On Bose-Einstein Condensation

Author(s):  
P. T. Landsberg

ABSTRACTThis paper contains a proof that the description of the phenomenon of Bose-Einstein condensation is the same whether (1) an open system is contemplated and treated on the basis of the grand canonical ensemble, or (2) a closed system is contemplated and treated on the basis of the canonical ensemble without recourse to the method of steepest descents, or (3) a closed system is contemplated and treated on the basis of the canonical ensemble using the method of steepest descents. Contrary to what is usually believed, it is shown that the crucial factor governing the incidence of the condensation phenomenon of a system (open or closed) having an infinity of energy levels is the density of states N(E) ∝ En for high quantum numbers, a condition for condensation being n > 0. These results are obtained on the basis of the following assumptions: (i) For large volumes V (a) all energy levels behave like V−θ, and (b) there exists a finite integer M such that it is justifiable to put for the jth energy level Ej= c V−θand to use the continuous spectrum approximation, whenever j ≥ M c θ τ are positive constants, (ii) All results are evaluated in the limit in which the volume of the gas is allowed to tend to infinity, keeping the volume density of particles a finite and non-zero constant. The present paper also serves to coordinate much of previously published work, and corrects a current misconception regarding the method of steepest descents.

The Bose-Einstein condensation of a gas is investigated. Starting from the well-known formulae for Bose statistics, the problem has been generalized to include a variety of potential fields in which the particles of the gas move, and the number w of dimensions has not been restricted to three. The energy levels are taken to be ε i ≡ ε s 1 , . . . . , s 10 = constant h 2 m s 1 α − 1 a 1 2 + . . . + s w α a w 2 ( 1 ≤ α ≤ 2 ) the quantum numbers being s 1 , w = 1, 2, ..., and a 1 , ..., a w being certain characteristic lengths. (For α = 2, the potential field is that of the w -dimensional rectangular box; for α = 1, we obtain the w -dimensional harmonic oscillator field.) A direct rigorous method is used similar to that proposed by Fowler & Jones (1938). It is shown that the number q = w /α determines the appearance of an Einstein transition temperature T 0 ·For q≤ 1 there is no such point, while for q > 1 a transition point exists. For 1 < q≤ 2, the mean energy ϵ - per particle and the specific heat dϵ - /dT are continuous at T = T 0 · For q > 2, the specific heat is discontinuous at T = T 0 , giving rise to a A λ-point. A well-defined transition point only appears for a very large (theoretically infinite) number N of particles. T 0 is finite only if the quantity v = N/(a 1 .... a w )2/ α ¯ is finite. For a rectangular box, v is equal to the mean density of the gas. If v tends to zero or infinity as N→ ∞, then T 0 likewise tends to zero or infinity. In the case q > 1, and at temperatures T < T 0 ' there is a finite fraction N 0 /N of the particles, given by N 0 /N = 1-(T/T 0 ) q , in the lowest state. London’s formula (1938 b ) for the three-dimensional box is an example of this equation. Some further results are also compared with those given by London’s continuous spectrum approximation.


2013 ◽  
Vol 20 (02) ◽  
pp. 1350008 ◽  
Author(s):  
C. N. Gagatsos ◽  
A. I. Karanikas ◽  
G. Kordas

In this work we study an ideal bosonic quantum field system at finite temperature, and in a canonical and a grand canonical ensemble. For a simple spatial partition we derive the corresponding mutual information, a quantity that measures the total amount of information of one of the parts about the other. In order to find it, we first derive the von Neumann entropy that corresponds to the spatially separated subsystem (i.e. the geometric entropy) and then we subtract its extensive part which coincides with the thermal entropy of the subsystem. In the framework of the grand canonical description, we examine the influence of the underlying Bose-Einstein condensation on the behaviour of the mutual information, and we find that its derivative with respect to the temperature possesses a finite discontinuity at exactly the critical temperature.


1999 ◽  
Vol 13 (11) ◽  
pp. 349-362 ◽  
Author(s):  
S. BUND ◽  
A. M. J. SCHAKEL

A nonrelativistic Bose gas is represented as a grand-canonical ensemble of fluctuating closed spacetime strings of arbitrary shape and length. The loops are characterized by their string tension and the number of times they wind around the imaginary time axis. At the temperature where Bose–Einstein condensation sets in, the string tension, being determined by the chemical potential, vanishes and the strings proliferate. A comparison with Feynman's description in terms of rings of cyclicly permuted bosons shows that the winding number of a loop corresponds to the number of particles contained in a ring.


The theory of quantum-mechanical grand canonical ensembles is used to derive for the case of a perfect Bose-Einstein gas the average number of particles in the different energy levels, the fluctuations in these numbers and the equation of state. The Einstein condensation phenomenon is then discussed, and it is shown that in a p-v diagram (v being the specific volume) the isotherm consists of two analytically different parts in the limit where the number of particles in the system, JV, goes to infinity. It is also shown that for finite N at the critical volume ∂ n p/∂v n is of the order N1/3 (n-2) in accordance with a result obtained by Wergeland & Hove-Storhoug.


2021 ◽  
pp. 2150285
Author(s):  
Meng-Jun Ou ◽  
Ji-Xuan Hou

It is well known that Bose–Einstein condensation cannot occur in a free two-dimensional (2D) system. Recently, several studies have showed that BEC can occur on the surface of a sphere. We investigate BEC on the surface of cylinder on both sides of which atoms are confined in a one-dimensional (1D) harmonic potential. In this work, only the non-interacting Bose gas is considered. We determine the critical temperature and the condensate fraction in the geometry using the semi-classical approximation. Moreover, the thermodynamic properties of ideal bosons are also studied using the grand canonical partition function.


2020 ◽  
Vol 65 (11) ◽  
pp. 963
Author(s):  
К.А. Bugaev ◽  
O.I. Ivanytskyi ◽  
B.E. Grinyuk ◽  
I.P. Yakimenko

We investigate the phase transition of Bose–Einstein particles with the hard-core repulsion in the grand canonical ensemble within the Van der Waals approximation. It is shown that the pressure of non-relativistic Bose–Einstein particles is mathematically equivalent to the pressure of simplified version of the statistical multifragmentation model of nuclei with the vanishing surface tension coefficient and the Fisher exponent тF = 5/2 , which for such parameters has the 1-st order phase transition. The found similarity of these equations of state allows us to show that within the present approach the high density phase of Bose-Einstein particles is a classical macro-cluster with vanishing entropy at any temperature which, similarly to the system of classical hard spheres, is a kind of solid state. To show this we establish new relations which allow us to identically represent the pressure of Fermi–Dirac particles in terms of pressures of Bose–Einstein particles of two sorts.


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