Synthesis, Reaction Byproduct Characterization, and Mechanistic Understanding of Hemiformal Hydrogen Sulfide Scavengers: Part 2─Identification of Byproducts, Reaction Mechanisms, and Suppression Thereof

Author(s):  
J. J. Wylde ◽  
G. N. Taylor ◽  
K. S. Sorbie ◽  
W. N. Samaniego
2016 ◽  
Vol 64 (20) ◽  
pp. 4095-4104 ◽  
Author(s):  
Gal Y. Kreitman ◽  
John C. Danilewicz ◽  
David. W. Jeffery ◽  
Ryan J. Elias

2010 ◽  
Vol 177 ◽  
pp. 12-15
Author(s):  
Bao Rang Li ◽  
Xing Tao Liu ◽  
Yang Sheng Zheng ◽  
Hui Bin Chang

In this paper SrBi2Nb2O9 was prepared by molten salt synthesis method and KCl chosen as molten medium. In order to disclose possible formation mechanism of SrBi2Nb2O9, a simple route was established for comparison by dividing the starting precursors into four groups. With the help of XRD, possible synthesis route was analyzed. The results showed that pure SrBi2Nb2O9 powders could be obtained at temperature higher than 700oC by molten salt synthesis. Intense synthesis reaction happened in the temperature range from 500 to 700oC. The reaction mechanisms of SrBi2Nb2O9 included four steps, namely the formation of 1) SrBi2O4 at close to 600oC,2) BiNbO4 from the reaction of at 600-700 oC, 3) SrBi2Nb2O9 from the reaction of SrBi2O4 and Nb2O5 and 4)SrBi2Nb2O9 from the reaction of BiNbO4 and SrCO3. The molten salt could improve distribution and reactivity of the precursors and significant formation of SrBi2Nb2O9.


2020 ◽  
Vol 34 (4) ◽  
pp. 4808-4821 ◽  
Author(s):  
J. J. Wylde ◽  
G. N. Taylor ◽  
K. S. Sorbie ◽  
W. N. Samaniego

2019 ◽  
Vol 55 (85) ◽  
pp. 12749-12764 ◽  
Author(s):  
Gui-Juan Cheng ◽  
Xiu-Mei Zhong ◽  
Yun-Dong Wu ◽  
Xinhao Zhang

The combination of mass spectrometry and computational chemistry has been proven to be powerful for exploring reaction mechanisms. The former provides information of reaction intermediates, while the latter gives detailed reaction energy profiles.


2019 ◽  
Vol 16 (5) ◽  
pp. 422-452 ◽  
Author(s):  
Dau Xuan Duc

Furans are five-membered aromatic heterocycles containing one oxygen atom that are important building blocks in organic chemistry, but also as natural products found in various natural sources, mostly in plants, algae and microorganisms. In this review, we discussed recent advances in the synthesis of furan compounds. Some classical methods have been modified and improved, while other new methods have been developed. A vast variety of catalysts was used for these transformations. In many studies, furan synthesis reaction mechanisms were also investigated and proposed.


2016 ◽  
Vol 64 (20) ◽  
pp. 4105-4113 ◽  
Author(s):  
Gal Y. Kreitman ◽  
John C. Danilewicz ◽  
David. W. Jeffery ◽  
Ryan J. Elias

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