Adsorption and pH Values Determine the Distribution of Cadmium in Terrestrial and Marine Soils in the Nansha Area, Pearl River Delta

Cadmium is a toxic element with a half-life of several decades, which can accumulate in the human body by entering the food chain and seriously harm health. The cadmium adsorption and desorption processes in the soil directly affect the migration, transformation, bioavailability, and ecotoxicity of this element in soil-plant systems. Coastal zones are located in the transitional zone between land and sea, and large amounts of terrigenous material input have important environmental effects on this ecosystem. The pH, hydrodynamic conditions, soil organic matter (SOM), and other factors defining the sea-land interaction within the sedimentary environment are significantly different from those defining land facies. In order to study the key factors affecting cadmium adsorption in soils at the sea-land interface in the Nansha area of the Pearl River Delta, a test was conducted on a column of undisturbed soil. The results showed that the adsorption constant KF and the Cd2+ adsorption capacity of marine soils were higher than those of terrestrial soils. However, the saturation adsorption of cadmium in terrestrial sediments was higher than in marine sediments. Soil pH was an important factor affecting cadmium adsorption capacity in both terrestrial and ma-rine sediments. Neutral and alkaline topsoil conditions inhibited the vertical migration of cadmium, while the acidic environment favored it. The higher the clay and SOM were, the stronger the Cd2+ adsorption capacity of the soil was. These findings suggest that the distribution of cadmium in marine and continental sedimentary soils is not only related to adsorption, but also to the physical and chemical processes occurring in different sedimentary environments.

Radiological manifestations of benign mesenteric lipoma that presented with acute intestinal obstruction: A case report

Background Intestinal obstruction is a common surgical emergency that is presented to the hospital with various aetiologies. Among all, mesenteric lipoma is one of the uncommon extraluminal causes of intestinal obstruction. In such conditions, bowel volvulus, compression or even adhesion are the underlying pathologies. Case presentation We report a 69-year-old gentleman who presented with a triad of intestinal obstruction which required exploratory laparotomy. Preoperative computed tomography revealed multiple coalescing lobulated hypoattenuating lesions encircling part of a small bowel forming transitional zone. These lesions are comparatively more hypoattenuating in comparison with the surrounding mesenteric fat. Intraoperatively, a giant ileal mesenteric lipoma was identified causing compression and folding to the adjacent small bowel, leading to proximal bowel dilatation. Excision of the lipoma with a few mesenteric lymphadenectomy was done, revealing a benign mesenteric lipoma and reactive lymph nodes. Despite ileus, he made a good postoperative recovery and was discharged well. Conclusions Patients with recurrent abdominal pain must have a thorough endoscopic and imaging assessment. Besides common or malignant aetiology, rarities should be considered and actively sought. Mesenteric lipoma is a relatively indolent tumour for which early detection can alter clinical presentation.

STRUCTURE FORMATION OF DISPERSED-REINFORCED BUILDING COMPOSITES

The results of the study of the mechanism of structure formation of cement compositions reinforced with finely dispersed monofilament are presented in the article. The mechanism of microstructure organization of construction composites was studied on models of dispersed systems, with different qualitative and quantitative composition of linear and dispersed particles. At the same time, restrictions had been placed on particle size – fiber diameter and diameter of dispersed particles are proportional to each other. Study of cracking formation kinetics was carried out on disk-shaped samples made of water-clay and water-cement compositions. Physical and mechanical characteristics of dispersed-reinforced cement stone, including non-reinforced stone, have been defined on prisms-shaped samples of square section with size 40×40×160 mm. The analysis of physical models showed that cluster structures filling with particles of various nature and shape increases structural diversity of entire dispersed system. An inserting of linear particles changes nature of system structure formation. Depending on the characteristics, structural components of the system, substructures are formed, which differ in the periods of their formation and geometric parameters. It has been established that dispersed particles of different nature are structured in different ways into clusters with discrete fibers of different length. Linear particles were more active in the creation of structural aggregates (clusters) comparing to dispersed grains. The impact of highly dispersed fibers on the structure organization of the binder compositions was quantified by the damage coefficient determined on samples of different types. The presence of discrete fibers in the composition of the material leads to modify the qualitative characteristic of compositions cracking formation. Improvement of physical and mechanical properties of the dispersed-reinforced composite confirms the ability of the fiber to change a mechanism of material destruction due to a probable deposition of hydration products on monofilaments, to densify and strengthen the interfacial transitional zone.

Landscape Evolution and Simulation of Rural Settlements around Wetland Park Based on MCCA Model and Landscape Theory: A Case Study of Chaohu Peninsula, China

As a transitional zone between urban and rural areas, the peri-urban areas are the areas with the most intense urban expansion and the most frequent spatial reconfiguration, and in this context, it is particularly important to reveal the evolution pattern of rural settlements in the peri-urban areas to provide reference for the rearrangement of rural settlements. The study takes five townships in the urban suburbs, and explores the scale, shape, spatial layout, and spatial characteristics of the urban suburbs of Hefei from 1980 to 2030 under the influence of urban-lake symbiosis based on spatial mathematical analysis and geographical simulation software. The study shows that: (1) the overall layout of rural settlements in the study area is randomly distributed due to the hilly terrain, but in small areas there is a high and low clustering phenomenon, and the spatial density shows the distribution characteristics of “high in the east and low in the west”; (2) since the reform and opening up, there are large spatial differences in the scale of rural settlements in the study area. (3) Different development scenarios have a strong impact on the future spatial pattern of rural settlement land use within the study area, which is a strong reflection of policy.

