Facile In Situ Chemical Cross-Linking Gel Polymer Electrolyte, which Confines the Shuttle Effect with High Ionic Conductivity and Li-Ion Transference Number for Quasi-Solid-State Lithium–Sulfur Battery

2021 ◽  
Vol 13 (37) ◽  
pp. 44497-44508
Author(s):  
Tongwei Zhang ◽  
Jun Zhang ◽  
Shan Yang ◽  
Yuan Li ◽  
Ran Dong ◽  
...  
Keyword(s):  
Solid State ◽  
Gel Polymer Electrolyte ◽  
Transference Number ◽  
Cross Linking ◽  
Shuttle Effect ◽  
Li Ion ◽  
Sulfur Battery ◽  
Chemical Cross Linking ◽  
Lithium Sulfur

Metalophilic Gel Polymer Electrolyte for in Situ Tailoring Cathode/Electrolyte Interface of High-Nickel Oxide Cathodes in Quasi-Solid-State Li-Ion Batteries

2019 ◽  
Vol 11 (16) ◽  
pp. 14830-14839 ◽  
Author(s):  
Yan-Yun Sun ◽  
Yang-Yang Wang ◽  
Guo-Ran Li ◽  
Sheng Liu ◽  
Xue-Ping Gao
Keyword(s):  
Solid State ◽  
Nickel Oxide ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte ◽  
Li Ion Batteries ◽  
Electrolyte Interface ◽  
Oxide Cathodes ◽  
High Nickel ◽  
Li Ion

In situ generated Li2S-LPS composite for all-solid-state lithium-sulfur battery

Ionics ◽  
2019 ◽  
Vol 26 (5) ◽  
pp. 2335-2342 ◽  
Author(s):  
Huize Jiang ◽  
Yu Han ◽  
Hui Wang ◽  
Qingpeng Guo ◽  
Yuhao Zhu ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Sulfur Battery ◽  
Sulfur Battery ◽  
Lithium Sulfur

A lithium anode protection guided highly-stable lithium–sulfur battery

2014 ◽  
Vol 50 (91) ◽  
pp. 14209-14212 ◽  
Author(s):  
Guoqiang Ma ◽  
Zhaoyin Wen ◽  
Meifen Wu ◽  
Chen Shen ◽  
Qingsong Wang ◽  
...  
Keyword(s):  
Lithium Anode ◽  
Lithium Sulfur Battery ◽  
Shuttle Effect ◽  
Protection Layer ◽  
Sulfur Battery ◽  
Lithium Sulfur

A Li3N protection layer is fabricated on the surface of a Li anode by anin situmethod to suppress the shuttle effect on the basis of anode protection.

Phase Separation of Li2S/S at Nanoscale during Electrochemical Lithiation of the Solid-State Lithium-Sulfur Battery Using In Situ TEM

2016 ◽  
Vol 6 (20) ◽  
pp. 1600806 ◽  
Author(s):  
Zhenzhong Yang ◽  
Zhiyong Zhu ◽  
Jie Ma ◽  
Dongdong Xiao ◽  
Xian Kui ◽  
...  
Keyword(s):  
Phase Separation ◽  
Solid State ◽  
In Situ Tem ◽  
Lithium Sulfur Battery ◽  
Electrochemical Lithiation ◽  
Sulfur Battery ◽  
Lithium Sulfur

Lithiophilic gel polymer electrolyte to stabilize the lithium anode for a quasi-solid-state lithium–sulfur battery

2018 ◽  
Vol 6 (38) ◽  
pp. 18627-18634 ◽  
Author(s):  
Dian-Dian Han ◽  
Sheng Liu ◽  
Ya-Tao Liu ◽  
Ze Zhang ◽  
Guo-Ran Li ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte ◽  
Lithium Anode ◽  
Lithium Sulfur Battery ◽  
Sulfur Battery ◽  
Lithium Sulfur

