Mixed-Ligand Uranyl Squarate Coordination Polymers: Structure Regulation and Redox Activity

Author(s):  
Liao Meng ◽  
Yuan-yuan Liang ◽  
Lei Mei ◽  
Jun-shan Geng ◽  
Kong-qiu Hu ◽  
...  
2020 ◽  
Vol 18 (1) ◽  
pp. 391-398
Author(s):  
Shao-Hsuan Wu ◽  
Jun-Hui Huang

AbstractTwo novel mixed-ligand coordination polymers, {[Co(tdc)(btrp)]·0.67DMF}n (1) and {[Zn2(bimb)2(tdc)2]·2H2O}n (2) involving 2,5-thiophenedicarboxylate (H2tdc), and bitopic flexible N-donor ligands, 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) and 1,4-bis((1H-benzo[d]imidazol-1-yl)methyl)benzene (bimb), have been synthesized by the hydrothermal method and characterized via IR, elemental analysis, thermal analysis, and powder X-ray diffraction. The biological functional studies were performed; the treatment activity of the compounds on periodontitis and the specific mechanism was explored. First, the real-time RT-PCR was carried out to determine the inflammatory genes nf-κb and p53 relative expression in periodontal mucosal cells after treating with compounds 1 and 2. Then, the level of the inflammatory cytokine in the gingival crevicular fluid after treating with compounds was also determined by the ELISA detection kit.


2016 ◽  
Vol 45 (16) ◽  
pp. 6901-6908 ◽  
Author(s):  
Barun Dhara ◽  
Subrahmanyam Sappati ◽  
Santosh K. Singh ◽  
Sreekumar Kurungot ◽  
Prasenjit Ghosh ◽  
...  

Remarkable differences in the physicochemical properties of metal–organic gels of Fe(iii) and Al(iii) ions with the TCA ligand is reported.


2003 ◽  
Vol 2003 (14) ◽  
pp. 2705-2710 ◽  
Author(s):  
Junhua Luo ◽  
Maochun Hong ◽  
Ruihu Wang ◽  
Rong Cao ◽  
Lei Han ◽  
...  

2018 ◽  
Vol 19 (1) ◽  
pp. 470-478 ◽  
Author(s):  
Swapneswar Mondal ◽  
Parthasarathi Dastidar

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