Simulation of the Peritectic Phase Transition in Fe-C Alloys

In this work, a multi-phase cellular automaton (CA) model is extended for the quantitative simulation of peritectic phase transition. First, the effects of cooling rate/supersaturation and temperature on the peritectic transformation kinetics in Fe-C alloys are investigated by utilizing the present CA model. The CA simulations show that supersaturations in the parent phases (liquid and δ-ferrite) increase the L/γ interface growth velocity remarkably, but tinily for the δ/γ interface migration velocity. There exists a transition supersaturation for isothermal transformations, at which the growth rates of the two interfaces are equal. The transition supersaturation is found to increase with decreasing temperature. Microstructural evolution at different cooling rates during peritectic transformation is simulated using the experimental conditions. At low cooling rates, the δ/γ interface propagates at a higher velocity than the L/γ interface. At high cooling rates, however, the γ-phase grows more into the L-phase with a cellular morphology. Then, the proposed CA model is applied to simulate the microstructural evolution during peritectic reaction. It is observed that the γ-phase propagates along the L/δ interface and finally encircles the δ-phase. Meanwhile, the intervenient γ-phase grows in thickness through peritectic transformation. The CA simulations are compared reasonably well with the experimental data and analytical calculations.

Heterogeneous Microstructure-Induced Creep Failure Responses in Various Sub-Zones of Modified 310S Welded Joints

In order to reveal the creep failure behavior of novel modified 310S austenite steel welded joints, the creep life and microstructure evolution of the 310S austenite steel welded joints were investigated in this study. The rupture life was assessed to estimate the damage of the welded joint based on creep rupture tests performed at 600 °C in the stress range of 170–238 MPa. Compared with WM, HAZ facilitated the occurrence of creep failure in long term creep due to the combination of a smaller hardness value, a more heterogenous microstructure accompanied by coarsened M23C6, a larger grain size, higher KAM and Schmid factor. Discontinuous Laves phases appeared near the boundaries between the δ-ferrite and γ-austenite grains in the WM, and dislocation strengthening and precipitation strengthening were observed near the boundary in the BM. Furthermore, segregation elements were detected by APT and EDS adjacent to the boundary. Cr and C segregation near grain boundaries weaken the creep resistance in long term creep service.

Microstructure and Properties of the 308LSi Austenitic Steel Produced by Plasma-MIG Deposition Welding with Layer-by-Layer Peening

This paper investigates the effect of cold working via layer-by-layer peening on the microstructure and properties of a 308LSi steel workpiece produced by the wire deposition welding with a consumable electrode following the principle of 3D printing. The microstructure, phase composition and mechanical properties of the metal are studied before and after the workpiece synthesis. In the microstructure of the workpieces produced by peening, there is, in addition to austenite, a small quantity of fine-dispersed carbides and residual δ-ferrite in the interdendritic spaces. It is demonstrated that the use of layer-by-layer cold working in the process of deposition welding enables eliminating transcrystallization of the deposited metal, promotes an increase in the microstructure’s degree of dispersion and a more uniform distribution of fine-dispersed carbides in the volume of the dendrites. It is found that these structural features of the deposited metal in the additive manufacturing of a workpiece with layer-by-layer peening lead to an enhancement of the strength characteristics as compared to the material produced by the conventional wire deposition welding. Meanwhile, the level of the ductility characteristics remains high.

Effect of the Thermo-Mechanical Processing on the Impact Toughness of a 12% Cr Martensitic Steel with Co, Cu, W, Mo and Ta Doping

This paper presents the results of an experimental investigation of a 12% Cr steel where a significant increase in Charpy impact toughness and a slight decrease in ductile-brittle transition temperature (DBTT) from 70 °C to 65 °C were obtained through thermo-mechanical processing, including interim hot forging at 1050 °C with long-term annealing at 1000 °C, as compared with conventional heat treatment. At lower temperatures ranging from −20 °C to 25 °C, the value of impact toughness comprised ~40 J cm−2 in the present 12% Cr steel subjected to thermo-mechanical processing. The amount of δ-ferrite decreased to 3.8%, whereas the size of prior austenite grains did not change and comprised about 40–50 μm. The boundaries between δ-ferrite and martensitic laths were decorated by continuous chains of Cr- and W-rich carbides. M23C6 carbides also precipitated along the boundaries of prior austenite grains, packets, blocks and martensitic laths. Thermo-mechanical processing increased the mean size of M23C6 carbides and decreased their number particle densities along the lath boundaries. Moreover, the precipitation of a high number of non-equilibrium V-rich MX particles was induced by hot forging and long-term normalizing at 1000 °C for 24 h.

Deformation Mechanism Investigation on Low Density 18Mn Steels under Different Solid Solution Treatments

To meet the demand of the 10% weight reduction goal for automotive steel, the microstructure and mechanical properties of Fe-18Mn-Al-C steel with different carbon and aluminum contents were investigated under different solid solution treatments, and the deformation mechanisms of the experimental steels were elucidated. Aided by thermodynamic calculation, transmission electron microscopy (TEM) and in situ scanning electron microscope (SEM) analysis, it was shown that for the 18Mn-1.5Al experimental steel with about 20 mJ/m2 stacking fault energy (SFE), the twinning-induced plasticity (TWIP) effect always dominated in this steel after different solid solution treatments under tensile deformation. With the 7 wt% aluminum addition, the SFE of austenite was affected by temperature and the range of SFE was between 60 and 65 mJ/m2. The existence of δ-ferrite obviously inhibited the TWIP effect. With the increase in the solution treatment temperature, δ-ferrite gradually transformed into the austenite, and the n-value remained low and stable in a large strain range, which were caused by the local hardening during the tensile deformation. Due to the difference in the deformability of the austenite and δ-ferrite structure as well as the inconsistent extension of the slip band, the micro-cracks were easily initiated in the 18Mn-7Al experimental steel; then, it exhibited lower plasticity.

Laser Oscillating of Nickel Alloyed Welds on Press-hardened Steel

Laser oscillating welding was employed to fabricate Al-Si coated press-hardened steel (PHS) to improve the element homogeneity in the fusion zone. Three oscillation amplitudes that are 0 mm, 0.5 mm and 1.3 mm were studied in this present. Ni foil of 0.06 mm thickness was used as an interlayer between two tailored PHS welded. Welds defects was absent for any oscillation amplitudes, and weld width increased with increasing oscillation amplitudes. Compared to linear laser welding, Ni and Al had an uneven elemental profile due to strong stirring force, full martensite was achieved in fusion zone. However, δ-ferrite was present with oscillation amplitudes increased to 1.3 mm, since Ni content had a sharp descent compared to Al. Tensile srtength of welded joints was not influnced by altering oscillation amplitudes.