Defective Hexagonal Boron Nitride Nanosheet on Ni(111) and Cu(111): Stability, Electronic Structures, and Potential Applications

2016 ◽  
Vol 8 (36) ◽  
pp. 24238-24247 ◽  
Author(s):  
Xiaomei Gao ◽  
Shujiao Wang ◽  
Sen Lin
Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 206 ◽  
Author(s):  
Elisseos Verveniotis ◽  
Yuji Okawa ◽  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takaaki Taniguchi ◽  
...  

2021 ◽  
Author(s):  
Xinyi Li ◽  
Song Chen ◽  
Qian Liu ◽  
Yonglan Luo ◽  
Xuping Sun

Correction for ‘Hexagonal boron nitride nanosheet as an effective nanoquencher for the fluorescence detection of microRNA’ by Xinyi Li et al., Chem. Commun., 2021, DOI: 10.1039/d1cc03011f.


2018 ◽  
Vol 32 (06) ◽  
pp. 1850084 ◽  
Author(s):  
Yi-Min Ding ◽  
Jun-Jie Shi ◽  
Min Zhang ◽  
Meng Wu ◽  
Hui Wang ◽  
...  

It is difficult to integrate two-dimensional (2D) graphene and hexagonal boron-nitride (h-BN) in optoelectronic nanodevices, due to the semi-metal and insulator characteristic of graphene and h-BN, respectively. Using the state-of-the-art first-principles calculations based on many-body perturbation theory, we investigate the electronic and optical properties of h-BN nanosheet embedded with graphene dots. We find that C atom impurities doped in h-BN nanosheet tend to phase-separate into graphene quantum dots (QD), and BNC hybrid structure, i.e. a graphene dot within a h-BN background, can be formed. The band gaps of BNC hybrid structures have an inverse relationship with the size of graphene dot. The calculated optical band gaps for BNC structures vary from 4.71 eV to 3.77 eV, which are much smaller than that of h-BN nanosheet. Furthermore, the valence band maximum is located in C atoms bonded to B atoms and conduction band minimum is located in C atoms bonded to N atoms, which means the electron and hole wave functions are closely distributed around the graphene dot. The bound excitons, localized around the graphene dot, determine the optical spectra of the BNC hybrid structures, in which the exciton binding energies decrease with increase in the size of graphene dots. Our results provide an important theoretical basis for the design and development of BNC-based optoelectronic nanodevices.


NANO ◽  
2019 ◽  
Vol 14 (08) ◽  
pp. 1950107
Author(s):  
Shirin Daneshnia ◽  
Mohsen Adeli ◽  
Yaghoub Mansourpanah

Two-dimensional hexagonal boron nitride is a fascinating nanomaterial with a broad range of potential applications. However, further development of this nanomaterial is hampered because of its poor functionality and low processability. One of the efficient strategies for improving the processability of two-dimensional hexagonal boron nitride is the covalent functionalization of this nanomaterial. In this study, we report on a straightforward approach for functionalization of two-dimensional hexagonal boron nitride by lithium cyclopentadienyl and its application for water treatment. Cyclopentadienyl-functionalized boron nitride was characterized by different spectroscopy and microscopy methods as well as thermal and BET analysis. The synthesized nanomaterial was able to efficiently remove methylene blue from water in a short time. Adsorption capacity of this nanomaterial was as high as 476.3[Formula: see text]mg/g, which was superior to the nonfunctionalized boron nitride. Our results showed that cyclopentadienyl-functionalized boron nitride is a promising candidate for the removal of cationic pollutants from water.


2019 ◽  
Vol 29 (39) ◽  
pp. 1902245 ◽  
Author(s):  
Ana C. M. Moraes ◽  
Woo Jin Hyun ◽  
Jung‐Woo T. Seo ◽  
Julia R. Downing ◽  
Jin‐Myoung Lim ◽  
...  

2012 ◽  
Vol 122 ◽  
pp. 6-11 ◽  
Author(s):  
Masanori Mitome ◽  
Hidetaka Sawada ◽  
Yukihito Kondo ◽  
Yasumasa Tanishiro ◽  
Kunio Takayanagi

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