Physical Vapor Deposition Cluster Arrival Energy Enhances the Electrochemical Performance of Silicon Thin-Film Anodes for Li-Ion Batteries

Author(s):  
Mohammed Salah ◽  
Thushan Pathirana ◽  
Eva Alvarez de Eulate ◽  
Colin Hall ◽  
Bastian Stoehr ◽  
...  

MRS Advances ◽  
2018 ◽  
Vol 3 (60) ◽  
pp. 3513-3518 ◽  
Author(s):  
Taner Zerrin ◽  
Mihri Ozkan ◽  
Cengiz S. Ozkan

ABSTRACTIncreasing the operation voltage of LiCoO2 (LCO) is a direct way to enhance the energy density of the Li-ion batteries. However, at high voltages, the cycling stability degrades very fast due to the irreversible changes in the electrode structure, and formation of an unstable solid electrolyte interface layer. In this work, Ag thin film was prepared on commercial LCO cathode by using magnetron sputtering technique. Ag coated electrode enabled an improved electrochemical performance with a better cycling capability. After 100 cycles, Ag coated LCO delivers a discharge capacity of 106.3 mAh g-1 within 3 - 4.5 V at C/5, which is increased by 45 % compared to that of the uncoated LCO. Coating the electrode surface with Ag thin film also delivered an improved Coulombic efficiency, which is believed to be an indication of suppressed parasitic reactions at the electrode interface. This work may lead to new methods on surface modifications of LCO and other cathode materials to achieve high-capacity Li-ion batteries for high-voltage operations.



2019 ◽  
Vol 12 ◽  
pp. 297-302 ◽  
Author(s):  
Pui-Kit Lee ◽  
Mohammad H. Tahmasebi ◽  
Tian Tan ◽  
Sijia Ran ◽  
Steven T. Boles ◽  
...  


2017 ◽  
Vol 258 ◽  
pp. 800-806 ◽  
Author(s):  
Aliya Mukanova ◽  
Arailym Nurpeissova ◽  
Arshat Urazbayev ◽  
Sung-Soo Kim ◽  
Maksym Myronov ◽  
...  


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Alexander T. Tesfaye ◽  
Frédéric Dumur ◽  
Didier Gigmes ◽  
Sébastien Maria ◽  
Laure Monconduit ◽  
...  


ChemistryOpen ◽  
2017 ◽  
Vol 7 (1) ◽  
pp. 92-96 ◽  
Author(s):  
Aliya Mukanova ◽  
Arailym Nurpeissova ◽  
Sung-Soo Kim ◽  
Maksym Myronov ◽  
Zhumabay Bakenov




2015 ◽  
Vol 273 ◽  
pp. 52-61 ◽  
Author(s):  
M.T. Demirkan ◽  
L. Trahey ◽  
T. Karabacak


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