Plateau–Rayleigh Crystal Growth of Nanowire Heterostructures: Strain-Modified Surface Chemistry and Morphological Control in One, Two, and Three Dimensions

Nano Letters ◽  
2016 ◽  
Vol 16 (4) ◽  
pp. 2830-2836 ◽  
Author(s):  
Robert W. Day ◽  
Max N. Mankin ◽  
Charles M. Lieber
2005 ◽  
Vol 50 (2) ◽  
pp. 267-270 ◽  
Author(s):  
C. Robinson ◽  
S. Connell ◽  
S.J. Brookes ◽  
J. Kirkham ◽  
R.C. Shore ◽  
...  

2015 ◽  
Vol 56 (69) ◽  
pp. 127-136 ◽  
Author(s):  
Pat Wongpan ◽  
Patricia J. Langhorne ◽  
David E. Dempsey ◽  
Lisa Hahn-Woernle ◽  
Zhifa Sun

AbstractAntarctic coastal sea ice often grows in water that has been supercooled by interaction with an ice shelf. In these situations, ice crystals can form at depth, rise and deposit under the sea-ice cover to form a porous layer that eventually consolidates near the base of the existing sea ice. The least consolidated portion is called the sub-ice platelet layer. Congelation growth eventually causes the sub-ice platelet layer to become frozen into the sea-ice cover as incorporated platelet ice. In this study, we simulate these processes in three dimensions using Voronoi dynamics to govern crystal growth kinetics. Platelet deposition, in situ growth and incorporation into the sea-ice cover are integrated into the model. Heat and mass transfer are controlled by diffusion. We extract and compare spatial-temporal distributions of porosity, salinity, temperature and crystallographic c-axes with observations from McMurdo Sound, Antarctica. The model captures the crystallographic structure of incorporated platelet ice as well as the topology of the sub-ice platelet layer. The solid fraction, which has previously been poorly constrained, is simulated to be ∼0.22, in good agreement with an earlier estimate of 0.25 ± 0.06. This property of the sub-ice platelet layer is important for biological processes, and for the freeboard-thickness relationship around Antarctica.


2018 ◽  
Author(s):  
Daniel A. Estabrook ◽  
Amanda F. Ennis ◽  
Rachael Day ◽  
Ellen Sletten

Emulsions are dynamic materials that have been extensively employed within pharmaceutical, food and cosmetics industries. However, their use beyond conventional applications has been hindered by difficulties in surface functionalization, and an inability to selectively control physicochemical properties. Here, we employ custom poly(2-oxazoline) block copolymers to overcome these limitations. We demonstrate that poly(2-oxazoline) copolymers can effectively stabilize nanoscale droplets of hydrocarbon and perfluorocarbon in water. The living polymerization allows for the incorporation of chemical handles into the surfactants such that covalent modification of the emulsion surfaces can be performed. Through post-emulsion modification, we are able to access nanoemulsions with modified surface chemistries, yet consistent sizes. By decoupling size and surface charge, we explore structure-activity relationships involving the cellular uptake of nanoemulsions.


2000 ◽  
Vol 322 (5) ◽  
pp. 307-311 ◽  
Author(s):  
M.V. Bollinger ◽  
K.W. Jacobsen ◽  
J.K. Nørskov

2012 ◽  
Vol 581-582 ◽  
pp. 727-730 ◽  
Author(s):  
Xu Zhang ◽  
De Xiang Jia ◽  
Hua Xie

The geometric shape of a crystal can be simulated via a thermodynamic model using breaking bond energy calculations. When this model was applied to the case of the KDP crystal, a thermodynamic description of the KDP crystal growth was successfully developed, which was consistent with experimental observations. Additionally, the effect of surface chemistry on the morphology of the KDP crystal was also investigated using the model based on the surface energy of the KDP crystal. These results confirm that bond making and breaking strongly influence the thermodynamic morphology of the KDP crystal during the crystallization.


2002 ◽  
Vol 33 (4) ◽  
pp. 293-298 ◽  
Author(s):  
Janildo L. Magalhães ◽  
Leonardo M. Moreira ◽  
Ubirajara P. Rodrigues-Filho ◽  
Martha J. Giz ◽  
Marcelo A. Pereira-da-Silva ◽  
...  

Soft Matter ◽  
2011 ◽  
Vol 7 (14) ◽  
pp. 6501 ◽  
Author(s):  
Mathieu Lanniel ◽  
Ejaz Huq ◽  
Stephanie Allen ◽  
Lee Buttery ◽  
Philip M. Williams ◽  
...  

2012 ◽  
Vol 27 (5) ◽  
pp. 419-428 ◽  
Author(s):  
Zeynep A Gencer ◽  
Sedat Odabas ◽  
Hilal T Sasmazel ◽  
Erhan Piskin

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