Dynamic Blocking by CO of Hydrogen Transport across Pd70Au30(110) Surfaces

2017 ◽  
Vol 121 (6) ◽  
pp. 3373-3380 ◽  
Author(s):  
Shohei Ogura ◽  
Katsuyuki Fukutani
Keyword(s):  
Hydrogen Transport ◽  
Dynamic Blocking

Experimental study of hydrodynamic effects in the inverse water hydrocarbon emulsions flow in microchannels

2016 ◽  
Vol 11 (1) ◽  
pp. 30-37 ◽  
Author(s):  
A.A. Rakhimov ◽  
A.T. Akhmetov
Keyword(s):  
High Speed ◽  
Petroleum Industry ◽  
Chemical Compounds ◽  
High Viscosity ◽  
Blocking Effect ◽  
High Speed Photography ◽  
Simple Chemical ◽  
Reported Study ◽  
Dynamic Blocking ◽  
Hydrodynamic Effects

The paper presents results of hydrodynamic and rheological studies of the inverse water hydrocarbon emulsions. The success of the application of invert emulsions in the petroleum industry due, along with the high viscosity of the emulsion, greatly exceeding the viscosity of the carrier phase, the dynamic blocking effect, which consists in the fact that the rate of flow of emulsions in capillary structures and cracks falls with time to 3-4 orders, despite the permanent pressure drop. The reported study shows an increase in viscosity with increasing concentration or dispersion of emulsion. The increase in dispersion of w/o emulsion leads to an acceleration of the onset of dynamic blocking. The use of microfluidic devices, is made by soft photolithography, along with high-speed photography (10,000 frames/s), allowed us to see in the blocking condition the deformation of the microdroplets of water in inverse emulsion prepared from simple chemical compounds.

Numerical Simulation of Hydrogen Transport at a Crack Tip in a Pipeline Steel

2006 ◽  
Author(s):  
Mohsen Dadfarnia ◽  
Petros Sofronis ◽  
Ian Robertson ◽  
Brian P. Somerday ◽  
Govindarajan Muralidharan ◽  
...  
Keyword(s):  
Distribution System ◽  
Large Scale ◽  
Pipeline Steel ◽  
Rapid Assessment ◽  
Crack Tip ◽  
Hydrogen Transport ◽  
Natural Gas Pipeline ◽  
Central Production ◽  
Materials Used ◽  
Pressure Hydrogen

The technology of large scale hydrogen transmission from central production facilities to refueling stations and stationary power sites is at present undeveloped. Among the problems which confront the implementation of this technology is the deleterious effect of hydrogen on structural material properties, in particular at gas pressure of 1000 psi which is the desirable transmission pressure suggested by economic studies for efficient transport. In this paper, a hydrogen transport methodology for the calculation of hydrogen accumulation ahead of a crack tip in a pipeline steel is outlined. The approach accounts for stress-driven transient diffusion of hydrogen and trapping at microstructural defects whose density may evolve dynamically with deformation. The results are used to discuss a lifetime prediction methodology for failure of materials used for pipelines and welds exposed to high-pressure hydrogen. Development of such predictive capability and strategies is of paramount importance to the rapid assessment of using the natural-gas pipeline distribution system for hydrogen transport and of the susceptibility of new alloys tailored for use in the new hydrogen economy.

scholarly journals STUDIES ON THE MECHANISM OF HYDROGEN TRANSPORT IN ANIMAL TISSUES

1942 ◽  
Vol 142 (2) ◽  
pp. 543-555 ◽  
Author(s):  
V.R. Potter ◽  
W.C. Schneider
Keyword(s):  
Hydrogen Transport ◽  
Animal Tissues

ChemInform Abstract: Electrochemical Membrane Technique for Studying Hydrogen Transport in Germanium

ChemInform ◽  
2009 ◽  
Vol 40 (15) ◽  
Author(s):  
P. P. Konorov ◽  
N. V. Rodionov ◽  
A. M. Yafyasov ◽  
V. B. Bozhevol'nov
Keyword(s):  
Hydrogen Transport ◽  
Membrane Technique

Hydrogen transport and trapping in ODS-EUROFER

2007 ◽  
Vol 82 (15-24) ◽  
pp. 2634-2640 ◽  
Author(s):  
G.A. Esteban ◽  
A. Peña ◽  
F. Legarda ◽  
R. Lindau
Keyword(s):  
Hydrogen Transport

Investigation of the Hydrogen Transport Processes in Crystalline Silicon of n-Type Conductivity

2007 ◽  
Vol 131-133 ◽  
pp. 425-430 ◽  
Author(s):  
Anis M. Saad ◽  
Oleg Velichko ◽  
Yu P. Shaman ◽  
Adam Barcz ◽  
Andrzej Misiuk ◽  
...  
Keyword(s):  
Hydrogen Concentration ◽  
Room Temperature ◽  
Crystalline Silicon ◽  
Transport Processes ◽  
Concentration Profiles ◽  
Hydrogen Transport ◽  
Hydrogen Atoms ◽  
Near Surface ◽  
Type Conductivity ◽  
Hydrogen Molecules

The silicon substrates were hydrogenated at approximately room temperature and hydrogen concentration profiles vs. depth have been measured by SIMS. Czochralski grown (CZ) wafers, both n- and p-type conductivity, were used in the experiments under consideration. For analysis of hydrogen transport processes and quasichemical reactions the model of hydrogen atoms diffusion and quasichemical reactions is proposed and the set of equations is obtained. The developed model takes into account the formation of bound hydrogen in the near surface region, hydrogen transport as a result of diffusion of hydrogen molecules 2 H , diffusion of metastable complexes * 2 H and diffusion of nonequilibrium hydrogen atoms. Interaction of 2 H with oxygen atoms and formation of immobile complexes “oxygen atom - hydrogen molecule” (O - H2 ) is also taken into account to explain the hydrogen concentration profiles in the substrates of n-type conductivity. The computer simulation based on the proposed equations has shown a good agreement of the calculated hydrogen profiles with the experimental data and has allowed receiving a value of the hydrogen molecules diffusivity at room temperature.

Hydrogen transport in amorphous silicon

1992 ◽  
Vol 45 (12) ◽  
pp. 6564-6580 ◽  
Author(s):  
W. B. Jackson ◽  
C. C. Tsai
Keyword(s):  
Amorphous Silicon ◽  
Hydrogen Transport
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