Luminescence detection of rare-earth ions by energy transfer from counteranion to crown ether-lanthanide ion complexes

1990 ◽  
Vol 62 (8) ◽  
pp. 835-840 ◽  
Author(s):  
Chieu D. Tran ◽  
Weifeng. Zhang
Author(s):  
Ping Wu ◽  
Qianli Ma ◽  
Wensheng Yu ◽  
Jinxian Wang ◽  
Gui-Xia Liu ◽  
...  

Here, we put forward a viewpoint that the energy transfer between different rare earth (RE) ions plays negative effect in RE ions doped white fluorescent materials if the native fluorescence...


2019 ◽  
Vol 61 (5) ◽  
pp. 953
Author(s):  
А.В. Михеев ◽  
Б.Н. Казаков

AbstractThe regression analysis of the rise kinetics of up-conversion luminescence of the LiY_0.8Yb_0.2F_4:Tm^3+ (0.2 at %) crystal is performed. The kinetics curve is obtained with rectangular pulsed excitation by radiation from a laser diode (IR LD) with a wavelength of λ_ p = 933 nm. The most important—in these experimental conditions—mechanisms of the energy transfer from Yb^3+ ions to Tm^3+ ions are established, which are responsible for the transitions between the ground ^3 H _6 and excited ^3 F _4, ^3 H _4, ^1 G _4, ^1 D _2, and ^1 I _6 terms of the Tm^3+ ions. The durations of the relevant energy transfer processes are determined. It is shown that the energy transfer between rare earth ions in the LiY_0.8Yb_0.2F_4:Tm^3+ (0.2 at %) crystal occurs through the dipole–dipole interactions.


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