Spherical Aberration-Corrected Metalens for Polarization Multiplexed Imaging

We present a terahertz spherical aberration-corrected metalens that uses the dynamic phase to achieve polarization multiplexed imaging. The designed metalens has polarization–dependent imaging efficiencies and polarization extinction ratios that exceed 50% and 10:1, respectively. Furthermore, opposite gradient phases can be applied to orthogonal polarizations to shift the imaging of the two polarized sources in the longitudinal and transverse directions. Indeed, we find that the metalens has a smaller depth-of-focus than a traditional metalens when imaging point sources with limited objective lengths. These results provide a new approach for achieving multifunctional beam steering, tomographic imaging and chiroptical detection.

Atomic level fluxional behavior and activity of CeO2-supported Pt catalysts for CO oxidation

Reducible oxides are widely used catalyst supports that can increase oxidation reaction rates by transferring lattice oxygen at the metal-support interface. There are many outstanding questions regarding the atomic-scale dynamic meta-stability (i.e., fluxional behavior) of the interface during catalysis. Here, we employ aberration-corrected operando electron microscopy to visualize the structural dynamics occurring at and near Pt/CeO2 interfaces during CO oxidation. We show that the catalytic turnover frequency correlates with fluxional behavior that (a) destabilizes the supported Pt particle, (b) marks an enhanced rate of oxygen vacancy creation and annihilation, and (c) leads to increased strain and reduction in the CeO2 support surface. Overall, the results implicate the interfacial Pt-O-Ce bonds anchoring the Pt to the support as being involved also in the catalytically-driven oxygen transfer process, and they suggest that oxygen reduction takes place on the highly reduced CeO2 surface before migrating to the interfacial perimeter for reaction with CO.