Controlling Energy Levels and Blend Morphology for All-Polymer Solar Cells via Fluorination of a Naphthalene Diimide-Based Copolymer Acceptor

2016 ◽  
Vol 49 (17) ◽  
pp. 6374-6383 ◽  
Author(s):  
Mohammad Afsar Uddin ◽  
Youngkwon Kim ◽  
Robert Younts ◽  
Wonho Lee ◽  
Bhoj Gautam ◽  
...  
Keyword(s):  
Solar Cells ◽  
Polymer Solar Cells ◽  
Energy Levels ◽  
Blend Morphology ◽  
Naphthalene Diimide

scholarly journals Optimization of Sb2S3 Nanocrystal Concentrations in P3HT: PCBM Layers to Improve the Performance of Polymer Solar Cells

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2152
Author(s):  
E. M. Mkawi ◽  
Y. Al-Hadeethi ◽  
R. S. Bazuhair ◽  
A. S. Yousef ◽  
E. Shalaan ◽  
...  
Keyword(s):  
Solar Cells ◽  
Doping Concentration ◽  
Polymer Solar Cells ◽  
Energy Levels ◽  
Acid Methyl Ester ◽  
Visible Absorption ◽  
Block Polymer ◽  
Coating Method ◽  
Electronic Parameters ◽  
P Type

In this study, polymer solar cells were synthesized by adding Sb2S3 nanocrystals (NCs) to thin blended films with polymer poly(3-hexylthiophene)(P3HT) and [6,6]-phenyl-C61-butyric-acid-methyl-ester (PCBM) as the p-type material prepared via the spin-coating method. The purpose of this study is to investigate the dependence of polymer solar cells’ performance on the concentration of Sb2S3 nanocrystals. The effect of the Sb2S3 nanocrystal concentrations (0.01, 0.02, 0.03, and 0.04 mg/mL) in the polymer’s active layer was determined using different characterization techniques. X-ray diffraction (XRD) displayed doped ratio dependences of P3HT crystallite orientations of P3HT crystallites inside a block polymer film. Introducing Sb2S3 NCs increased the light harvesting and regulated the energy levels, improving the electronic parameters. Considerable photoluminescence quenching was observed due to additional excited electron pathways through the Sb2S3 NCs. A UV–visible absorption spectra measurement showed the relationship between the optoelectronic properties and improved surface morphology, and this enhancement was detected by a red shift in the absorption spectrum. The absorber layer’s doping concentration played a definitive role in improving the device’s performance. Using a 0.04 mg/mL doping concentration, a solar cell device with a glass /ITO/PEDOT:PSS/P3HT-PCBM: Sb2S3:NC/MoO3/Ag structure achieved a maximum power conversion efficiency of 2.72%. These Sb2S3 NCs obtained by solvothermal fabrication blended with a P3HT: PCBM polymer, would pave the way for a more effective design of organic photovoltaic devices.

scholarly journals Application of quinoline derivatives in third-generation photovoltaics

2021 ◽  
Author(s):  
Gabriela Lewinska ◽  
Jerzy Sanetra ◽  
Konstanty W. Marszalek
Keyword(s):  
Solar Cells ◽  
Polymer Solar Cells ◽  
Energy Levels ◽  
Photovoltaic Cells ◽  
Third Generation ◽  
Quinoline Derivatives ◽  
Emission Layer ◽  
Light Emitting ◽  
Photovoltaic Applications ◽  
Architecture And Design

AbstractAmong many chemical compounds synthesized for third-generation photovoltaic applications, quinoline derivatives have recently gained popularity. This work reviews the latest developments in the quinoline derivatives (metal complexes) for applications in the photovoltaic cells. Their properties for photovoltaic applications are detailed: absorption spectra, energy levels, and other achievements presented by the authors. We have also outlined various methods for testing the compounds for application. Finally, we present the implementation of quinoline derivatives in photovoltaic cells. Their architecture and design are described, and also, the performance for polymer solar cells and dye-synthesized solar cells was highlighted. We have described their performance and characteristics. We have also pointed out other, non-photovoltaic applications for quinoline derivatives. It has been demonstrated and described that quinoline derivatives are good materials for the emission layer of organic light-emitting diodes (OLEDs) and are also used in transistors. The compounds are also being considered as materials for biomedical applications.

scholarly journals Improving ternary blend morphology by adding a conjugated molecule into non-fullerene polymer solar cells

