Insight into the Electro-Oxidation Mechanism of Glucose and Other Carbohydrates by CuO-Based Electrodes

2018 ◽  
Vol 90 (5) ◽  
pp. 3357-3365 ◽  
Author(s):  
José T. C. Barragan ◽  
Sergio Kogikoski ◽  
Everson T. S. G. da Silva ◽  
Lauro T. Kubota
Keyword(s):  
Oxidation Mechanism ◽  
Electro Oxidation ◽  
Insight Into

Electrochemistry of Br−/Br2 Redox Couple in Acetonitrile, Methanol and Mix Media of Acetonitrile–Methanol: An Insight into Redox Behavior of Bromide on Platinum (Pt) and Gold (Au) Electrode

2020 ◽  
Vol 234 (2) ◽  
pp. 295-312 ◽  
Author(s):  
Muhammad Tariq
Keyword(s):  
Gold Electrode ◽  
Digital Simulation ◽  
Oxidation Mechanism ◽  
Redox Behavior ◽  
Protic Solvent ◽  
Redox Mechanism ◽  
Au Electrode ◽  
Protic Solvents ◽  
Electro Oxidation ◽  
Insight Into

AbstractElectro-oxidation of Br− on platinum and gold electrode was studied in acetonitrile, methanol and mix media of acetonitrile–methanol. The mechanism of Br− oxidation in these media was investigated using CV, Semi Integration Cyclic Voltammetry, and Digital Simulation technique. Since, Br− oxidation mechanism on platinum involves the formation of Br3− as intermediate, therefore, Kstab for Br3− formation in the mixed media was estimated using digital simulation, Nelson and Iwamoto method. Redox mechanism of Br− and Br2 on gold (Au) electrode was also investigated in protic solvent such as H2O, methanol, ethanol, 1-butanol, and formic acid. It was ascertained that Br− oxidation on gold (Au) electrode in these above protic solvents involve [AuBr2]− intermediate rather than Br3−.

Theoretical insight into adsorption and dissociation of water on NiCr binary alloy surfaces: Early-stage oxidation mechanism

2021 ◽  
Vol 130 (11) ◽  
pp. 115303
Author(s):  
Ya-Ru Yin ◽  
Cui-Lan Ren ◽  
Zhao-Feng Liang ◽  
Jian-Xing Dai ◽  
He-Fei Huang ◽  
...  
Keyword(s):  
Binary Alloy ◽  
Early Stage ◽  
Oxidation Mechanism ◽  
Adsorption And Dissociation ◽  
Theoretical Insight ◽  
Insight Into

ONIOM calculations on serotonin degradation by monoamine oxidase B: insight into the oxidation mechanism and covalent reversible inhibition

2016 ◽  
Vol 14 (39) ◽  
pp. 9239-9252 ◽  
Author(s):  
Kubra Cakir ◽  
Safiye Sag Erdem ◽  
Vildan Enisoglu Atalay
Keyword(s):  
Monoamine Oxidase ◽  
Oxidation Mechanism ◽  
Monoamine Oxidase B ◽  
Reversible Inhibition ◽  
Covalent Inhibition ◽  
Hybrid Mechanism ◽  
Reversible Covalent ◽  
Insight Into ◽  
Oniom Calculations

We propose a hybrid mechanism for MAO where the formation of FAD-N5-ylide causes a reversible covalent inhibition, which can be modulated for designing superior therapeutics.

Mechanistic insight into active chlorine species mediated electrochemical degradation of recalcitrant phenolic polymers

RSC Advances ◽  
2014 ◽  
Vol 4 (104) ◽  
pp. 59821-59830 ◽  
Author(s):  
S. Sundarapandiyan ◽  
T. Shiny Renitha ◽  
J. Sridevi ◽  
B. Chandrasekaran ◽  
P. Saravanan ◽  
...  
Keyword(s):  
Active Chlorine ◽  
Electrochemical Degradation ◽  
Mechanistic Insight ◽  
Electro Oxidation ◽  
Kinetics Of ◽  
Insight Into

Degradation of recalcitrant phenolic syntan by electro-oxidation was investigated. The kinetics of mineralization of phenolic syntan was followed both in terms of TOC and COD measurements.

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