Linking Serpentinization and Weathering of Peridotite: A Study on the Mineralogical and Geochemical Evolution of the Sta. Cruz Nickel Laterite Deposit, Zambales, Philippines

While there are extensive studies on the mineralogy and geochemistry of laterites worldwide, the temporal and spatial mineralogical development of a typical nickel laterite profile is still poorly constrained. In this study, we present a detailed mineralogical and geochemical characterization of samples systematically collected from a nickel laterite profile at the Sta. Cruz nickel laterite deposit, Zambales, Philippines, to describe the temporal and spatial development of the laterite profile. Wavelength-dispersive X-ray fluorescence spectroscopy (WDSXRF), mass balance-element mobility calculations, transmitted and reflected light microscopy, and previously reported results from coupled X-ray diffraction (XRD) and Rietveld refinement analyses, reveal that the laterite profile investigated is composed of two main horizons: the limonite and saprolite zones, separated by a thin transitional zone. The main zones are further subdivided into subzones based primarily on the mineral assemblage and major element chemistry: upper limonite, lower limonite, transitional zone, upper saprolite, and lower saprolite. Late-stage garnierite veins were observed cutting the upper and lower saprolite subzones. Investigation of the structure of goethite within the limonite zone via Rietveld refinement show that the crystallinity of goethite decreases with increasing Ni content and increasing crystallite size. This suggests that upwards through the limonite zone, as goethite ages, its crystallinity increases which possibly results in the removal of Ni from its crystal structure and eventual remobilization to the lower laterite zones. We propose a spatio-temporal model of the formation of the Sta. Cruz laterite consisting of four stages: (1) early-stage alteration, (2) continued serpentinization and volume expansion, (3) late stage serpentinization and incipient oxide formation, and (4) goethite ageing and garnierite formation.

Inflammatory Cloacogenic Polyps In Children: Diagnostic Yield of Rectal Retroflexion During Colonoscopy

Background and Aims: Inflammatory cloacogenic polyps (ICPs) are inflammatory lesions occurring around the anal transitional zone. These are rare in the pediatric population, and most reported cases are found in adults. Therefore, this study aimed to evaluate the usefulness of rectal retroflexion (RR) during colonoscopy in detecting ICPs in children.Methods: A total of 1,837 colonoscopies were performed in 1,278 children between September 2003 and August 2020 at the Seoul National University Bundang Hospital. The laboratory test results and colonoscopic and histopathological findings were retrospectively reviewed. ICP was detected using the RR and was diagnosed based on the histologic findings of the polyp. Results: A total of 69 patients were diagnosed with juvenile polyps (n = 62) or ICP (n = 7), with the latter being detected through RR. All children with ICP were diagnosed from 2013 onwards when RR during colonoscopy came to be routinely performed in our medical center. The patients with ICP were older at diagnosis and more associated with a family history of colorectal polyps than JP. Stool occult blood and the polyps’ endoscopic characteristics, such as number, location, volume, and shape, significantly varied between the two groups. Additionally, there was a statistically significant difference in the polypectomy method. During the long-term follow-up, there was no recurrence of ICP. Conclusions: Due to their location at the anorectal junction, ICPs may be overlooked during colonoscopy, leading to misdiagnosis. Therefore, a retroflexion view during colonoscopy may help detect ICPs in pediatric patients, especially those presenting with hematochezia.

Sedimentary Environments and Coal Accumulation of the Middle Xishanyao Formation, Jurassic, in the Western Dananhu Coalfield, Turpan-Hami Basin

The Dananhu coalfield, at the southern margin of Turpan-Hami Basin, Xinjiang, has good coal-forming geological conditions. Due to the low research level on the depositional environment and coal accumulation, the comprehensive coal mining is restricted. Based on drilling and sectioning outcrop data, the depositional characteristics, lithofacies, paleogeography, and coal accumulation of the coal-bearing formations in western Dananhu coalfield are analyzed. The middle member of the Xishanyao Formation is the major coal-bearing strata of the Dananhu coalfield, composed of conglomerate, sandstone, siltstone, mudstone, and combustible organic rock, which can be further subdivided into 14 lithofacies according to substance composition, sediment texture, and structure. During the early Middle Jurassic coal-accumulating period, alluvial fan, fluvial plain, fluvial delta, and shallow lacustrine deposits were developed from northeast to southwest in the western Dananhu mining area. Coal accumulation was most developed in the center regions of the study area extending from northeast to southwest, which were primarily concentrated in margin fans, floodplains, interdeltaic bays, and lakeshore environments, especially the transitional zone between the fluvial plain and the delta plain in the west of No. 1 mining area. This coal accumulation was mainly controlled by synsedimentary tectonic subsidence and clastic sediments supply or sedimentary environment, where tectonic subsidence was the primary controlling factor and the source supply was the secondary controlling factor for coal accumulation, which provided theoretical support for the coal prediction and geological exploration in western Dananhu coalfield.

Dynamic Model and Numerical Simulation of Maximum Turbidity Zone Formation in River Inlet

The estuary of a river can be seen as a relatively free and partially closed coastal body. It is connected to the ocean and is a transitional zone of rivers, which contains processes from land to sea and from fresh water to salt water. The estuary is one of the most productive natural habitats in the world and carries a large number of sediments due to natural factors such as changes in runoff and tides. Therefore, many coastal areas with river estuaries have become the most densely populated areas in the human population. In this paper, the RSM (Reynolds stress model) turbulence model and the PID (proportional integral derivative) algorithm are successfully used to simulate the dynamic model and for the numerical simulation of the formation of turbidity maximum zone in the estuary, which provides a theoretical basis for the follow-up of the similar research studies.