The lithiophilic gel polymer electrolyte is demonstrated to be feasible to stabilize the lithium anode in a quasi-solid-state Li–S battery.

scholarly journals Flexible Quasi-Solid-State Composite Electrolyte of Poly (Propylene Glycol)-co-Pentaerythritol Triacry-Late/Li1.5Al0.5Ge1.5(PO4)3 for High-Performance Lithium-Sulfur Battery

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1979
Author(s):  
Zekun Deng ◽  
Zhenyang Zheng ◽  
Wenhong Ruan ◽  
Mingqiu Zhang
Keyword(s):  
Solid State ◽  
Propylene Glycol ◽  
Specific Capacity ◽  
Ion Conductivity ◽  
Composite Electrolyte ◽  
Shuttle Effect ◽  
Electrochemical Window ◽  
Li Ion ◽  
Poly Propylene ◽  
Lithium Sulfur

With a higher theoretical specific capacity (1675 mAh g−1) and energy density (2600 Wh kg−1), the lithium-sulfur (Li-S) battery is considered as a promising candidate for a next-generation energy storage device. However, the shuttle effect of polysulfides as well as the large interfacial impedance between brittle solid electrolyte and electrodes lead to the capacity of the Li-S battery decaying rapidly, which limits the practical commercial applications of the Li-S battery. Herein, we reported a facile in situ ultraviolet (UV) curing method to prepare a flexible quasi-solid-state composite electrolyte (QSSCE) of poly(propylene glycol)-co-pentaerythritol triacrylate/Li1.5Al0.5Ge1.5(PO4)3 (PPG-co-PETA/LAGP). By combining the high Li-ion conductivity and mechanical strength of inorganic NASICON-structure LAGP and good flexibility of the crosslinked PPG-co-PETA with nanopore structure, the flexible QSSCE with 66.85 wt% LAGP exhibited high Li-ion conductivity of 5.95 × 10−3 S cm−1 at 25 °C, Li-ion transference number of 0.83 and wide electrochemical window of ~5.0 V (vs. Li/Li+). In addition, the application of QSSCE in the Li-S battery could suppress the shuttle effect of polysulfides effectively, thus the Li-S battery possessed the excellent electrochemical cyclic performance, showing the first-cycle discharge-specific capacity of 1508.1 mAh g−1, the capacity retention of 73.6% after 200 cycles with 0.25 C at 25 °C and good rate performance.

A new high ionic conductive gel polymer electrolyte enables highly stable quasi-solid-state lithium sulfur battery

2019 ◽  
Vol 22 ◽  
pp. 256-264 ◽  
Author(s):  
Jinqiu Zhou ◽  
Haoqing Ji ◽  
Jie Liu ◽  
Tao Qian ◽  
Chenglin Yan
Keyword(s):  
Solid State ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte ◽  
Lithium Sulfur Battery ◽  
Sulfur Battery ◽  
Lithium Sulfur

Quasi-solid-state dye-sensitized solar cells assembled by in-situ chemical cross-linking at ambient temperature

2011 ◽  
Vol 13 (11) ◽  
pp. 1284-1287 ◽  
Author(s):  
Su Jung Lim ◽  
Yeon Jeong Choi ◽  
Kwang Soup Song ◽  
Dong-Won Kim
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Ambient Temperature ◽  
Dye Sensitized Solar Cells ◽  
Cross Linking ◽  
Dye Sensitized ◽  
Sensitized Solar Cells ◽  
Chemical Cross Linking

Fast Li-ion Conductor of Li3HoBr6 for Stable All-Solid-State Lithium–Sulfur Battery

Nano Letters ◽  
2021 ◽  
Author(s):  
Xiaomeng Shi ◽  
Zhichao Zeng ◽  
Mingzi Sun ◽  
Bolong Huang ◽  
Hongtu Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Conductor ◽  
Lithium Sulfur Battery ◽  
Li Ion ◽  
Sulfur Battery ◽  
Lithium Sulfur
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