Total Oxidation of Toluene and Propane over Supported Co3O4 Catalysts: Effect of Structure/Acidity of MWW Zeolite and Cobalt Loading

2021 ◽  
Vol 13 (13) ◽  
pp. 15143-15158
Author(s):  
Weidong Zhang ◽  
Yong Zhou ◽  
Mariya Shamzhy ◽  
Sidónia Molitorisová ◽  
Maksym Opanasenko ◽  
...  

2016 ◽  
Vol 59 (3) ◽  
pp. 161-176 ◽  
Author(s):  
Maninder Kumar ◽  
Gaurav Rattan ◽  
Ram Prasad


2018 ◽  
Vol 4 (4) ◽  
pp. 52-63
Author(s):  
V. Yu. Shumskaya ◽  
S. F. Zhandarov ◽  
L. A. Kalinin ◽  
L. F. Ivanov ◽  
V. V. Snezhkov ◽  
...  




2018 ◽  
Author(s):  
Kenshiro Matsui ◽  
Kunio Fujiwara ◽  
Yoshitaka Ueki ◽  
Masahiko Shibahara


2020 ◽  
Vol 2020 (7) ◽  
pp. 760-766
Author(s):  
M. Yu. Kollerov ◽  
D. E. Gusev ◽  
M. B. Afonina ◽  
R. E. Vinogradov


1966 ◽  
Vol 31 (7) ◽  
pp. 2714-2726 ◽  
Author(s):  
J. Kolínský ◽  
M. Vašta ◽  
R. Chromeček ◽  
M. Bohdanecký


1983 ◽  
Vol 48 (2) ◽  
pp. 586-595 ◽  
Author(s):  
Alexander Perjéssy ◽  
Pavol Hrnčiar ◽  
Ján Šraga

The wave numbers of the fundamental C=O and C=C stretching vibrations, as well as that of the first overtone of C=O stretching vibration of 2-(3-, and 4-substituted phenylmethylene)-1,3-cycloheptanediones and 1,3-cycloheptanedione were measured in tetrachloromethane and chloroform. The spectral data were correlated with σ+ constants of substituents attached to phenyl group and with wave number shifts of the C=O stretching vibration of substituted acetophenones. The slope of the linear dependence ν vs ν+ of the C=C stretching vibration of the ethylenic group was found to be more than two times higher than that of the analogous correlation of the C=O stretching vibration. Positive values of anharmonicity for asymmetric C=O stretching vibration can be considered as an evidence of the vibrational coupling in a cyclic 1,3-dicarbonyl system similarly, as with derivatives of 1,3-indanedione. The relationship between the wave numbers of the symmetric and asymmetric C=O stretching vibrations indicates that the effect of structure upon both vibrations is symmetric. The vibrational coupling in 1,3-cycloheptanediones and the application of Seth-Paul-Van-Duyse equation is discussed in relation to analogous results obtained for other cyclic 1,3-dicarbonyl compounds.



2019 ◽  
Vol 83 ◽  
pp. 107133
Author(s):  
Reza Hasanzadeh Ghasemi ◽  
Masoud Keramati ◽  
Mohammad Hashemi Saleh Mojarrad


Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 252
Author(s):  
Tadej Žumbar ◽  
Alenka Ristić ◽  
Goran Dražić ◽  
Hristina Lazarova ◽  
Janez Volavšek ◽  
...  

The structure–property relationship of catalytic supports for the deposition of redox-active transition metals is of great importance for improving the catalytic efficiency and reusability of the catalysts. In this work, the role of alumina support precursors of Cu-Fe/Al2O3 catalysts used for the total oxidation of toluene as a model volatile organic air pollutant is elucidated. Surface characterization of the catalysts revealed that the surface area, pore volume and acid site concentration of the alumina supports are important but not the determining factors for the catalytic activity of the studied catalysts for this type of reaction. The determining factors are the structural order of the support precursor, the homogeneous distribution of the catalytic sites and reducibility, which were elucidated by XRD, NMR, TEM and temperature programed reduction (TPR). Cu–Fe/Al2O3 prepared from bayerite and pseudoboehmite as highly ordered precursors showed better catalytic performance compared to Cu-Fe/Al2O3 derived from the amorphous alumina precursor and dawsonite. Homogeneous distribution of FexOy and CuOx with defined Cu/Fe molar ratio on the Al2O3 support is required for the efficient catalytic performance of the material. The study showed a beneficial effect of low iron concentration introduced into the alumina precursor during the alumina support synthesis procedure, which resulted in a homogeneous metal oxide distribution on the support.



2021 ◽  
Author(s):  
Miguel Jose Marin Figueredo ◽  
Tahrizi Andana ◽  
Samir Bensaid ◽  
Melodj Dosa ◽  
Debora Fino ◽  
...  


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