the movement of water and H ion through a forested watershed. The model is appropriate to a small (1 km 2 ) non-calcareous basin. The model is run on a daily time step with meteorological and pH of precipitation inputs. The model incorporates acid neutralizing capacity (a.n.c.) for various soil horizons. Changes in field capacity on the short and long term (weeks and months) and change in the hydraulic conductivity of the saturated zone on the long term affect basin outflow; a.n.c. and depth of the soil affect the pH of water on the long term. Reasonable changes in snow leaching, canopy enrichment, a.n.c., soil depth and total soil thickness have no effect on pH in the short term.


2005 ◽  
Vol 62 (11) ◽  
pp. 2620-2631 ◽  
Author(s):  
Atle Hindar ◽  
Richard F Wright

Lake Store Hovvatn and the adjacent Lake Lille Hovvatn (Norway) are acidified owing to long-term deposition of S and N. By 1974, pH was 4.46 and acid-neutralizing capacity was –42 µequiv.·L–1. Following a lake SO4 reduction from 92 to 33 µequiv.·L–1, pH had increased to 4.8 and acid-neutralizing capacity had increased to –8 µequiv.·L–1 by 2003. The acidification history is well reconstructed using the dynamic model MAGIC. The model predicts that the lakes will not, however, recover to conditions adequate to support a self-reproducing brown trout (Salmo trutta) population. Lake Store Hovvatn was first limed in 1981 and subsequently annually or biannually until 1999, at which time the entire catchment was limed. Liming increased pH to above target levels of 6.0 and reduced inorganic Al to below 5 µequiv.·L–1 in the main water body. Only after the terrestrial liming in 1999, however, was pH potentially adequate for egg survival in the lake during winter, as pH at shallow depths below the ice stayed above 5.5. The results indicate that even the dramatic reduction in acid deposition in Europe will be insufficient to provide water quality adequate for fish populations; such lakes will require some sort of liming for many decades to come.


2016 ◽  
Vol 5 (04) ◽  
pp. 4524
Author(s):  
Abdullah Shaikh Farooque ◽  
Md. Azharuddin Ismail Atar*

Medicinal plants are being widely used, either as single drug or in combination in health care delivery system. Indian Sarsaparilla, Hemidesmus indicus (Family: Asclepiadaceae) is a commonly known Indian Medicinal Plant, which is widely recognized in traditional systems of Medicine. It contains various phytoconstituents belonging to the category glycosides, flavonoids, tannins, sterols and volatile oils. It has been reported as useful in biliousness, blood diseases, dysentery, diarrhea, respiratory disorders, skin diseases, syphilis, fever, leprosy, leucoderma, leucorrhoea, itching, bronchitis, asthma, eye diseases, epileptic fits in children, kidney and urinary disorders, loss of appetite, burning sensation, dyspepsia, nutritional disorders, ulcer and rheumatism. Several studies are being carried towards its activities like analgesic, anti-inflammatory, antiulcer, hepatoprotective, antioxidant and helicobactericidal properties. In our study we have evaluated antacid activity of sariva (Anantmool) by using In-Vitro method, i.e. ANC (Acid Neutralizing Capacity). This evaluation was done by comparing the ANC of sariva macerated & powdered drug with water as blank & standard drug i.e. NaHCO3. Based on this In-Vitro experiment, we can conclude that, the macerated & powdered drug of sariva (Anantmool) evaluated in this study, varied in potency as measured in terms of their ANC. These results having ** i.e. P < 0.01 & Passed the normality test. However, the present study being in-vitro, the effects of antacid may vary In-Vitro; individual variations also contribute to the ultimate effectiveness of as antacid.        


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