Analysis and lattice imaging of a transitional event on garnets

Author(s):  
J.Y. Laval

The exsolution of magnetite from a substituted Yttrium Iron Garnet, containing an iron excess may lead to a transitional event. This event is characterized hy the formation of a transitional zone at the center of which the magnetite nucleates (Fig.1). Since there is a contrast between the matrix and these zones and since selected area diffraction does not show any difference between those zones and the matrix in the reciprocal lattice, it is of interest to analyze the structure of the transitional zones.By using simultaneously different techniques in electron microscopy, (oscillating crystal method microdiffraction and X-ray microanalysis)one may resolve the ionic process corresponding to the transitional event and image this event subsequently by high resolution technique.

2012 ◽  
Vol 185 (12) ◽  
pp. 598-601 ◽  
Author(s):  
V.V. Mesilov ◽  
V.R. Galakhov ◽  
B.A. Gizhevskii ◽  
N.I. Lobachevskaya ◽  
M. Raekers ◽  
...  

2011 ◽  
Vol 222 ◽  
pp. 235-238 ◽  
Author(s):  
Aurelija Gatelyte ◽  
Darius Jasaitis ◽  
Aldona Beganskiene ◽  
Aivaras Kareiva

In the present work, the sinterability and formation of nanosized yttrium iron garnet (Y3Fe5O12), yttrium perovskite ferrite (YFeO3), cobalt, nickel and zinc iron spinel (CoFe2O4, NiFe2O4 and ZnFe2O4, respectively) powders by an aqueous sol-gel processes are investigated. The phase purity of synthesized nano-compounds was characterized by powder X-ray diffraction analysis (XRD). The microstructural evolution and morphological features of obtained transition metal ferrites were studied by scanning electron microscopy (SEM). The possible application of these nanosized transition metal ferrites as ceramic pigments was demonstrated.


2009 ◽  
Vol 321 (23) ◽  
pp. 3945-3962 ◽  
Author(s):  
A. Rogalev ◽  
J. Goulon ◽  
F. Wilhelm ◽  
Ch. Brouder ◽  
A. Yaresko ◽  
...  

1962 ◽  
Vol 6 ◽  
pp. 389-395
Author(s):  
J. C. Lloyd ◽  
J. D. Kuptsis

AbstractAnalysis schemes for eleven rare earths (Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb) taken singly in Y-Fe garnet powders are presented. Straight-line calibrations result in all cases, usually over a range from below 0.5 wt.% to better than 6 wt.%. Errors were held to ±5-10% even using extraordinarily simple sample preparation techniques. Data are presented relating to the effects of particle size and sample preparation on precision and accuracy of the resulting analysis.


1989 ◽  
Vol 22 (4) ◽  
pp. 378-380 ◽  
Author(s):  
R. Argoud ◽  
J. Muller

For high- or low-temperature single-crystal X-ray data collection, the glues used to bind crystals to silica rods may induce strong modifications of the intensities. When an yttrium iron garnet (YIG) crystal was cooled, reflections which were equivalent at room temperature became different. This is explained by strong stresses of the glue on the crystal which lead to an anisotropic modification of the secondary extinction. At low temperatures, `glues' such as beeswax or paraffin do not exert stresses.


2019 ◽  
Vol 126 (17) ◽  
pp. 173909 ◽  
Author(s):  
J. Förster ◽  
S. Wintz ◽  
J. Bailey ◽  
S. Finizio ◽  
E. Josten ◽  
...  

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