Kinetic Molecular Sieving of Cyclopentane/Neohexane Mixtures by the MFI Zeolite with Intersecting 10-Ring Channels

2021 ◽  
Author(s):  
Lin Zhou ◽  
Jianbo Hu ◽  
Dengzhuo Zhou ◽  
Zhenglu Yang ◽  
Liyuan Chen ◽  
...  
Keyword(s):  
Mfi Zeolite ◽  
Molecular Sieving

scholarly journals Selective Production of Aromatics from 2-Octanol on Zinc Ion-Exchanged MFI Zeolite Catalysts

Catalysts ◽  
2015 ◽  
Vol 5 (4) ◽  
pp. 2122-2133 ◽  
Author(s):  
Masakazu Iwamoto ◽  
Ryota Takezawa ◽  
Masao Morimoto
Keyword(s):  
Zinc Ion ◽  
Zeolite Catalysts ◽  
Mfi Zeolite

scholarly journals Gas Permeation Properties of High-Silica CHA-Type Zeolite Membrane

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 249
Author(s):  
Yasuhisa Hasegawa ◽  
Chie Abe ◽  
Mayumi Natsui ◽  
Ayumi Ikeda
Keyword(s):  
Molecular Size ◽  
Gas Permeation ◽  
Zeolite Membrane ◽  
Type Zeolite ◽  
High Silica ◽  
Separation Of Co2 ◽  
Α Al2o3 ◽  
Separation Performances ◽  
Molecular Sieving ◽  
Permeation Properties

The polycrystalline CHA-type zeolite layer with Si/Al = 18 was formed on the porous α-Al2O3 tube in this study, and the gas permeation properties were determined using single-component H2, CO2, N2, CH4, n-C4H10, and SF6 at 303–473 K. The membrane showed permeation behavior, wherein the permeance reduced with the molecular size, attributed to the effect of molecular sieving. The separation performances were also determined using the equimolar mixtures of N2–SF6, CO2–N2, and CO2–CH4. As a result, the N2/SF6 and CO2/CH4 selectivities were as high as 710 and 240, respectively. However, the CO2/N2 selectivity was only 25. These results propose that the high-silica CHA-type zeolite membrane is suitable for the separation of CO2 from CH4 by the effect of molecular sieving.

scholarly journals Molecular sieving using metal–polymer coordination membranes in organic media

2021 ◽  
Author(s):  
Rifan Hardian ◽  
Peter Pogany ◽  
Young Moo Lee ◽  
Gyorgy Szekely
Keyword(s):  
Chemical Resistance ◽  
Organic Media ◽  
Nanofiltration Membranes ◽  
Molecular Sieving ◽  
Metal Polymer

Improving the chemical resistance of membranes without sacrificing their molecular sieving performance is highly challenging. Herein, a novel scalable methodology was developed for fabricating solvent-resistant nanofiltration membranes based on metal–polymer...

scholarly journals Few‐unit‐cell MFI zeolite synthesized using a simple di‐quaternary ammonium structure‐directing agent

2021 ◽  
Author(s):  
Michael Tsapatsis ◽  
Peng Lu ◽  
Supriya Ghosh ◽  
Matheus Dorneles de Mello ◽  
Huda Sharbini Kamaluddin ◽  
...  
Keyword(s):  
Quaternary Ammonium ◽  
Unit Cell ◽  
Mfi Zeolite ◽  
Structure Directing Agent

scholarly journals Publisher Correction: Mixed matrix formulations with MOF molecular sieving for key energy-intensive separations

2021 ◽  
Author(s):  
Gongping Liu ◽  
Valeriya Chernikova ◽  
Yang Liu ◽  
Kuang Zhang ◽  
Youssef Belmabkhout ◽  
...  
Keyword(s):  
Mixed Matrix ◽  
Molecular Sieving

Molecular sieving mixed matrix membranes embodying nano-fillers with extremely narrow pore-openings

2020 ◽  
Vol 601 ◽  
pp. 117880 ◽  
Author(s):  
Ang Guo ◽  
Yujie Ban ◽  
Kun Yang ◽  
Yingwu Zhou ◽  
Na Cao ◽  
...  
Keyword(s):  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Molecular Sieving ◽  
Matrix Membranes

Molecular sieving of small solutes by outer medullary descending vasa recta

1997 ◽  
Vol 272 (5) ◽  
pp. F579-F586 ◽  
Author(s):  
T. L. Pallone ◽  
M. R. Turner
Keyword(s):  
Water Channel ◽  
Fluorescein Isothiocyanate ◽  
Pressure Gradients ◽  
Volume Flux ◽  
Aquaporin 1 ◽  
A Value ◽  
Vasa Recta ◽  
Mathematical Simulations ◽  
Molecular Sieving ◽  
Hydrophilic Solutes

Molecular sieving of small solutes by outer medullary descending vasa recta (OMDVR). Descending vasa recta (DVR) plasma equilibrates with the medullary interstitium by volume efflux (Jv), as well as by influx of solutes. Jv is driven by transmural osmotic pressure gradients due to small hydrophilic solutes (delta pi s), NaCl and urea. DVR endothelium probably contains a "water-only" pathway most likely mediated by the aquaporin-1 (AQP1) water channel. We measured the ability of microperfused OMDVR to concentrate lumenal 22Na and [3H]raffinose when Jv was driven by transmural NaCl gradients. Collectate-to-perfusate ratios of 2 x 10(6) M(r) fluorescein isothiocyanate-labeled dextran volume marker (RDx), 22Na (RNa), and [3H]raffinose (Rraf) were measured in the absence and presence of Jv. During volume efflux (Jv > 0), RDx was 1.37 +/- 0.31. RNa increased from 0.64 +/- 0.03 when Jv = 0 to 0.82 +/- 0.05 when Jv > 0 and Rraf increased from 0.83 +/- 0.03 to 1.13 +/- 0.05: Mathematical simulations predict RNa and Rraf most accurately when the OMDVR reflection coefficient to the tracers is assigned a value near unity. This indicates that the OMDVR wall contains a pathway for osmotic volume flux that excludes small hydrophilic solutes, a behavior consistent with that of aquaporins.

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