Modeling of solute drag in the massive phase transformation

2000 ◽  
Vol 48 (2) ◽  
pp. 461-468 ◽  
Author(s):  
M. Hillert ◽  
M. Schalin
Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 334 ◽  
Author(s):  
Samuel Rodrigues ◽  
Fulvio Siciliano ◽  
Clodualdo Aranas ◽  
Eden Silva ◽  
Gedeon Reis ◽  
...  

A five-pass torsion simulation of the roughing passes applied during hot plate rolling was performed in the single-phase austenite region of a Nb-microalloyed steel under continuous cooling conditions. The deformation temperatures were approximately half-way between the Ae3 and the delta ferrite formation temperature (i.e., 250 °C above the Ae3) in which the free energy difference of austenite and ferrite is at maximum. The microstructures in-between passes were analyzed to characterize and quantify the occurrence of deformation-induced dynamic phase transformation. It was observed that about 7% of austenite transforms into ferrite right after the final pass. The results are consistent with the calculated critical strains and driving forces which indicate that dynamic transformation (DT) can take place at any temperature above the Ae3. This mechanism occurs even with the presence of high Nb in the material, which is known to retard and hinder the occurrence of DT by means of pinning and solute drag effects. The calculated cooling rate during quenching and the time–temperature–transformation curves of the present material further verified the existence of dynamically transformed ferrite.


2006 ◽  
Vol 55 (9) ◽  
pp. 783-786 ◽  
Author(s):  
Wei-Chun Cheng ◽  
Chih-Kang Lai

2020 ◽  
Vol 1000 ◽  
pp. 428-435
Author(s):  
Eung Ryul Baek ◽  
Ghozali Suprobo

Microstructural design is generally applied to improve the mechanical property of titanium alloy by introducing different phase transformations and thermomechanical treatments. Aside from the martensitic and diffusion transformation, the occurrence of massive transformation occurs in Ti alloy. Massive transformation is categorized as civilian phase transformation, which resulted in the change of crystal structure of an alloy with a given composition without changing the chemical composition of its initial phase. It happened when the body centered-cubic β phase changed into hexagonal closed-pack α phase without decomposing into α+β. Massive transformation involves a diffusion and growth mechanism in a short-range and generally occurs during the introduction of high cooling rates to restrict the full diffusion mechanism. Owing to the nature of a rapid cooling rate as a requirement for massive transformation, the massive phase is normally found together with the product of martensitic transformation. On the other hand, the product of massive transformation is observed as a blocky grain with a featureless characteristic using optical microscopy and. Phase identification using electron backscattered diffraction shows that the region of αm shows only the presence of the α phase. It was reported for containing a high dislocation density similar to martensitic transformation. Specifically, in Ti alloy, the higher magnification using scanning electron microscopy shows fine sub-lamellar morphology, which observed as a combination product morphology between martensitic and diffusion transformation. It resulted in the mechanical property of the massive phase is between those two morphologies. Hence, it brings a new perspective on designing the microstructure of Ti alloy, which can be used to improve the mechanical property of Ti alloy.


2006 ◽  
Vol 54 (15) ◽  
pp. 3953-3960 ◽  
Author(s):  
J SVOBODA ◽  
J VALA ◽  
E GAMSJAGER ◽  
F FISCHER

2014 ◽  
Vol 97 (12) ◽  
pp. 3733-3736 ◽  
Author(s):  
Shantanu Sood ◽  
Kim Kisslinger ◽  
Perena Gouma

2021 ◽  
Author(s):  
Jian Wang ◽  
Yusuke Hirayama ◽  
Zheng Liu ◽  
Kazuyuki Suzuki ◽  
Wataru Yamaguchi ◽  
...  

Abstract L10-ordered FeNi alloy (tetrataenite), a promising candidate for rare-earth-free and low-cost permanent magnet applications, is attracting increasing attention from academic and industrial communities. Highly ordered single-phase L10-FeNi is difficult to synthesis efficiently because of its low chemical order-disorder transition temperature (200–320 ℃). A non-equilibrium synthetic route utilizing a nitrogen topotactic reaction has been considered a valid approach, although the phase transformation mechanism is currently unknown. Herein, we investigated the basis of this reaction, namely the formation mechanism of the tetragonal FeNiN precursor phase during the nitridation of FeNi nanopowders. Detailed microstructure analysis revealed that the FeNiN precursor phase could preferentially nucleated at the nanotwinned region during nitridation and subsequently grew following a massive transformation, with high-index irrational orientation relationships and ledgewise growth motion detected at the migrating phase interface. This is the first report of a massive phase transformation detected in an Fe-Ni-N system and provides new insights into the phase transformation during the nitriding process. This work is expected to promote the synthetic optimization of fully ordered FeNi alloys for various magnetic applications.


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