RSC Advances ◽  
2020 ◽  
Vol 10 (71) ◽  
pp. 43508-43513
Author(s):  
Di Zhao ◽  
Pengcheng Jia ◽  
Ling Li ◽  
Yang Tang ◽  
Qiuhong Cui ◽  
...  
Keyword(s):  
Solar Cells ◽  
Fill Factor ◽  
Polymer Solar Cells ◽  
Photovoltaic Performance ◽  
Ternary Blend ◽  
Promising Strategy ◽  
Blend Morphology ◽  
Ternary Polymer ◽  
Conjugated Molecule

The use of ternary polymer solar cells (PSCs) is a promising strategy to enhance photovoltaic performance while improving the fill factor (FF) of a device, but is still a challenge due to the complicated morphology.

High photovoltage achieved in low band gap polymer solar cells by adjusting energy levels of a polymer with the LUMOs of fullerene derivatives

2008 ◽  
Vol 18 (45) ◽  
pp. 5468 ◽  
Author(s):  
Fengling Zhang ◽  
Johan Bijleveld ◽  
Erik Perzon ◽  
Kristofer Tvingstedt ◽  
Sophie Barrau ◽  
...  
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
Polymer Solar Cells ◽  
Energy Levels ◽  
Low Band Gap ◽  
Fullerene Derivatives ◽  
Low Band Gap Polymer

Bandgap Engineering of Dual Acceptor-Containing Naphthalene Diimide Polymers for All-Polymer Solar Cells

2018 ◽  
Vol 6 (12) ◽  
pp. 16005-16010 ◽  
Author(s):  
Dandan Tu ◽  
Xuan Liu ◽  
Jing Zhang ◽  
Qing Yang ◽  
Shuwen Yu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Polymer Solar Cells ◽  
Bandgap Engineering ◽  
Naphthalene Diimide

scholarly journals Naphthalene Diimide-Based Polymers Consisting of Amino Alkyl Side Groups:Three-Component One-Pot Polymerization and Their Application in Polymer Solar Cells

2017 ◽  
Vol 75 (8) ◽  
pp. 808 ◽  
Author(s):  
Tao Jia ◽  
Nannan Zheng ◽  
Wanqing Cai ◽  
Lei Ying ◽  
Fei Huang
Keyword(s):  
Solar Cells ◽  
Polymer Solar Cells ◽  
One Pot ◽  
Naphthalene Diimide

scholarly journals Polymerized small molecular acceptor based all-polymer solar cells with an efficiency of 16.16% via tuning polymer blend morphology by molecular design

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jiaqi Du ◽  
Ke Hu ◽  
Jinyuan Zhang ◽  
Lei Meng ◽  
Jiling Yue ◽  
...  
Keyword(s):  
Solar Cells ◽  
Molecular Design ◽  
Polymer Solar Cells ◽  
Energy Levels ◽  
Photovoltaic Performance ◽  
Electronic Energy ◽  
Force Microscopy ◽  
Transmission Electron ◽  
Electronic Energy Levels ◽  
20 Nm

AbstractAll-polymer solar cells (all-PSCs) based on polymerized small molecular acceptors (PSMAs) have made significant progress recently. Here, we synthesize two A-DA’D-A small molecule acceptor based PSMAs of PS-Se with benzo[c][1,2,5]thiadiazole A’-core and PN-Se with benzotriazole A’-core, for the studies of the effect of molecular structure on the photovoltaic performance of the PSMAs. The two PSMAs possess broad absorption with PN-Se showing more red-shifted absorption than PS-Se and suitable electronic energy levels for the application as polymer acceptors in the all-PSCs with PBDB-T as polymer donor. Cryogenic transmission electron microscopy visualizes the aggregation behavior of the PBDB-T donor and the PSMA in their solutions. In addition, a bicontinuous-interpenetrating network in the PBDB-T:PN-Se blend film with aggregation size of 10~20 nm is clearly observed by the photoinduced force microscopy. The desirable morphology of the PBDB-T:PN-Se active layer leads its all-PSC showing higher power conversion efficiency of 16.16%.

Optimal extent of fluorination enabling strong temperature-dependent aggregation, favorable blend morphology and high-efficiency polymer solar cells

2017 ◽  
Vol 60 (4) ◽  
pp. 545-551 ◽  
Author(s):  
Guofang Yang ◽  
Zhengke Li ◽  
Kui Jiang ◽  
Jie Zhang ◽  
Jianya Chen ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Temperature Dependent ◽  
Blend Morphology
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