Cyclopentadienone Oxidation Reaction Kinetics and Thermochemistry for the Alcohols, Hydroperoxides, and Vinylic, Alkoxy, and Alkylperoxy Radicals

2016 ◽  
Vol 120 (3) ◽  
pp. 433-451 ◽  
Author(s):  
Suriyakit Yommee ◽  
Joseph W. Bozzelli
Keyword(s):  
Reaction Kinetics ◽  
Oxidation Reaction ◽  
Alkylperoxy Radicals

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

Hydrodynamics, mass transfer, and photocatalytic phenol selective oxidation reaction kinetics in a fixed TiO2microreactor

AIChE Journal ◽  
2014 ◽  
Vol 61 (2) ◽  
pp. 572-581 ◽  
Author(s):  
Matic Krivec ◽  
Andrej Pohar ◽  
Blaž Likozar ◽  
Goran Dražić
Keyword(s):  
Mass Transfer ◽  
Reaction Kinetics ◽  
Selective Oxidation ◽  
Oxidation Reaction

Highly dispersed SmMn2O5 nanorods for electrochemical water oxidation reaction kinetics

2019 ◽  
Vol 6 (9) ◽  
pp. 095090 ◽  
Author(s):  
B Jansi Rani ◽  
M Gowsalya ◽  
G Ravi ◽  
R Yuvakkumar ◽  
S I Hong
Keyword(s):  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Highly Dispersed

Enhanced water oxidation reaction kinetics on a BiVO4 photoanode by surface modification with Ni4O4 cubane

2019 ◽  
Vol 7 (1) ◽  
pp. 278-288 ◽  
Author(s):  
Bin Gao ◽  
Tao Wang ◽  
Xiaoli Fan ◽  
Hao Gong ◽  
Peng Li ◽  
...  
Keyword(s):  
Surface Modification ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Adsorbed Layer ◽  
Highly Efficient ◽  
Photoelectrochemical Water Oxidation

Ni4O4 cubane is combined with a BiVO4 photoanode via an Al2O3 adsorbed layer for highly efficient and stable photoelectrochemical water oxidation.

scholarly journals Efficient optimization of nickel-cerium interface by constructing ethylene glycol ligand environment for fast water oxidation reaction kinetics

2020 ◽  
Vol 63 (9) ◽  
pp. 1731-1740 ◽  
Author(s):  
Changhong Zhan ◽  
Zijia Yu ◽  
Zheng Liu ◽  
Yong Chen ◽  
Delun Chen ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Ligand Environment
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