Molecular Packing Dependent Solid State Fluorescence Response of Supramolecular Metal–Organic Frameworks: Phenoxo-Bridged Trinuclear Zn(II) Centered Schiff Base Complexes with Halides and Pseudohalides

2018 ◽  
Vol 18 (9) ◽  
pp. 5628-5637 ◽  
Author(s):  
Nidhi Dwivedi ◽  
Sailaja S. Sunkari ◽  
Abhineet Verma ◽  
Satyen Saha
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Metal Organic Frameworks ◽  
Molecular Packing ◽  
Schiff Base Complexes ◽  
Fluorescence Response ◽  
Metal Organic ◽  
Solid State Fluorescence

Post-synthetic modification of luminescent metal-organic frameworks using schiff base complexes for biological and chemical sensing

2021 ◽  
Vol 449 ◽  
pp. 214214
Author(s):  
Manpreet Kaur ◽  
Sanjay Kumar ◽  
M. Yusuf ◽  
Jechan Lee ◽  
Richard J.C. Brown ◽  
...  
Keyword(s):  
Schiff Base ◽  
Chemical Sensing ◽  
Metal Organic Frameworks ◽  
Schiff Base Complexes ◽  
Metal Organic

Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

Polyhedron ◽  
2018 ◽  
Vol 155 ◽  
pp. 202-208 ◽  
Author(s):  
A.N. Gusev ◽  
V.F. Shul'gin ◽  
E.V. Braga ◽  
I. Nemec ◽  
B.F. Minaev ◽  
...  
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Photophysical Properties ◽  
Schiff Base Complexes ◽  
Solid State Fluorescence

An insight to the noncovalent interactions in two triamine based mononuclear iron(III) Schiff base complexes with special emphasis on the formation of Br•••π halogen bonding

CrystEngComm ◽  
2021 ◽  
Author(s):  
Shouvik Chattopadhyay ◽  
Tanmoy Basak ◽  
Antonio Frontera
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Noncovalent Interactions ◽  
Halogen Bonding ◽  
Schiff Base Complexes ◽  
X Ray ◽  
Mononuclear Iron

Two mononuclear iron(III) complexes, [FeL1Cl]∙CH3CN (1) and [FeL2(N3)] (2) {H2L1= N,N′-bis(5-chlorosalicylidene)diethylenetriamine and H2L2= N,N′-bis(5-bromosalicylidene)diethylenetriamine}, have been synthesized and characterized by X-ray crystallographic studies. In the solid state, there are strong...

Rational strategies for proton-conductive metal–organic frameworks

2021 ◽  
Author(s):  
Dae-Woon Lim ◽  
Hiroshi Kitagawa
Keyword(s):  
Solid State ◽  
Potential Application ◽  
High Performance ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Solid State Electrolytes

Since the transition of energy platforms, the proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.

Photoactive Zr and Ti Metal‐Organic‐Frameworks for solid‐state solar cells

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Arianna Melillo ◽  
Rocio Garcia ◽  
Sergio Navalon ◽  
Pedro Atienzar ◽  
Belen Ferrer ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Metal Organic Frameworks ◽  
Metal Organic

A MOF based on a lead(II) 2-oxido-6-methylpyridine-4-carboxylate network

2020 ◽  
Vol 75 (4) ◽  
pp. 365-369
Author(s):  
Long Tang ◽  
Yu Pei Fu ◽  
Na Cui ◽  
Ji Jiang Wang ◽  
Xiang Yang Hou ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Carboxylic Acid ◽  
Thermogravimetric Analysis ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Connected Node ◽  
Metal Organic ◽  
Solid State Fluorescence

AbstractA new metal-organic framework, [Pb(hmpcaH)2]n (1), has been hydrothermally synthesized from Pb(OAc)2 · 3H2O and 2-hydroxy-6-methylpyridine-4-carboxylic acid (hmpcaH2; 2), and characterized by IR spectroscopy, elemental and thermogravimetric analysis, and single-crystal X-ray diffraction. In complex 1, each hmpcaH− ligand represents a three-connected node to combine with the hexacoordinated Pb(II) ions, generating a 3D binodal (3,6)-connected ant network. The crystal structure of 2 was determined. The solid-state fluorescence properties of 1 and 2 were investigated.

scholarly journals Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks

2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Solid State ◽  
High Temperatures ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Accelerated Aging ◽  
Solvent Free ◽  
Catalytically Active ◽  
Metal Organic ◽  
Strong Acids ◽  
Zirconium Metal

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

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